3-(HYDROXYMETHYL)BENZALDEHYDE

Product Name: 3-(HYDROXYMETHYL)BENZALDEHYDE
CAS No.: 52010-98-7
Chemical Name: 3-(HYDROXYMETHYL)BENZALDEHYDE
Synonyms: 130910;3-FORMYLBENZYL ALCOHOL;m-(Hydroxymethyl)benzaldehyde;3-(HYDROXYMETHYL)BENZALDEHYDE;Benzaldehyde, 3-(hydroxymethyl)-
CBNumber: CB2343640
Molecular Formula: C8H8O2
Formula Weight: 136.15
MOL File: 52010-98-7.mol

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3-(HYDROXYMETHYL)BENZALDEHYDE Property

Melting point:: 120℃
Boiling point:: 282℃
Density: 1.184
Flash point:: 118℃
storage temp.: 2-8°C, stored under nitrogen
pka: 14.10±0.10(Predicted)
form: solid
Appearance: Colorless to off-white Liquid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: PH017016
Product name: 3-(Hydroxymethyl)benzaldehyde
Purity: AldrichCPR
Packaging: 50MG
Price: $167
Updated: 2023/06/20

TRC

Product number: F697420
Product name: 3-FormylbenzylAlcohol
Packaging: 500mg
Price: $175
Updated: 2021/12/16

AK Scientific

Product number: 4151CU
Product name: 3-(Hydroxymethyl)benzaldehyde
Packaging: 1g
Price: $863
Updated: 2021/12/16

Chemenu

Product number: CM219864
Product name: 3-(Hydroxymethyl)benzaldehyde
Purity: 95%
Packaging: 1g
Price: $309
Updated: 2021/12/16

Alichem

Product number: 52010987
Product name: 3-(Hydroxymethyl)benzaldehyde
Packaging: 1g
Price: $336.6
Updated: 2021/12/16

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3-(HYDROXYMETHYL)BENZALDEHYDE Chemical Properties,Usage,Production

Synthesis Reference(s)

Journal of the American Chemical Society, 105, p. 7175, 1983 DOI: 10.1021/ja00362a028

Synthesis

626-19-7

52010-98-7

General procedure for the synthesis of 3-(hydroxymethyl)benzaldehyde from m-toluenedicarboxaldehyde: NaBH4 (1.7 g) was slowly added to a mixed solution of ethanol (100 mL) and tetrahydrofuran (150 mL) of m-toluenedicarboxaldehyde (1b, 20.0 g). The reaction mixture was stirred under ice bath conditions for 6 hours. Upon completion of the reaction, the pH was adjusted to 5-6 with 2 M hydrochloric acid solution to quench the reaction. Subsequently, the solvent was removed by rotary evaporator and the residue was extracted by adding water and ethyl acetate to the residue. The organic phase was washed with saturated NaCl solution and dried with anhydrous Na2SO4 for 8 hours. Finally, the product was purified by silica gel column chromatography using petroleum ether-ethyl acetate (5:1, v/v) as eluent to afford the target compound 3-(hydroxymethyl)benzaldehyde (2b, 16.4 g, 80.2% yield).

References

[1] Organic and Biomolecular Chemistry, 2016, vol. 14, # 45, p. 10688 - 10694
[2] Journal of Organometallic Chemistry, 2010, vol. 695, # 1, p. 82 - 89
[3] Dalton Transactions, 2015, vol. 44, # 9, p. 4054 - 4062
[4] Molecules, 2016, vol. 21, # 7,
[5] Patent: CN107522647, 2017, A. Location in patent: Paragraph 0082; 0083

3-(HYDROXYMETHYL)BENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(HYDROXYMETHYL)BENZALDEHYDE Suppliers

China 35 France 1 United Kingdom 2 United States 4 Global 42

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52010-98-7, 3-(HYDROXYMETHYL)BENZALDEHYDERelated Search:

3-CYANOBENZYL ALCOHOL Salicylaldehyde 4-Hydroxybenzaldehyde

3-FORMYLBENZYL ALCOHOL

3-(HYDROXYMETHYL)BENZALDEHYDE

m-(Hydroxymethyl)benzaldehyde

130910

Benzaldehyde, 3-(hydroxymethyl)-

52010-98-7

Aromatic Aldehydes & Derivatives (substituted)