tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate
- Product Name
- tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate
- CAS No.
- 410529-86-1
- Chemical Name
- tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate
- Synonyms
- Tert-butyl N-(diphenylphosphorylmethylsulfonyl)carbamate;tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate;Carbamic acid, N-[[(diphenylphosphinyl)methyl]sulfonyl]-, 1,1-dimethylethyl ester
- CBNumber
- CB22693394
- Molecular Formula
- C18H22NO5PS
- Formula Weight
- 395.41
- MOL File
- 410529-86-1.mol
tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate Property
- storage temp.
- 2-8°C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- AK110652
- Product name
- tert-Butyl((diphenylphosphoryl)methyl)sulfonylcarbamate
- Purity
- 95+%
- Packaging
- 100mg
- Price
- $93
- Updated
- 2021/12/16
- Product number
- 098195
- Product name
- tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $189
- Updated
- 2021/12/16
- Product number
- AK110652
- Product name
- tert-Butyl((diphenylphosphoryl)methyl)sulfonylcarbamate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $298
- Updated
- 2021/12/16
- Product number
- 5620AB
- Product name
- tert-Butyl((diphenylphosphoryl)methyl)sulfonylcarbamate
- Packaging
- 1g
- Price
- $412
- Updated
- 2021/12/16
- Product number
- 098195
- Product name
- tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate
- Purity
- 95+%
- Packaging
- 5g
- Price
- $504
- Updated
- 2021/12/16
tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate Chemical Properties,Usage,Production
Synthesis
147751-16-4
1499-21-4
410529-86-1
At -78 °C, tert-butyl N-methylsulfonylcarbamate (2 g, 10 mmol) was dissolved in THF (25 mL) and LDA (2 M solution of THF, 15.4 mL, 30.7 mmol) was added slowly. After addition, the reaction was maintained at -78 °C with stirring for 10 min. Subsequently, diphenylphosphinic chloride (2.42 g, 10.2 mmol) was added dropwise and the reaction was continued at -78 °C for 90 min. Upon completion of the reaction, the reaction was quenched by the addition of water (100 mL) and the reaction mixture was diluted with ethyl acetate (250 mL). The pH of the aqueous layer was adjusted to 5 with 5% aqueous HCl, at which time a white precipitate was produced. The precipitate was collected by filtration and the resulting solid was dried under vacuum to give tert-butyl ((diphenylphosphino)methyl)sulfonylcarbamate (2.9 g, 72% yield) as a final white solid.
References
[1] Synthesis, 2003, # 15, p. 2321 - 2324
[2] Patent: WO2011/28741, 2011, A1. Location in patent: Page/Page column 331
tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate Preparation Products And Raw materials
Raw materials
Preparation Products
tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate Suppliers
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- 15921303235
- Fax
- QQ489466966
- sales@synthfine.com
- Country
- China
- ProdList
- 1020
- Advantage
- 58
- Tel
- 15121041756
- xingui2022@126.com
- Country
- China
- ProdList
- 9975
- Advantage
- 58
- Tel
- +86-021-61654350
- Fax
- +86-021-61654350
- 1245958370@qq.com
- Country
- China
- ProdList
- 2982
- Advantage
- 50
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 86249
- Advantage
- 60
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 025-66162170
- Fax
- 025-66162170
- Country
- China
- ProdList
- 7181
- Advantage
- 55
- Tel
- 0371-55900031 18137872243
- 3927209986@qq.com
- Country
- China
- ProdList
- 10000
- Advantage
- 55
- Tel
- 13811826434
- Fax
- -
- lichen13811826434@126.com
- Country
- China
- ProdList
- 677
- Advantage
- 58
- Tel
- 400-711-5280 86-571-81025280
- Fax
- 86-571-85806285
- sales@molcore.com
- Country
- China
- ProdList
- 9967
- Advantage
- 58
View Lastest Price from tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate manufacturers
- Product
- tert-Butyl ((diphenylphosphoryl)-methyl)sulfonylcarbamate 410529-86-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-10