ChemicalBook > CAS DataBase List > (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
Reaction- Product Name
- (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
- CAS No.
- 1037287-79-8
- Chemical Name
- (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
- Synonyms
- CamphorNHC-Mes;(5AR,6S,9S,9AS)-2-MESITYL-6,11,11-TRIMETHYL-5A,6,7,8,9,9A-HEXAHYDRO-4H-6,9-METHANOBENZO[B][1,2,4]TRIAZOLO[4,3-D][1,4]OXAZIN-2-IUM TETRAFLUOROBORATE;(5aS,6R,9S,9aR)-2-mesityl-6,11,11-trimethyl-5a,6,7,8,9,9a-hexahydro-4H-6,9-methanobenzo[b][1,2,4]triazolo[4,3-d][1,4]oxazin-2-ium tetrafluoroborate;(5aR,6S,9S,9aS)-2-Mesityl-6,11,11-trimethyl-5a,6,7,8,9,9a-hexahydro-4H-6,9-methanobenzo[b][1,2,4]triazolo[4,3-d][1,4]oxazin-2-ium Tetrafluoroborate,99%e.e.;(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
- CBNumber
- CB22710020
- Molecular Formula
- C22H30BF4N3O
- Formula Weight
- 439.31
- MOL File
- 1037287-79-8.mol
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(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate Property
- form
- Powder
- color
- white to off-white
- Stability:
- hygroscopic
- CAS DataBase Reference
- 1037287-79-8
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 07-0975
- Product name
- (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-trimethyl-2-(2,4,6-trimethylphenyl)-6,9-methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxazinium tetrafluoroborate
- Packaging
- 250mg
- Price
- $97
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 07-0975
- Product name
- (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-trimethyl-2-(2,4,6-trimethylphenyl)-6,9-methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxazinium tetrafluoroborate
- Packaging
- 1g
- Price
- $290
- Updated
- 2024/03/01
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(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate Chemical Properties,Usage,Production
Reaction
- Chiral ligand used in the diastereoselective and enantioselective desymmetrization of α-substituted cyclohexadienones via an intramolecular Stetter reaction.
- N-Heterocyclic, carbene-catalyzed, enantioselective intramolecular N-tethered aldehyde-ketone reactions.
- Desymmetrization of cyclohexadienones via intramolecular Stetter reaction to construct tricylic carbocycles.
(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
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(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate Suppliers
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1037287-79-8, (5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborateRelated Search:
DHIQ-NHC-C6F5
DHIQ-NHC-Ph
(11bS)-N-allyl-N-benzhydryl-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
INDEX NAME NOT YET ASSIGNED
(11bS)-N-Benzhydryl-N-cinnamyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine