Physical Properties Uses Preparation Reactions
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Hexaammonium molybdate

Physical Properties Uses Preparation Reactions
Product Name
Hexaammonium molybdate
CAS No.
12027-67-7
Chemical Name
Hexaammonium molybdate
Synonyms
AMMONIUM HEPTAMOLYBDATE;Ammonium molybdate (para) hydrate;ammonium heptamolybdrate;hexaammonium heptamolybdate;PHOSPHATE MONITOR FIRST REAGENT;ammoniummolybdate((nh4)6(mo7o24));NPW-150 AMMONIUM MOLYBDATE MIXTURE;PHOSPHATE MONITOR REDUCTION REAGENT;PHOSPHATE MONITOR REDUCTION SOLUTION;ammonium molybdate (para) hydrate, puratronic
CBNumber
CB2309998
Molecular Formula
H4Mo7NO24(-5)
Formula Weight
1073.67
MOL File
12027-67-7.mol
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Hexaammonium molybdate Property

Melting point:
190°C
Density 
2,498 g/cm3
storage temp. 
Store at RT.
solubility 
H2O: soluble
form 
Liquid
Specific Gravity
2.498
color 
Clear light colored
Water Solubility 
Freely soluble in water.
Merck 
14,533
Exposure limits
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 1000 mg/m3
Stability:
Stable.
CAS DataBase Reference
12027-67-7(CAS DataBase Reference)
EPA Substance Registry System
Molybdate (Mo7O246-), ammonium (1:6) (12027-67-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
22-36/38-52/53-36/37/38
Safety Statements 
26-36
RIDADR 
UN 3264
WGK Germany 
-
RTECS 
QA4900000
TSCA 
Yes
HS Code 
28417010
Hazardous Substances Data
12027-67-7(Hazardous Substances Data)
Toxicity
mic-esc 2 mmol/L MUREAV 31,185,1975
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
010811
Product name
Ammonium molybdate (para) hydrate, Puratronic?, 99.999% (metals basis excluding W), W 300ppm max
Packaging
5g
Price
$44.6
Updated
2021/12/16
Alfa Aesar
Product number
010811
Product name
Ammonium molybdate (para) hydrate, Puratronic?, 99.999% (metals basis excluding W), W 300ppm max
Packaging
25g
Price
$152
Updated
2021/12/16
Strem Chemicals
Product number
02-0745
Product name
Ammonium molybdate tetrahydrate (99.98%-Mo)
Packaging
100g
Price
$29
Updated
2021/12/16
Strem Chemicals
Product number
02-0745
Product name
Ammonium molybdate tetrahydrate (99.98%-Mo)
Packaging
500g
Price
$97
Updated
2021/12/16
Strem Chemicals
Product number
93-0245
Product name
Ammonium molybdate tetrahydrate (ACS)
Packaging
500g
Price
$97
Updated
2021/12/16
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Hexaammonium molybdate Chemical Properties,Usage,Production

Physical Properties

Colorless, monoclinic crystal; density 2.276 g/cm3; decomposes on heating; soluble in water (decomposes); also soluble in acid; insoluble in alcohol and liquid ammonia.

Uses

Ammonium molybdates are used to prepare high purity grade molybdenum metal powder, sheet, or wire; for colorimetric analysis of phosphates and arsenates; for decorating ceramics; and as catalysts.

Preparation

Ammonium molybdate is prepared by treating molybdenum oxide with excess ammonia in an aqueous solution. The crystals are obtained after evaporation of water.
MoO3 + 2NH3 + H2O → (NH4)2MoO4

Reactions

Decomposes on heating or on treatment with alkalies; reacts with lead chloride and other metal salts to form their metal molybdates:
(NH4)2MoO4 + PbCl2 → PbMoO4 + 2NH4Cl
Reacts with phosphates or arsenates to form ammonium phosphomolybdate (NH4)3PO4•12MoO3, or ammonium arsenomolybdate, (NH4)3AsO4•12MoO3.

Chemical Properties

Ammonium heptamolybdate is an odourless crystalline compound ranging in colour from white to yellow-green. It is usually encoutered as the tetrahydrate, whose chemical formula is (NH4)6Mo7O24·4H2O. It is often referred to simply as ammonium molybdate, although this name can also refer to ammonium orthomolybdate, (NH4)2MoO4, and several other species.

General Description

White to greenish-yellow solid. Sinks and mixes with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Salts, basic, such as Hexaammonium molybdate , are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Health Hazard

Inhalation causes irritation of nose and throat. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire.

Flammability and Explosibility

Not classified

Agricultural Uses

Ammonium molybdate, (NH4)6MO7O24·2H2O is an important molybdenum fertilizer. It is an ammonium salt of molybdic acid and contains about 50% molybdenum.
Ammonium molybdate is generally mixed with NPK fertilizers, depending on the crop requirement (generally 50 to l000 gm per ha). The fertilizer is also applied as a foliar spray, but coating or soaking seeds with ammonium molybdate is the easiest method of application, which requires very little fertilizer.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits toxic vapors of Mo andNH3.

Hexaammonium molybdate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Hexaammonium molybdate manufacturers

Shaanxi Haibo Biotechnology Co., Ltd
Product
Hexaammonium molybdate 12027-67-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000kg/Mouth
Release date
2023-09-07
Shaanxi Haibo Biotechnology Co., Ltd
Product
Hexaammonium molybdate 12027-67-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000ton
Release date
2023-09-08
Hebei Dongdu Import and Export Co. LTD
Product
hexaammonium molybdate 12027-67-7
Price
US $15.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000ton
Release date
2023-12-20

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