Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO

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Product Name: Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
CAS No.: 1295649-40-9
Chemical Name: Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
Synonyms: Ru-MACHO(regR);Ru-MACHO^?;Ru-MACHO (contains 5% Toluene at maximum) ;Ru-MACHO[R] (contains 5% Toluene at maximum);Ru-MACHO(regR) (contains 5% Toluene at maximum);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II);Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO;Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM)
CBNumber: CB22709282
Molecular Formula: C29H31ClNOP2Ru
Formula Weight: 608.04
MOL File: 1295649-40-9.mol

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Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Property

Melting point:: 260-290 °C
storage temp.: 2-8°C, stored under nitrogen
form: Powder
color: white to yellow
Sensitive: air sensitive
InChI: 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
InChIKey: GQFWSAKCCNATEV-UHFFFAOYSA-M
SMILES: Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
CAS DataBase Reference: 1295649-40-9

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Safety

WGK Germany: WGK 3
HS Code: 2843.90.0000
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 739103
Product name: Ru-MACHO®
Packaging: 250MG
Price: $69.09
Updated: 2025/07/31

Sigma-Aldrich

Product number: 739103
Product name: Ru-MACHO®
Packaging: 1G
Price: $263.12
Updated: 2025/07/31

Sigma-Aldrich

Product number: 739103
Product name: Ru-MACHO®
Packaging: 5G
Price: $478
Updated: 2025/07/31

TCI Chemical

Product number: R0136
Product name: Ru-MACHO[R] (contains 5% Toluene at maximum)
Packaging: 200mg
Price: $65
Updated: 2025/07/31

TCI Chemical

Product number: R0136
Product name: Ru-MACHO[R] (contains 5% Toluene at maximum)
Packaging: 1g
Price: $203
Updated: 2025/07/31

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Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Chemical Properties,Usage,Production

Reaction

Highly efficient ruthenium-catalyzed used in the N-formylation of amines with hydrogen and carbon dioxide.
Rutheniumcatalyzed hydrogen generation from glycerol and selective synthesis of lactic acid

Uses

<ul>
<li>Dehydrogenative Intramolecular Macrolactonization: Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li>Acceptorless Dehydrogenation of Methanol: Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li>Precapture and Hydrogenation of CO₂: A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO₂ into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li>Pressure-dependent Hydrogenative Depolymerization: The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul>

reaction suitability

core: ruthenium
reagent type: catalyst

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Suppliers

Belgium 1 China 34 Germany 1 India 2 Japan 3 United States 6 Global 47

J & K SCIENTIFIC LTD.

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Sigma-Aldrich

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parabiochem

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1295649-40-9, Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHORelated Search:

Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH

Ru-MACHO(regR)

Ru-MACHO(regR) (contains 5% Toluene at maximum)

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO

Ru-MACHO (contains 5% Toluene at maximum)

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II)

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM)

Ru-MACHO[R] (contains 5% Toluene at maximum)

Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II)

Ru-MACHO?

1295649-40-9

C29H30ClNOP2Ru