UiO-66-NH2(Zr)
Uses- Product Name
- UiO-66-NH2(Zr)
- CAS No.
- 1260119-00-3
- Chemical Name
- UiO-66-NH2(Zr)
- Synonyms
- UIO-66-NH2;NH2-UiO-66;UiO-66-NH2(Zr);NH2-UIO-66(Zr);MOF:UiO-66(Zr)-NH2;Zirconium aminobenzenedicarboxylate MOF;ZIRCONIUMAMINOBENZENEDICARBOXYLATEMOF(UIO-66-BDC-NH2,BDC-NH2:ZR=0.9-1.0);UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0,Zirconium aminobenzenedicarboxylate MOF
- CBNumber
- CB23357141
- Molecular Formula
- C48H30N6O32Zr6
- Formula Weight
- 1750.12
- MOL File
- 1260119-00-3.mol
UiO-66-NH2(Zr) Property
- form
- solid
- color
- Yellow
- InChI
- InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12
- InChIKey
- SGCQKKMGUIJGFK-UHFFFAOYSA-B
N-Bromosuccinimide Price
- Product number
- 40-1109
- Product name
- Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0)
- Packaging
- 500mg
- Price
- $95
- Updated
- 2024/03/01
- Product number
- 40-1109
- Product name
- Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0)
- Packaging
- 2g
- Price
- $283
- Updated
- 2024/03/01
UiO-66-NH2(Zr) Chemical Properties,Usage,Production
Uses
Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0) Useful MOF for adsorption of CO2 applications
Catalyst MOF used in the conversion of toxic agents to non-toxic products
Definition
UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].
References
[1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197.
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