ChemicalBook > CAS DataBase List > 1,2-Dibromo-4-fluorobenzene

1,2-Dibromo-4-fluorobenzene

Product Name
1,2-Dibromo-4-fluorobenzene
CAS No.
2369-37-1
Chemical Name
1,2-Dibromo-4-fluorobenzene
Synonyms
3,4-DIBROMOFLUOROBENZENE;1,2-Dibromo-4-fluorobezene;3,4-Dibromo-1-fluorobenzene;1,2-DIBROMO-4-FLUOROBENZENE;Benzene, 1,2-dibromo-4-fluoro-;1,2-Dibromo-4-fluorobenzene>1,2-Dibromo-4-fluorobenzene99%;1,2-Dibromo-4-fluorobenzene 99%;1,2-Dibromo-4-fluorobenzene,98%;1,2-DibroMo-4-fluorobenzene[3,4-DibroMofluorobenzene]
CBNumber
CB2316804
Molecular Formula
C6H3Br2F
Formula Weight
253.89
MOL File
2369-37-1.mol
More
Less

1,2-Dibromo-4-fluorobenzene Property

Melting point:
69℃
Boiling point:
220℃
Density 
2.014
refractive index 
1.5780-1.5820
Flash point:
87℃
form 
clear liquid
color 
Colorless to Light yellow
CAS DataBase Reference
2369-37-1(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
2903998090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
D2854
Product name
1,2-Dibromo-4-fluorobenzene
Purity
>98.0%(GC)
Packaging
5g
Price
$39
Updated
2024/03/01
TCI Chemical
Product number
D2854
Product name
1,2-Dibromo-4-fluorobenzene
Purity
>98.0%(GC)
Packaging
25g
Price
$153
Updated
2024/03/01
Alfa Aesar
Product number
B20935
Product name
1,2-Dibromo-4-fluorobenzene, 98%
Packaging
2.5g
Price
$28.65
Updated
2024/03/01
Alfa Aesar
Product number
B20935
Product name
1,2-Dibromo-4-fluorobenzene, 98%
Packaging
10g
Price
$98.65
Updated
2024/03/01
TRC
Product number
D425673
Product name
1,2-Dibromo-4-fluorobenzene
Packaging
2.5g
Price
$65
Updated
2021/12/16
More
Less

1,2-Dibromo-4-fluorobenzene Chemical Properties,Usage,Production

Reactivity Profile

The Suzuki–Miyaura reaction of 1,2- dibromo-4-fluorobenzene with two equivalents of arylboronic acids 2a–d, i,v afforded the fluorinated terphenyls 15a–f in moderate to good yields. The best yields were obtained using 2.2 equivalents of the aryl boronic acid, Pd(PPh3)4 (0.03 equiv) as the catalyst, and Cs2CO3 (2.2 equiv) as the base (1,4-dioxane, 90 8C, 8 h). The low site-selectivity in the case of 1,2-dibromo-4-fluorobenzene (13) can be explained by the fact that the positions 1 and 2, located meta and para to the fluorine atom, are sterically and electronically very similar[1].

References

[1] Muhammad Sharif . “Synthesis of functionalized fluorinated terphenyls by site-selective Suzuki–Miyaura cross-coupling reactions of dibrominated fluorobenzenes.” Journal of Fluorine Chemistry 146 (2013): Pages 19-36.

1,2-Dibromo-4-fluorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1,2-Dibromo-4-fluorobenzene Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Aceschem Inc.
Tel
+1-817863-6948 +1-(817)863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
Advantage
58
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
AOBChem USA
Tel
--
Fax
--
Email
sales@aobchem.com
Country
United States
ProdList
3487
Advantage
50
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
INDOFINE Chemical Company, Inc.
Tel
--
Fax
--
Email
chemical@indofinechemical.com
Country
United States
ProdList
6176
Advantage
69
2A PharmaChem USA
Tel
--
Fax
--
Email
sales@2apharmachem.com
Country
United States
ProdList
6137
Advantage
39
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Esprit Chemical Company
Tel
--
Fax
--
Email
admin@esprixtech.com
Country
United States
ProdList
1616
Advantage
55
More
Less

View Lastest Price from 1,2-Dibromo-4-fluorobenzene manufacturers

Henan Fengda Chemical Co., Ltd
Product
1,2-DIBROMO-4-FLUOROBENZENE 2369-37-1
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Career Henan Chemical Co
Product
1,2-DIBROMO-4-FLUOROBENZENE 2369-37-1
Price
US $1.00/KG
Min. Order
1KG
Purity
97-99%
Supply Ability
1000KGS
Release date
2019-12-18