METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE

Product Name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
CAS No.: 39503-52-1
Chemical Name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Synonyms: SALOR-INT L446718-1EA;METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE;5-bromo-2-hydroxy-4-methoxyBenzoic acid methyl ester;Benzoic acid, 5-bromo-2-hydroxy-4-methoxy-, methyl ester
CBNumber: CB2272375
Molecular Formula: C9H9BrO4
Formula Weight: 261.07
MOL File: 39503-52-1.mol

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METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE Property

Melting point:: 143 °C
Boiling point:: 328.9±37.0 °C(Predicted)
Density: 1.573±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 8.83±0.23(Predicted)
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: L446718
Product name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Purity: Aldrich
Packaging: 250mg
Price: $28.6
Updated: 2023/06/20

AK Scientific

Product number: 9347BA
Product name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Packaging: 5g
Price: $375
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0037018
Product name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

Ambeed

Product number: A316365
Product name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Purity: 95+%
Packaging: 100mg
Price: $18
Updated: 2021/12/16

Ambeed

Product number: A316365
Product name: METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE
Purity: 95+%
Packaging: 250mg
Price: $30
Updated: 2021/12/16

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METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE Chemical Properties,Usage,Production

Synthesis

98437-41-3

18107-18-1

39503-52-1

A) General procedure for synthesizing methyl 5-bromo-2-hydroxy-4-methoxybenzoate: to a solution of 5-bromo-2-hydroxy-4-methoxybenzoic acid (2.00 g) in methanol (10.0 mL) was slowly added a solution of 0.6 M (diazomethyl)trimethylsilane in hexanes (14.8 mL) under cooling conditions in an ice bath. The reaction mixture was stirred at room temperature for 3 hours. Upon completion of the reaction, acetic acid (0.12 mL) was added to quench the reaction, followed by evaporation of the solvent under reduced pressure. The resulting crude product was purified by silica gel column chromatography (eluent: ethyl acetate/hexane) to afford the target compound methyl 5-bromo-2-hydroxy-4-methoxybenzoate (2.08 g). The product was characterized by 1H NMR (300 MHz, CDCl3) with chemical shifts of δ3.91 (3H, s), 3.93 (3H, s), 6.49 (1H, s), 7.99 (1H, s), 10.93 (1H, s).

References

[1] Patent: WO2015/163485, 2015, A1. Location in patent: Paragraph 0342

METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE Suppliers

China 18 India 1 The Netherlands 1 United States 2 Global 22

Bide Pharmatech Ltd.

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Bide Pharmatech Ltd.

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39503-52-1, METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATERelated Search:

10-BROMO-2,2,6,6-TETRAMETHYL-2H-1,5,7-TRIOXA-PHENANTHREN-8-ONE 2,4-Dimethoxy-5-bromobenzoic acid methyl ester METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE RARECHEM AL BI 0813 METHYL 3,5-DIBROMO-2,4-DIMETHOXY-6-METHYLBENZOATE RARECHEM AL BF 0813 RARECHEM AL BI 0685

METHYL 5-BROMO-2-HYDROXY-4-METHOXYBENZOATE

SALOR-INT L446718-1EA

5-bromo-2-hydroxy-4-methoxyBenzoic acid methyl ester

Benzoic acid, 5-bromo-2-hydroxy-4-methoxy-, methyl ester

39503-52-1