ChemicalBook > CAS DataBase List > (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

Product Name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
CAS No.
174467-31-3
Chemical Name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Synonyms
]-2,2'-bis(diphenyL;(SP,S'P)-1,1'-Bis[(R)-aL; (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe;(SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene;(2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene;(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene;(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
CBNumber
CB23357015
Molecular Formula
C52H48FeN2P2
Formula Weight
818.76
MOL File
174467-31-3.mol
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Property

alpha 
-320.0° (c 1.0, CHCl3)
form 
solid
color 
orange-red
Stability:
store cold
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0252
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-0252
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-0252
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
26-0252
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
Packaging
10g
Price
$4824
Updated
2024/03/01
Ambeed
Product number
A1158824
Product name
(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Purity
98%
Packaging
250mg
Price
$158
Updated
2021/12/16
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Chemical Properties,Usage,Production

Uses

Chlorotricarbonyl(4,4'-di-t-butyl-2,2'-bipyridine)rhenium(I) is used for the reduction of carbon dioxide as a catalyst.

Reactions

  1. Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate.
  2. Ligand used for the gold-catalyzed phenol synthesis from furyldialkyne.
  3. Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [( 6 -benzylamine)Cr(CO)3]
  4. Ligand used for the palladium-catalyzed asymmetric synthesis of α-allyl-α-aryl α-amino acids by tandem alkylation/π-allylation of α-iminoesters

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Suppliers

China 20 United States 3 Global 23
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52927
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4911
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6825
Advantage
87

174467-31-3, (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferroceneRelated Search:

(S)-1-{(R)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (S)-1-{(R)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLBIS(2-METHYLPHENYL)PHOSPHINE (R)-1-{(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLDI(3,5 (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT (R)-1-[(S)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE (R)-1-{(S)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLBIS(2-METHYLPHENYL)PHOSPHINE (S)-1-[(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLDI(3,5 (AS,AS)-1,1#-BIS[<ALPHA>-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2#-BIS(DIPHENYLPHOSPHINO

  • (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene
  • (2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE
  • (SP,S'P)-1,1'-Bis[(R)-aL
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe
  • (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
  • ]-2,2'-bis(diphenyL
  • (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
  • (S,S)Fc-1,1’- Bis(diphenylphosphino)-2,2'- bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]fer rocene
  • (SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene
  • (1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene
  • (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene
  • (S,S)-(-)-2,2''-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1''-bis(diphenylphosphino)ferrocene
  • (Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
  • (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
  • 174467-31-3