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ChemicalBook > CAS DataBase List > AdBrettPhos Pd G3

AdBrettPhos Pd G3

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Product Name
AdBrettPhos Pd G3
CAS No.
1445972-29-1
Chemical Name
AdBrettPhos Pd G3
Synonyms
AdBrettPhos Pd G3;AdBrettPhos Palladacycle Gen. 3;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...;bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane;bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3;METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
CBNumber
CB23357121
Molecular Formula
C56H74NO5PPdS
Formula Weight
1010.66
MOL File
1445972-29-1.mol
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AdBrettPhos Pd G3 Property

Melting point:
251-253 °C
form 
solid
color 
brown to green
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
100MG
Price
$101
Updated
2023/06/20
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
500MG
Price
$362
Updated
2023/06/20
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
2G
Price
$1350
Updated
2023/06/20
Sigma-Aldrich
Product number
776106
Product name
AdBrettPhos Pd G3
Packaging
5G
Price
$3280
Updated
2023/06/20
Strem Chemicals
Product number
46-0480
Product name
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
Packaging
50mg
Price
$42
Updated
2024/03/01
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AdBrettPhos Pd G3 Chemical Properties,Usage,Production

Reaction

Palladium catalyst used in the highly selective monoarylation of ammonia.

Uses

Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

AdBrettPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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AdBrettPhos Pd G3 Suppliers

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1445972-29-1, AdBrettPhos Pd G3Related Search:


  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3
  • METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • AdBrettPhos Palladacycle Gen. 3
  • bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...
  • AdBrettPhos Pd G3
  • bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
  • Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • 1445972-29-1
  • C56H74NO5PPdS