ChemicalBook > CAS DataBase List > Methyl 4-bromo-2-chloro-6-fluorobenzoate
Methyl 4-bromo-2-chloro-6-fluorobenzoate
- Product Name
- Methyl 4-bromo-2-chloro-6-fluorobenzoate
- CAS No.
- 1321613-02-8
- Chemical Name
- Methyl 4-bromo-2-chloro-6-fluorobenzoate
- Synonyms
- Methyl 4-bromo-6-chloro-2-fluorobenzoate;Methyl 4-bromo-2-chloro-6-fluorobenzoate;4-bromo-2-chloro-6-fluorobenzoic acid methyl ester;Benzoic acid, 4-bromo-2-chloro-6-fluoro-, methyl ester
- CBNumber
- CB22738406
- Molecular Formula
- C8H5BrClFO2
- Formula Weight
- 267.48
- MOL File
- 1321613-02-8.mol
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Methyl 4-bromo-2-chloro-6-fluorobenzoate Property
- Boiling point:
- 299.4±40.0 °C(Predicted)
- Density
- 1.675±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- Appearance
- Colorless to light yellow Liquid
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Safety
- HS Code
- 2916399090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
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N-Bromosuccinimide Price
TRC
- Product number
- M221970
- Product name
- Methyl4-Bromo-2-Chloro-6-Fluorobenzoate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
AK Scientific
- Product number
- X3649
- Product name
- Methyl4-bromo-2-chloro-6-fluorobenzoate
- Packaging
- 100mg
- Price
- $96
- Updated
- 2021/12/16
AK Scientific
- Product number
- X3649
- Product name
- Methyl4-bromo-2-chloro-6-fluorobenzoate
- Packaging
- 250mg
- Price
- $111
- Updated
- 2021/12/16
SynQuest Laboratories
- Product number
- 2623-F-02
- Product name
- Methyl 4-bromo-2-chloro-6-fluorobenzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $114
- Updated
- 2021/12/16
AK Scientific
- Product number
- X3649
- Product name
- Methyl4-bromo-2-chloro-6-fluorobenzoate
- Packaging
- 10g
- Price
- $911
- Updated
- 2021/12/16
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Methyl 4-bromo-2-chloro-6-fluorobenzoate Chemical Properties,Usage,Production
Synthesis
1321613-01-7
74-88-4
1321613-02-8
Procedure for the synthesis of methyl 4-bromo-2-chloro-6-fluorobenzoate: to a mixture of compound 4-bromo-2-chloro-6-fluorobenzoic acid (20 g, 80 mmol) and potassium carbonate (13.2 g, 96 mmol) in N,N-dimethylformamide (200 mL) was added methylene iodide (23 g, 160 mmol). The reaction mixture was stirred at room temperature for 2 hours and subsequently poured into water (600 mL) and extracted with dichloromethane (2 x 200 mL). The organic layers were combined, washed sequentially with water and brine, dried over anhydrous sodium sulfate and concentrated under reduced pressure to give a brown oil. Purification by silica gel column chromatography (petroleum ether: ethyl acetate = 100:1) gave the target product methyl 4-bromo-2-chloro-6-fluorobenzoate (8 g, 49% yield, two-step reaction) as a light yellow oil.
References
[1] Patent: US2012/28952, 2012, A1. Location in patent: Page/Page column 17
Methyl 4-bromo-2-chloro-6-fluorobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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