ChemicalBook > CAS DataBase List > 2-(2'-BROMOPHENOXY)PROPANE

2-(2'-BROMOPHENOXY)PROPANE

Product Name
2-(2'-BROMOPHENOXY)PROPANE
CAS No.
701-07-5
Chemical Name
2-(2'-BROMOPHENOXY)PROPANE
Synonyms
Bedaquiline Impurity 99;2-BROMOISOPROPOXYBENZENE;O-BROMOISOPROPOXYBENZENE;2-(2'-BROMOPHENOXY)PROPANE;1-Bromo-2-isopropoxybenzen;1-Bromo-2-isopropoxybenzene;1-bromo-2-propan-2-yloxybenzene;1-Bromo-2-isopropoxybenzene >Benzene, 1-bromo-2-(1-methylethoxy)-;B-9,9 '- spirodifluorene-2' - ylboronic acid
CBNumber
CB2280864
Molecular Formula
C9H11BrO
Formula Weight
215.09
MOL File
701-07-5.mol
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2-(2'-BROMOPHENOXY)PROPANE Property

Boiling point:
73 °C / 2mmHg
Density 
1.34
refractive index 
1.5360-1.5400
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Light yellow
Water Solubility 
Slightly soluble in water.
CAS DataBase Reference
701-07-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2909309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3100
Product name
1-Bromo-2-isopropoxybenzene
Purity
>97.0%(GC)
Packaging
5g
Price
$57
Updated
2025/07/31
TCI Chemical
Product number
B3100
Product name
1-Bromo-2-isopropoxybenzene
Purity
>97.0%(GC)
Packaging
25g
Price
$226
Updated
2025/07/31
TRC
Product number
B700738
Product name
2-(2''-Bromophenoxy)propane
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
B700738
Product name
2-(2''-Bromophenoxy)propane
Packaging
500mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
Y6589
Product name
1-Bromo-2-isopropoxybenzene
Packaging
1g
Price
$14
Updated
2021/12/16
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2-(2'-BROMOPHENOXY)PROPANE Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

1-Bromo-2-isopropoxybenzene is used as an intermediate in organic syntheses.

Synthesis

95-56-7

75-26-3

701-07-5

General procedure for the synthesis of 1-bromo-2-isopropoxybenzene from 2-bromophenol and 2-bromopropane: A mixture of 2-bromophenol (1.156 mmol), anhydrous K2CO3 (1.20 eq., 192 mg), sodium iodide (4 mg), and anhydrous ethanol (3 mL) was magnetically stirred at room temperature under argon protection. 2-Bromopropane (1.20 eq.) was added slowly and the mixture was then refluxed for 5 hours. After the reaction was complete, it was cooled to room temperature and the solvent was removed under reduced pressure. Ethyl acetate (50 mL) was added to dissolve the residue and the organic phase was washed sequentially with 1M NaOH and brine (15 mL each). The organic phase was dried with anhydrous Na2SO4 and the solvent was evaporated under reduced pressure to obtain the crude product. Finally, the crude product was purified by fast column chromatography.

References

[1] Journal of Organic Chemistry, 2000, vol. 65, # 26, p. 9143 - 9151
[2] Journal of Medicinal Chemistry, 1998, vol. 41, # 12, p. 1997 - 2009
[3] Organic Preparations and Procedures International, 2015, vol. 47, # 3, p. 227 - 231
[4] Patent: WO2009/55674, 2009, A1. Location in patent: Page/Page column 59
[5] Journal of Medicinal Chemistry, 2012, vol. 55, # 9, p. 4189 - 4204

2-(2'-BROMOPHENOXY)PROPANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(2'-BROMOPHENOXY)PROPANE manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-(2'-BROMOPHENOXY)PROPANE 701-07-5
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Career Henan Chemical Co
Product
1-Bromo-2-isopropoxybenzene 701-07-5
Price
US $8.00/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
kg--ton
Release date
2020-03-08

701-07-5, 2-(2'-BROMOPHENOXY)PROPANERelated Search:

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  • 1-bromo-2-propan-2-yloxybenzene
  • 1-Bromo-2-isopropoxybenzen
  • 2-BROMOISOPROPOXYBENZENE
  • 2-(2'-BROMOPHENOXY)PROPANE
  • O-BROMOISOPROPOXYBENZENE
  • 1-Bromo-2-isopropoxybenzene
  • 1-Bromo-2-isopropoxybenzene &gt
  • Benzene, 1-bromo-2-(1-methylethoxy)-
  • B-9,9 '- spirodifluorene-2' - ylboronic acid
  • Bedaquiline Impurity 99
  • 701-07-5
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds