Uses
ChemicalBook > CAS DataBase List > Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)

Uses
Product Name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
CAS No.
2049086-37-3
Chemical Name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
Synonyms
SK-J014-1n;)[(R)-1-[(S)-2-[bis(4-fL;CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(BIS(4-FLUOROPHENYL)PHOSPHINOFERROCENYL]ETHYL(DI-T-BUTYLPHOSPHINE)}NICKEL(II);Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II);Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) >=95%;Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)
CBNumber
CB23357075
Molecular Formula
C39H37ClF2FeNNiP2
Formula Weight
769.66
MOL File
2049086-37-3.mol
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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Property

form 
solid
color 
red-violet
CAS DataBase Reference
2049086-37-3
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Safety

RIDADR 
UN 3175 4.1 / PGII
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900941
Product name
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)
Purity
≥95%
Packaging
250mg
Price
$245
Updated
2025/07/31
Strem Chemicals
Product number
28-0178
Product name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
28-0178
Product name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
Packaging
500mg
Price
$355
Updated
2024/03/01
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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Chemical Properties,Usage,Production

Uses

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) is used for:
1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions.
2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines.
3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions.
4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.

Uses

Amination of functionalized aryl chlorides with ammonia and ammonium salts.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Suppliers

Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
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Sigma-Aldrich
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021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
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51395
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Tianjin Kailiqi Biotechnology Co., Ltd.
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15076683720
Fax
022-23754520
Email
klq@cw-bio.com
Country
China
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8011
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55
Career Henan Chemica Co
Tel
+86-0371-86658258 +8613203830695
Fax
0371-86658258
Email
laboratory@coreychem.com
Country
China
ProdList
30229
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Energy Chemical
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021-58432009 400-005-6266
Fax
021-58436166
Email
marketing@energy-chemical.com
Country
China
ProdList
44918
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Beijing Jin Ming Biotechnology Co., Ltd.
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010-60605840 15801484223;
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psaitong@jm-bio.com
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China
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29757
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Shanghai Aladdin Biochemical Technology Co.,Ltd.
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400-6206333 13167063860
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anhua.mao@aladdin-e.com
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China
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48457
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Shaanxi Istare Biotechnology Co., Ltd.
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18682931470; 18682931470
Email
2142355700@qq.com
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China
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4723
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Taizhou Chuanxu Pharmaceutical Technology Co., Ltd.
Tel
13000000000
Email
974144639@qq.com
Country
China
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9979
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Merck KGaA
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21-20338288
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ordercn@merckgroup.com
Country
China
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Shanghai Hao Zhun Biological Technology Co., Ltd.
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Email
info@zzsrm.com
Country
CHINA
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6650
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2049086-37-3, Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)Related Search:


  • CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(BIS(4-FLUOROPHENYL)PHOSPHINOFERROCENYL]ETHYL(DI-T-BUTYLPHOSPHINE)}NICKEL(II)
  • Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) >=95%
  • Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)
  • )[(R)-1-[(S)-2-[bis(4-fL
  • Chloro(4-cyanophenyl)[(<i>R</i>)-1-[(<i>S</i>)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-<i>tert</i>-butylphosphine]nickel(II)
  • SK-J014-1n
  • 2049086-37-3
  • C39H42ClF2FeNNiP2