FluoroMethyl 2-pyridyl sulfone

Product Name: FluoroMethyl 2-pyridyl sulfone
CAS No.: 1365765-53-2
Chemical Name: FluoroMethyl 2-pyridyl sulfone
Synonyms: FM-2-pyridyl sulfone;2-Pyridyl fluoromethyl sulfone;FluoroMethyl 2-pyridyl sulfone;2-[(Fluoromethyl)sulfonyl]-pyridine;Pyridine, 2-[(fluoromethyl)sulfonyl]-;Pyridine, 2-[(fluoromethyl)sulfonyl]-2-fluoromethanesulfonylpyridine
CBNumber: CB22709646
Molecular Formula: C6H6FNO2S
Formula Weight: 175.18
MOL File: 1365765-53-2.mol

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FluoroMethyl 2-pyridyl sulfone Property

Boiling point:: 353.2±35.0 °C(Predicted)
Density: 1.348±0.06 g/cm3(Predicted)
storage temp.: Store at room temperature
pka: -3.04±0.19(Predicted)
Appearance: White to off-white Solid
InChI: InChI=1S/C6H6FNO2S/c7-5-11(9,10)6-3-1-2-4-8-6/h1-4H,5H2
InChIKey: KCKYDPXAKVBJHE-UHFFFAOYSA-N
SMILES: C1(S(CF)(=O)=O)=NC=CC=C1

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Safety

Safety Statements: 24/25
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Frontier Specialty Chemicals

Product number: JK1711631
Product name: Fluoromethyl2-pyridylsulfone
Purity: 98%
Packaging: 250mg
Price: $60
Updated: 2021/12/16

Apolloscientific

Product number: PC10695
Product name: Fluoromethyl2-pyridylsulfone
Purity: 95%
Packaging: 250mg
Price: $104
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK1711631
Product name: Fluoromethyl2-pyridylsulfone
Purity: 98%
Packaging: 1g
Price: $178
Updated: 2021/12/16

Apolloscientific

Product number: PC10695
Product name: Fluoromethyl2-pyridylsulfone
Purity: 95%
Packaging: 1g
Price: $320
Updated: 2021/12/16

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FluoroMethyl 2-pyridyl sulfone Chemical Properties,Usage,Production

Description

Fluoromethyl 2-pyridyl sulfone and its derivatives can be used as novel monofluoromethylation reagents. The monofluorinated sulfinate intermediates during the monofluoroolefination of aldehydes and ketones can be halogenated in situ to afford mono- and dihalofluoroalkyl compounds. The coupling reaction between iodofluoromethyl 2-pyridyl sulfone and aryl iodides mediated by copper can be used to prepare monofluoromethyl arenes and heteroarenes.

Chemical Properties

white solid

Reactions

(1) Dihalofluoromethylation of aldehydes and ketones.
(2) Halofluoroalkylation of aldehydes.

(3) Monofluoromethylation of arenes and heteroarenes.

References

[1] YANCHUAN ZHAO Jinbo H Bing Gao. From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds[J]. Journal of the American Chemical Society, 2012, 134 13: 5790-5793. DOI:10.1021/ja301601b.
[2] YANCHUAN ZHAO. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group[J]. Organic Letters, 2012, 14 23: 6080-6083. DOI:10.1021/ol3029737.

FluoroMethyl 2-pyridyl sulfone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from FluoroMethyl 2-pyridyl sulfone manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: FluoroMethyl 2-pyridyl sulfone 1365765-53-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

1365765-53-2, FluoroMethyl 2-pyridyl sulfoneRelated Search:

Difluoromethyl 2-pyridyl sulfone Difluoromethyl phenyl sulfone Fluoromethyl phenyl sulfone BroModifluoroMethyl phenyl sulfone

FluoroMethyl 2-pyridyl sulfone

2-[(Fluoromethyl)sulfonyl]-pyridine

Pyridine, 2-[(fluoromethyl)sulfonyl]-

FM-2-pyridyl sulfone

2-Pyridyl fluoromethyl sulfone

Pyridine, 2-[(fluoromethyl)sulfonyl]-2-fluoromethanesulfonylpyridine

1365765-53-2