ChemicalBook > CAS DataBase List > TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE

TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE

Product Name
TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE
CAS No.
14275-61-7
Chemical Name
TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE
Synonyms
SKL980;bisbutylstannylethylene;-1,2-Bis(tributylstannyl);2-Bis(tributylstannyl)ethene;1,2-bis(tributylstannyl)ethene;(E)-1,2-Bis(tributyltin)ethylene;(E)-1,2-Bis(tributylstannyl)ethene;(E)-1,2-Bis(tributylstannyl)ethylene;trans-1,2-Bis(tributylstannyl)ethene;Trans-1,2-bis (tributyltin) ethylene
CBNumber
CB2303572
Molecular Formula
C26H56Sn2
Formula Weight
606.14
MOL File
14275-61-7.mol
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TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Property

Melting point:
180-182℃
Boiling point:
185°C 0,01mm
Density 
1,15 g/cm3
refractive index 
1.5030
Flash point:
185°C/0.01mm
storage temp. 
Inert atmosphere,2-8°C
solubility 
sol THF, DMF
form 
liquid
color 
Orange
Specific Gravity
1.150
Water Solubility 
Miscible with terahydrofuran and dimethyl formamide. Slightly miscible with water.
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3613803
InChIKey
VNKOWRBFAJTPLS-UHFFFAOYSA-N
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Safety

Hazard Codes 
T,N
Risk Statements 
21-25-36/38-48/23/25-50/53
Safety Statements 
36/37/39-45-61-60
RIDADR 
2788
WGK Germany 
3
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29312000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
731625
Product name
trans-1,2-Bis(tributylstannyl)ethene
Purity
97%
Packaging
1g
Price
$76.4
Updated
2024/03/01
Sigma-Aldrich
Product number
731625
Product name
trans-1,2-Bis(tributylstannyl)ethene
Purity
97%
Packaging
5g
Price
$304
Updated
2024/03/01
Alfa Aesar
Product number
L20130
Product name
trans-1,2-Bis(tri-n-butylstannyl)ethylene
Purity
96%
Packaging
1g
Price
$129
Updated
2023/06/20
Alfa Aesar
Product number
L20130
Product name
trans-1,2-Bis(tri-n-butylstannyl)ethylene
Purity
96%
Packaging
5g
Price
$534
Updated
2023/06/20
Matrix Scientific
Product number
069567
Product name
trans-1,2-Bis(tributylstannyl)ethene
Purity
90%
Packaging
25g
Price
$1378
Updated
2021/12/16
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TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Chemical Properties,Usage,Production

Chemical Properties

colorless to slightly yellow liquid

Uses

trans-1,2-Bis(tri-n-butylstannyl)ethylene can be used in versatile vinyl anion synthon: efficiently monotransmetalated by alkyllithium reagents and higher order organocuprates; palladium-catalyzed coupling with a variety of electrophilic partners affords substituted vinylstannanes.

Preparation

TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE is prepared in high yield by the reductive hydrostannation of tributylstannylacetylene with Tri-n-butylstannane and catalytic Azobisisobutyronitrile.

Preparation

TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE can be purified by distillation or by preparative reverse-phase chromatography.

TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Suppliers

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View Lastest Price from TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE 14275-61-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-18
Hebei Mojin Biotechnology Co., Ltd
Product
TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE 14275-61-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-26
Honest Joy Holdings Limited
Product
Trans-1,2-bis(tri-n-butylstannyl)ethylene 14275-61-7
Price
US $0.00/KG
Min. Order
1KG
Purity
98.2%
Supply Ability
100 tons
Release date
2022-01-26

14275-61-7, TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENERelated Search:

TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE [(1E)-1,2-DIFLUORO-1,2-ETHENEDIYL]BISTRIBUTYLSTANNANE Tributyl(vinyl)tin

  • (E)-1,2-Bis(tributylstannyl)ethene
  • (E)-1,2-Ethenediylbis(tributylstannane)
  • [(E)-1,2-Ethenediyl]bis(tributylstannane)
  • trans-1,2-Bis(tri-n-butylstannyl)ethylene,95%
  • 2-Bis(tributylstannyl)ethene
  • trans-1,2-Bis(tributylstannyl)ethene
  • BIS(TRI-n-BUTYLSTANNYL)ETHYLENE, trans isomer
  • (E)-1,2-Bis(tributylstannyl)ethylene
  • (E)-1,2-Bis(tributyltin)ethylene
  • TRANS-1,2-BIS(TRIBUTYLSTANNYL)ETHYLENE
  • TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE
  • TRANS-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE
  • bisbutylstannylethylene
  • -1,2-Bis(tributylstannyl)
  • Trans-1,2-bis (tributyltin) ethylene
  • Stannane, 1,1'-(1E)-1,2-ethenediylbis[1,1,1-tributyl-
  • 1,2-bis(tributylstannyl)ethene
  • TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE ISO 9001：2015 REACH
  • SKL980
  • 1,1'-(1E)-1,2-Ethenediylbis[1,1,1-tributylstannane
  • Trans-1,2-bis (tri-n-butyltin) ethylene
  • 1,1'-(1E)-1,2-Ethenediylbis[1,1,1-tributylstannane
  • 14275-61-7
  • C26H56Sn2
  • Classes of Metal Compounds
  • Typical Metal Compounds
  • Sn (Tin) Compounds
  • Stannanes
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Typical Metal Compounds