Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

Reaction

Product Name: Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
CAS No.: 27057-09-6
Chemical Name: Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Synonyms: Bis(triphenylphosphino)(2-methylphenyl)chloronickel;Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II);BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%;Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride;Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%;2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide
CBNumber: CB23151060
Molecular Formula: C43H39ClNiP2
Formula Weight: 711.88
MOL File: 27057-09-6.mol

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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Property

Melting point:: 195-200°C
storage temp.: 2-8°C
form: Powder
color: yellow
CAS DataBase Reference: 27057-09-6

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 794279
Product name: Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Packaging: 250mg
Price: $81.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 794279
Product name: Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Packaging: 1g
Price: $358
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0096
Product name: Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%
Packaging: 250mg
Price: $117
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0096
Product name: Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%
Packaging: 1g
Price: $352
Updated: 2024/03/01

Arctom

Product number: AS591439
Product name: Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)
Purity: 98%
Packaging: 1g
Price: $160
Updated: 2021/12/16

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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Chemical Properties,Usage,Production

Reaction

This complex is used as an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.
This nickel precatalyst is used for the polymerization of halothiophenes.

Uses

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Suppliers

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27057-09-6, Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)Related Search:

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%

Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%

2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide

Bis(triphenylphosphino)(2-methylphenyl)chloronickel

Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride

27057-09-6

C43H37ClNiP2