ChemicalBook > CAS DataBase List > COBALTOCENE HEXAFLUOROPHOSPHATE
COBALTOCENE HEXAFLUOROPHOSPHATE
- Product Name
- COBALTOCENE HEXAFLUOROPHOSPHATE
- CAS No.
- 12427-42-8
- Chemical Name
- COBALTOCENE HEXAFLUOROPHOSPHATE
- Synonyms
- COBALTOCENE HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III);COBALTOCENIUM HEXAFLUOROPHOSPHATE;COBALTICINIUM HEXAFLUOROPHOSPHATE;Cobalticiniumhexafluorophosphate,98%;Cobaltocenium hexafluorophosphate,98%;cobaltocenium hexafluorophosphate(1-);Dicyclopentadienylcobalt hexafluorophosphate;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE;Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
- CBNumber
- CB2314446
- Molecular Formula
- C10H10CoF6P10*
- Formula Weight
- 334.08
- MOL File
- 12427-42-8.mol
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COBALTOCENE HEXAFLUOROPHOSPHATE Property
- solubility
- slightly sol. in Dimethylformamide
- form
- crystal
- color
- yellow
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- HS Code
- 2931.90.9051
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 279811
- Product name
- Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate
- Purity
- 98%
- Packaging
- 1g
- Price
- $67.3
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1589
- Product name
- Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate
- Purity
- >96.0%(T)
- Packaging
- 1g
- Price
- $207
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 27-0410
- Product name
- Cobalticinium hexafluorophosphate, 98%
- Packaging
- 1g
- Price
- $76
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 27-0410
- Product name
- Cobalticinium hexafluorophosphate, 98%
- Packaging
- 5g
- Price
- $303
- Updated
- 2024/03/01
TRC
- Product number
- B424105
- Product name
- Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
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COBALTOCENE HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production
Chemical Properties
yellow powder
Uses
Uses:
- Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
- Reactant for modification of organometallic electrodes surfaces through cathodic reduction
- Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers
Synthesis Reference(s)
[1](a) Gmelin, Handbuch der Anorganischen Chemie, 8th ed; Verlag Chemie: Weinheim, 1973; Supplement, Vol. 5, part 1. (b) Sheats, J. E. JOM Libr. 1979, 7, 461.
Synthesis
Cobaltocene hexafluorophosphate is readily synthesized from cobalt(II) salts + CpNa, followed by air + HPF6 or NH4PF6. Salts with a wide range of other counterions may be obtained similarly. The cobaltocenium ion[1] may be precipitated from aqueous solution by a variety of large anions. In addition to PF6 -, convenient counterions include Br3 - and I3 -. The simple halides are hygroscopic, but may be obtained in anhydrous form by removal of water under vacuum.
Precautions
COBALTOCENE HEXAFLUOROPHOSPHATE is very stable; irritant.
COBALTOCENE HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
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COBALTOCENE HEXAFLUOROPHOSPHATE Suppliers
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