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p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-

Product Name
p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-
CAS No.
1080632-76-3
Chemical Name
p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-
Synonyms
2-dioxaborolan-2-yl)-;2-([1,1':4',1''-Terphenyl]-4-yl);4,4,5,5-Tetramethyl-2-(1,1':4',1''-t erphenyl-4- yl);[1,1':4',1''-Terphenyl]-4-boronic acid pinacol ester;(1,1':4',1''-Terphenyl)-4-ylboronic Acid Pinacol Ester;p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-;4,4,5,5-tetramethyl-2-[4-(4-phenylphenyl)phenyl]-1,3,2-dioxaborolane;4,4,5,5-Tetramethyl-2-[1,1':4',1''-terphenyl]-4-yl-1,3,2-dioxaborolane;2-([1,1':4',1"-terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxabolorane;[1,1′:4′,1′′-Terphenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)
CBNumber
CB22610485
Molecular Formula
C24H25BO2
Formula Weight
356.27
MOL File
1080632-76-3.mol
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p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- Property

Melting point:
146 °C
Boiling point:
508.5±29.0 °C(Predicted)
Density 
1.10
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
White to off-white Solid
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Safety

HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T3875
Product name
2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Packaging
1G
Price
$99
Updated
2026/03/19
AK Scientific
Product number
9235DN
Product name
2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Packaging
1g
Price
$150
Updated
2021/12/16
Chem-Impex
Product number
39927
Product name
2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,≥98%(GC)
Purity
≥98%(GC)
Packaging
1G
Price
$171.23
Updated
2021/12/16
Ambeed
Product number
A254301
Product name
2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity
97%
Packaging
5g
Price
$211
Updated
2021/12/16
Crysdot
Product number
CD12181973
Product name
2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity
95+%
Packaging
5g
Price
$594
Updated
2021/12/16
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p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- Chemical Properties,Usage,Production

Synthesis

1762-84-1

73183-34-3

1080632-76-3

General procedure for the synthesis of [1,1':4',1''-terphenyl]-4-boronic acid pinacol ester from 4-bromo-p-terphenyl and bis(pinacolato)diboronic acid: 4-bromo-p-terphenyl (120 g, 388 mmol) was dissolved in 1.2 L of dimethylformamide (DMF) under nitrogen protection. Subsequently, bis(pinacolato)diboron (118 g, 466 mmol), 1,1'-bis(diphenylphosphino)ferric-palladium(II) dichloride (3.17 g, 3.88 mmol) and potassium acetate (114 g, 1,164 mmol) were added. The reaction mixture was heated to reflux at 150 °C for 4 hours. After completion of the reaction, the reaction solution was poured into water and the precipitate was collected by filtration. The resulting solid was dried in a vacuum oven. Finally, the crude product was separated and purified by fast column chromatography to afford [1,1':4',1''-terphenyl]-4-boronic acid pinacol ester (124 g, 90% yield).

References

[1] Patent: KR2015/117173, 2015, A. Location in patent: Paragraph 0284-0286
[2] Patent: US2017/331067, 2017, A1. Location in patent: Paragraph 0248-0251
[3] Patent: US2017/40550, 2017, A1. Location in patent: Paragraph 0083

p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- Preparation Products And Raw materials

Raw materials

Preparation Products

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p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- Suppliers

Energy Chemical
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View Lastest Price from p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- 1080632-76-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-17
Career Henan Chemical Co
Product
p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)- 1080632-76-3
Price
US $8.68/KG
Min. Order
1KG
Purity
95.0%-99.0%
Supply Ability
1kg-100kg
Release date
2020-03-12

1080632-76-3, p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-Related Search:


  • p-Terphenyl, 4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-
  • [1,1':4',1''-Terphenyl]-4-boronic acid pinacol ester
  • 4,4,5,5-Tetramethyl-2-[1,1':4',1''-terphenyl]-4-yl-1,3,2-dioxaborolane
  • 2-([1,1':4',1''-Terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • 2-([1,1':4',1''-Terphenyl]-4-yl)
  • 2-([1,1':4',1"-terphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxabolorane
  • 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[1,1':4',1''-terphenyl]-4-yl-
  • (1,1':4',1''-Terphenyl)-4-ylboronic Acid Pinacol Ester
  • 2-dioxaborolan-2-yl)-
  • [1,1′:4′,1′′-Terphenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)
  • 4,4,5,5-Tetramethyl-2-(1,1':4',1''-t erphenyl-4- yl)
  • 4,4,5,5-tetramethyl-2-[4-(4-phenylphenyl)phenyl]-1,3,2-dioxaborolane
  • 1080632-76-3
  • C24H25BO2
  • OLED