4-broMo-3-(hydroxyMethyl)benzoic acid

Product Name: 4-broMo-3-(hydroxyMethyl)benzoic acid
CAS No.: 790230-04-5
Chemical Name: 4-broMo-3-(hydroxyMethyl)benzoic acid
Synonyms: 4-broMo-3-(hydroxyMethyl)benzoic acid;Benzoic acid, 3-bromo-4-(bromomethyl)-
CBNumber: CB22596073
Molecular Formula: C8H7BrO3
Formula Weight: 231.04338
MOL File: 790230-04-5.mol

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4-broMo-3-(hydroxyMethyl)benzoic acid Property

storage temp.: Sealed in dry,Room Temperature
Appearance: White to off-white Solid

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Safety

HS Code: 2918199890

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B696183
Product name: 4-Bromo-3-(hydroxymethyl)benzoicacid
Packaging: 100mg
Price: $180
Updated: 2021/12/16

Apolloscientific

Product number: OR908216
Product name: 4-Bromo-3-(hydroxymethyl)benzoicacid
Purity: 97%
Packaging: 1g
Price: $292
Updated: 2021/12/16

AK Scientific

Product number: 2357AC
Product name: 4-Bromo-3-(hydroxymethyl)benzoicacid
Packaging: 1g
Price: $397
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0365679
Product name: 4-BROMO-3-(HYDROXYMETHYL)BENZOIC ACID
Purity: 95.00%
Packaging: 5MG
Price: $497.67
Updated: 2021/12/16

Oakwood

Product number: 211450
Product name: 4-Bromo-3-(hydroxymethyl)benzoicacid
Purity: 95+%
Packaging: 1g
Price: $715
Updated: 2021/12/16

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4-broMo-3-(hydroxyMethyl)benzoic acid Chemical Properties,Usage,Production

Synthesis

254746-41-3

790230-04-5

b) Synthesis of 4-bromo-3-(hydroxymethyl)benzoic acid A solution of lithium hydroxide monohydrate (2.278 g, 54.3 mmol) in water (12 mL) was slowly added to a solution of tetrahydrofuran (40 mL) containing methyl 3-(acetoxymethyl)-4-bromobenzoate (3.89 g), and the reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the pH was adjusted with 2 M hydrochloric acid solution to about 1. Subsequently, an appropriate amount of water and ethyl acetate were added for extraction, and the aqueous phase was re-extracted with ethyl acetate. All organic phases were combined, washed sequentially with water and saturated brine, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to afford the title compound 4-bromo-3-(hydroxymethyl)benzoic acid 3.06 g in 98% yield. The product was characterized by 1H NMR (500 MHz, DMSO-d6): δ 13.15 (br.s, 1H), 8.11 (d, 1H), 7.65-7.76 (m, 2H), 5.55-5.69 (m, 1H), 4.54 (d, 2H); mass spectra (ESI) m/z 229,231 [M-1]-.

References

[1] Patent: WO2010/132016, 2010, A1. Location in patent: Page/Page column 74
[2] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 23, p. 7688 - 7705

4-broMo-3-(hydroxyMethyl)benzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-broMo-3-(hydroxyMethyl)benzoic acid Suppliers

China 52 India 2 United States 3 Global 57

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790230-04-5, 4-broMo-3-(hydroxyMethyl)benzoic acidRelated Search:

4-broMo-3-(hydroxyMethyl)benzoic acid

Benzoic acid, 3-bromo-4-(bromomethyl)-

790230-04-5