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PMK ethyl glycidate

Product Name
PMK ethyl glycidate
CAS No.
28578-16-7
Chemical Name
PMK ethyl glycidate
Synonyms
GLYCIDATE;ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate;Pmk Glycidate Oil;3,4-MDP-2-P intermediate;ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate;2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester;cheap 3,4-MDP-2P ethyl ester;3-(1,3-benzodioxol-5-yl)-2-Methyl-;PMK BMK;New PMK
CBNumber
CB22731285
Molecular Formula
C13H14O5
Formula Weight
250.25
MOL File
28578-16-7.mol
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PMK ethyl glycidate Property

Boiling point:
327.8±42.0 °C(Predicted)
Density 
1.302±0.06 g/cm3(Predicted)
solubility 
DMF: 15 mg/ml; DMSO: 30 mg/ml; Ethanol: 10 mg/ml; PBS (pH 7.2): 1 mg/ml
InChI
InChI=1S/C13H14O5/c1-3-15-12(14)13(2)11(18-13)8-4-5-9-10(6-8)17-7-16-9/h4-6,11H,3,7H2,1-2H3
InChIKey
BRILFEZHPXQINW-UHFFFAOYSA-N
SMILES
O1C(C2=CC=C3OCOC3=C2)C1(C)C(OCC)=O
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Cayman Chemical
Product number
21990
Product name
PMK ethyl glycidate
Purity
≥98%
Packaging
1mg
Price
$73
Updated
2024/03/01
Cayman Chemical
Product number
21990
Product name
PMK ethyl glycidate
Purity
≥98%
Packaging
5mg
Price
$189
Updated
2024/03/01
TRC
Product number
N900275
Product name
NSC195099
Packaging
10mg
Price
$140
Updated
2021/12/16
AK Scientific
Product number
9011CB
Product name
Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate
Packaging
1mg
Price
$179
Updated
2021/12/16
AK Scientific
Product number
9011CB
Product name
Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate
Packaging
5mg
Price
$309
Updated
2021/12/16
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PMK ethyl glycidate Chemical Properties,Usage,Production

Description

PMK ethyl glycidate is an analytical reference standard categorized as a precursor in the synthesis of methylenedioxy phenethylamines and amphetamines, including 3,4-MDMA. This product is intended for research and forensic applications.

Uses

NSC 195099 can be used as an analytical reference standard.

Application

PMK methyl glycidate is applied as immediate precursors of 3,4-methylenedioxymethamphetamine. 

Synthesis

To a solution of piperonal (1, 3.00 g, 19.9 mmol) in CH2Cl2 (100 mL) was added (carbethoxyethylidene)triphenylphosphorane (2,14.5 g, 40.0 mmol), and the reaction mixture was stirred for 24 h at room temperature. The mixture was then concentrated at reduced pressure, and the residue was purified by flash column chromatography on silica gel (hexanes/EtOAc,10:1) to afford olefin 3 (4.45 g, 95%) as a colorless oil: 1H NMR (400 MHz, CDCl3) d 7.58 (s, 1H), 6.92 (d, J = 1.7 Hz, 1H), 6.90 (dd, J = 7.9, 1.7 Hz, 1H), 6.82 (d, J = 8.0 Hz, 1H), 5.97 (s, 2H), 4.24 (q, J = 7.1 Hz, 2H), 2.10 (d, J = 1.6 Hz, 3H),1.33 (t, J = 7.1 Hz, 3H); 13C NMR (100 MHz, CDCl3) d 168.7,147.6, 138.3, 129.9, 126.9, 124.6, 109.5, 108.2, 101.2,  60.7, 14.3,1 4.0; IR (ATR, cm-1): 2981, 2902,1698, 1628, 1502, 1489,1442, 1258, 1224; HRMS (EI) m/z calcd for C13H14O4 (M+) 234.0892, found 234.0895.
Fig The synthetic step of PMK ethyl glycidate

PMK ethyl glycidate Preparation Products And Raw materials

Raw materials

Preparation Products

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PMK ethyl glycidate Suppliers

China 110 United States 2 Global 112
Shanghai Worldyang Chemical Co.,Ltd.
Tel
021-021-56795766
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9352
Advantage
58
nanjing huayan chemical corp.
Tel
25-86661363 18951712139
Email
ruishi@hychemm.com
Country
China
ProdList
52
Advantage
58
Henan Vcommend Consultrading Co., Ltd.
Tel
13393721940
Email
sales@vcommend.com
Country
China
ProdList
9982
Advantage
58
Hebei mo Jin biotechnology co., ltd
Tel
15097329902; 15097329902
Fax
18503279000
Email
sales@hebeimojin.com
Country
China
ProdList
2234
Advantage
58
Chizhou Kailong Import and Export Trade Co., Ltd.
Tel
Fax
-
Email
xg01_gj@163.com
Country
China
ProdList
9503
Advantage
50
Hangzhou Dingyan Chem Co., LTD
Tel
0571-87157530-8002 15267169049
Fax
0571-87156470
Email
sales@dingyanchem.com
Country
China
ProdList
1997
Advantage
58
Shanghai Hongye Biotechnology Co. Ltd
Tel
400-9205774
Email
sales@glpbio.cn
Country
China
ProdList
6870
Advantage
58
ANHUI WITOP BIOTECH CO., LTD
Tel
+8615255079626
Email
eric@witopchemical.com
Country
China
ProdList
23556
Advantage
58
Hong Kong Excellence Biotechnology Co., Ltd.
Tel
+86-86-18838029171 +8618126314766
Fax
wickrme：chemical888
Email
ada@sh-teruiop.com
Country
China
ProdList
889
Advantage
58
Henan Alfa Chemical Co., Ltd
Tel
+8618339805032
Email
alfa4@alfachem.cn
Country
China
ProdList
13037
Advantage
58
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View Lastest Price from PMK ethyl glycidate manufacturers

Dorne Chemical Technology co. LTD
Product
PMK ethyl glycidate/PMK Powder PMK Oil 28578-16-7
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-03-26
Dorne Chemical Technology co. LTD
Product
3,4-MDP-2-P intermediate 28578-16-7
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-03-26
Nanjing Deda New Material Technology Co., Ltd
Product
PMK ethyl glycidate 28578-16-7
Price
US $5.00-3.00/kg
Min. Order
1kg
Purity
99.8%
Supply Ability
20tons
Release date
2024-04-17

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