ChemicalBook > CAS DataBase List > 1-Phenyl-1,2-propanedione-2-oxime

1-Phenyl-1,2-propanedione-2-oxime

Product Name
1-Phenyl-1,2-propanedione-2-oxime
CAS No.
119-51-7
Chemical Name
1-Phenyl-1,2-propanedione-2-oxime
Synonyms
ra58;NSC 5410;TIMTEC-BB SBB003926;Oximinopropiophenone;A-OXIMINOPROPIOPHENONE;2-propanedione-2-oxime;isonitroso-propiophenon;ISONITROSO PROPIOPHENONE;2-ISONITROSOPROPIOPHENONE;2-lsonitrosopropiophenone
CBNumber
CB2260444
Molecular Formula
C9H9NO2
Formula Weight
163.17
MOL File
119-51-7.mol
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1-Phenyl-1,2-propanedione-2-oxime Property

Melting point:
113-115 °C(lit.)
Boiling point:
290.25°C (rough estimate)
Density 
1.2021 (rough estimate)
refractive index 
1.5460 (estimate)
storage temp. 
2-8°C
solubility 
soluble in Methanol
form 
Crystals
pka
9.28±0.10(Predicted)
color 
White to light yellow
λmax
398nm(MeOH)(lit.)
CAS DataBase Reference
119-51-7(CAS DataBase Reference)
NIST Chemistry Reference
1-Phenyl-1,2-propane-dione-2-oxime(119-51-7)
EPA Substance Registry System
1,2-Propanedione, 1-phenyl-, 2-oxime (119-51-7)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
24/25-37/39-26
WGK Germany 
2
RTECS 
UH2975000
HS Code 
29280090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H400Very toxic to aquatic life

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I3502
Product name
α-Isonitrosopropiophenone
Packaging
10g
Price
$56.7
Updated
2024/03/01
Sigma-Aldrich
Product number
I3502
Product name
α-Isonitrosopropiophenone
Packaging
50g
Price
$104.4
Updated
2024/03/01
TCI Chemical
Product number
P0211
Product name
2-Isonitrosopropiophenone
Purity
>98.0%(GC)
Packaging
25g
Price
$61
Updated
2024/03/01
TRC
Product number
P399488
Product name
1-Phenyl-1,2-propanedione-2-oxime
Packaging
2.5g
Price
$75
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK307788
Product name
1-Phenyl-1,2-propanedione-2-oxime
Purity
99%
Packaging
25g
Price
$77
Updated
2021/12/16
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1-Phenyl-1,2-propanedione-2-oxime Chemical Properties,Usage,Production

Chemical Properties

WHITE TO LIGHT YELLOW CRYSTALS

Uses

Reactant involved in synthesis of:

  • Cyclometalated iridium complexes for photophysical and electrochemical studies
  • Hydroimidazothiazoles via iodination and cyclization reactions

Reactant involved in:
  • Sonogashira coupling reactions
  • Allylation of aromatic aldehydes using imidazole oside catalysts
  • Beckmann rearrangement of α-oximinoketones

Reagent used in the colorimetric determination of urea

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 2, p. 363, 1943
Tetrahedron Letters, 30, p. 2833, 1989 DOI: 10.1016/S0040-4039(00)99137-8

1-Phenyl-1,2-propanedione-2-oxime Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Phenyl-1,2-propanedione-2-oxime Suppliers

Americas 1 Belgium 1 China 85 Europe 4 Germany 4 India 14 Japan 5 Poland 1 Slovakia 1 South Korea 1 Switzerland 2 United Kingdom 7 United States 26 USA 1 Global 153
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from 1-Phenyl-1,2-propanedione-2-oxime manufacturers

Career Henan Chemical Co
Product
1-Phenyl-1,2-propanedione-2-oxime 119-51-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-09

119-51-7, 1-Phenyl-1,2-propanedione-2-oximeRelated Search:

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  • A-OXIMINOPROPIOPHENONE
  • ISONITROSO PROPIOPHENONE
  • ALPHA-ISONITROSOPROPIOPHENONE
  • 1-PHENYL-1,2-PROPANEDIONE-2-OXIME
  • 2-ISONITROSOPROPIOPHENONE
  • 2-HYDROXYIMINOPROPIOPHENONE
  • Methylbenzoyl ketone oxime
  • α-(Hydroxyimino)propiophenone
  • 1-Phenyl-1,2-propanedione-2-oxime,99%
  • 1-Phenyl-1,2-propanedione-2-oxiMe, 99% 25GR
  • 2-Hydroxyiminopropiophenone 1-Phenyl-1,2-propanedione 2-Oxime
  • (E)-2-(hydroxyiMino)-1-phenylpropan-1-one
  • 2-lsonitrosopropiophenone
  • NSC 5410
  • 2-PHENYL-1,2-PROPANEDIONE-2-OXIME
  • 2-propanedione-2-oxime
  • (2E)-2-hydroxyimino-1-phenyl-1-propanone
  • (2E)-1-Phenyl-1,2-propanedione 2-oxime
  • 1,2-Propanedione, 1-phenyl-, 2-oxime
  • 2-propanedione,1-phenyl-2-oxime
  • alpha-Oximinopropiophenone
  • isonitroso-propiophenon
  • Propiophenone, isonitroso-
  • ra58
  • TIMTEC-BB SBB003926
  • Oximinopropiophenone
  • A-ISONITROSOPROPIOPHENONE
  • 2-Hydroxyimino-1-phenylpropan-1-one
  • 1-Phenyl-2-(hydroxyimino)-1-propanone
  • 1-Phenyl-2-hydroxyimino-1-propanone
  • 2-(Hydroxyimino)-1-phenyl-1-propanone
  • 1-PHENYL-1,2-PROPANEDIONE 2-OXIME 99%
  • 2-Isonitrosopropiophenone&gt
  • 119-51-7---1-Phenyl-1,2-propanedione-2-oxime
  • α-Isonitrosopropiophenone
  • 119-51-7
  • C6H5COCNOHCH3
  • Oximes
  • Organic Building Blocks
  • Nitrogen Compounds
  • Photopolymerization Initiators
  • Building Blocks
  • Functional Materials
  • Photopolymerization Initiators