2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine

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Product Name: 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
CAS No.: 1660153-91-2
Chemical Name: 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
Synonyms: 2;2-(t-ButyL;98% (t-Bu)PhCPhos;phosphino)-2',6'-dimethyL;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl;2-Tert-butyl(phenyl)phosphine-2',6'-dimethylamine-1,1'-biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl,98%;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98%;2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, (t-Bu)PhCPhos
CBNumber: CB23140277
Molecular Formula: C26H33N2P
Formula Weight: 404.53
MOL File: 1660153-91-2.mol

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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Property

Melting point:: 112 °C
Boiling point:: 537.6±50.0 °C(Predicted)
pka: 5.00±0.28(Predicted)
form: Powder
color: white to off-white
InChI: InChI=1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3
InChIKey: HTHOMNNVAUPLKK-UHFFFAOYSA-N
SMILES: C1(C2=CC=CC=C2P(C(C)(C)C)C2=CC=CC=C2)=C(N(C)C)C=CC=C1N(C)C

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 900275
Product name: (t-Bu)PhCPhos
Purity: 95%
Packaging: 250mg
Price: $203
Updated: 2024/03/01

Sigma-Aldrich

Product number: 900275
Product name: (t-Bu)PhCPhos
Purity: 95%
Packaging: 1g
Price: $573
Updated: 2024/03/01

Strem Chemicals

Product number: 15-3010
Product name: 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging: 250mg
Price: $108
Updated: 2024/03/01

Strem Chemicals

Product number: 15-3010
Product name: 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging: 1g
Price: $323
Updated: 2024/03/01

Strem Chemicals

Product number: 15-3010
Product name: 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging: 5g
Price: $1293
Updated: 2024/03/01

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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Chemical Properties,Usage,Production

Reactions

Ligand for the Palladium-catalyzed Buchwald-Hartwig cross-coupling of hindered primary amines and aryl halides.

Uses

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Suppliers

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View Lastest Price from 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (t-Bu)PhCPhos 1660153-91-2
Price: US $0.00-0.00/g
Min. Order: 100g
Purity: 98%
Supply Ability: 15KG
Release date: 2024-05-06

1660153-91-2, 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamineRelated Search:

2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine

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2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl

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2

1660153-91-2

C26H33N2P

Achiral Phosphine

Aryl Phosphine

Buchwald Ligands Series

Buchwald Ligands&Precatalysts