Reaction
ChemicalBook > CAS DataBase List > AdBrettPhos Pd G3

AdBrettPhos Pd G3

Reaction
Product Name
AdBrettPhos Pd G3
CAS No.
1445972-29-1
Chemical Name
AdBrettPhos Pd G3
Synonyms
AdBrettPhos Pd G3;AdBrettPhos Pd G3,98%;AdBrettPhos Pd G3 ChemBeads;AdBrettPhos Palladacycle Gen. 3;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...;bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane;2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][[3,6-dimethoxy-2′,4′,6′-tris(1-methylethy…;bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CBNumber
CB23357121
Molecular Formula
C56H74NO5PPdS
Formula Weight
1010.66
MOL File
1445972-29-1.mol
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AdBrettPhos Pd G3 Property

Melting point:
251-253 °C
storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
solid
color 
brown to green
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
100MG
Price
$108
Updated
2025/07/31
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
500MG
Price
$389
Updated
2025/07/31
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
2G
Price
$1440
Updated
2025/07/31
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
5G
Price
$3520
Updated
2025/07/31
Strem Chemicals
Product number
46-0480
Product name
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
Packaging
50mg
Price
$42
Updated
2024/03/01
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AdBrettPhos Pd G3 Chemical Properties,Usage,Production

Reaction

Palladium catalyst used in the highly selective monoarylation of ammonia.

Uses

Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

AdBrettPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from AdBrettPhos Pd G3 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
AdBrettPhos Pd G3 1445972-29-1
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-19

1445972-29-1, AdBrettPhos Pd G3Related Search:


  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3
  • METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
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  • AdBrettPhos Pd G3 ChemBeads
  • Methanesulfonicacid(2-di-tert-butylphosphino-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),AdBrettPhosPalladacycleGen.3
  • Bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(propan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane, {2'-amino-[1,1'-biphenyl]-2-yl}palladio methanesulfonate
  • 2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][[3,6-dimethoxy-2′,4′,6′-tris(1-methylethy…
  • AdBrettPhos Pd G3,98%
  • 1445972-29-1
  • C56H74NO5PPdS