(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE

Product Name: (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
CAS No.: 27032-63-9
Chemical Name: (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
Synonyms: 5-CHLORO-2-HYDRAZINOPYRIDINE;PYRIDINE,5-CHLORO-2-HYDRAZINYL-;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE;5-chloro-2-hydrazono-1,2-dihydropyridine;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 5193-03-3
CBNumber: CB2349930
Molecular Formula: C5H6ClN3
Formula Weight: 143.57
MOL File: 27032-63-9.mol

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(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Property

Melting point:: 127-128
Boiling point:: 221.6±50.0 °C(Predicted)
Density: 1.43±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form: solid
pka: 9.00±0.70(Predicted)
color: Beige
InChI: InChI=1S/C5H6ClN3/c6-4-1-2-5(9-7)8-3-4/h1-3H,7H2,(H,8,9)
InChIKey: UXJYFOOFLZGBEK-UHFFFAOYSA-N
SMILES: C1(NN)=NC=C(Cl)C=C1

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: C349405
Product name: 5-Chloro-2-hydrazinopyridine
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: C349405
Product name: 5-Chloro-2-hydrazinopyridine
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC139335
Product name: 5-Chloro-2-hydrazinylpyridine
Packaging: 2g
Price: $57
Updated: 2021/12/16

Ark Pharm

Product number: AK126165
Product name: 5-Chloro-2-hydrazinylpyridine
Purity: 97%
Packaging: 1g
Price: $18
Updated: 2021/12/16

Matrix Scientific

Product number: 047249
Product name: 5-Chloro-2-hydrazinopyridine
Purity: >95%
Packaging: 1g
Price: $24
Updated: 2021/12/16

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(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Chemical Properties,Usage,Production

Synthesis

16110-09-1

27032-63-9

General procedure for the synthesis of 5-chloro-2-hydrazinopyridine from 2,5-dichloropyridine: A mixed solution of 2,5-dichloropyridine (7.4 g, 50.0 mmol) and hydrazine hydrate (101 mL, 3250 mmol) in pyridine (100 mL) was heated and refluxed for 6 hours. Upon completion of the reaction, the reaction solution was concentrated to dryness in vacuum. The resulting residue was dissolved in dichloromethane (500 mL) and washed sequentially with 1N aqueous sodium hydroxide (500 mL) and water (3 x 500 mL). The organic layer was dried with anhydrous magnesium sulfate, filtered and concentrated to dryness in vacuo to afford 5-chloro-2-hydrazinopyridine (2.95 g, 20.55 mmol, 41% yield) as a light yellow solid.1H NMR (300 MHz, DMSO-d6) δ 7.97 (d, J = 2.5 Hz, 1H), 7.67 (s, 1H), 7.50 (dd, J = 9.0, 2.6 Hz, 1H), 6.73 (dd, J = 9.0, 0.6 Hz, 1H), 4.17 (s, 2H); MS (ES+) m/z 144.2 ([M+H]+).

References

[1] Journal of the American Chemical Society, 2011, vol. 133, # 17, p. 6780 - 6790
[2] Patent: US2003/187014, 2003, A1
[3] Patent: WO2015/134998, 2015, A1. Location in patent: Page/Page column 147
[4] Patent: US5750550, 1998, A
[5] Patent: US4997835, 1991, A

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Suppliers

China 93 India 2 United Kingdom 3 United States 9 Global 107

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View Lastest Price from (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE manufacturers

Career Henan Chemical Co

Product: (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 27032-63-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-02

27032-63-9, (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINERelated Search:

1-[5-CHLORO-3-(TRIFLUOROMETHYL)-2-PYRIDYL]HYDRAZINE 5-CHLORO-3-IODOPYRIDIN-2-YLHYDRAZINE (3-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 2-Hydrazinopyridine (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE (3,5,6-TRICHLORO-PYRIDIN-2-YL)-HYDRAZINE 1-[5-CHLORO-3-(TRIFLUOROMETHYL)-2-PYRIDYL]-1-METHYLHYDRAZINE 5-chloro-3-fluoro-2-hydrazinylpyridine (3,5-DICHLORO-PYRIDIN-2-YL)-HYDRAZINE (4-CHLORO-PYRIDIN-2-YL)-HYDRAZINE N'3-[5-CHLORO-3-(TRIFLUOROMETHYL)-2-PYRIDYL]-2,5-DICHLOROPYRIDINE-3-CARBOHYDRAZIDE 2-FLUOROPHENYL 2-(3,4,5-TRICHLORO-6-(3,5-DITERT-BUTYL-4-HYDROXYPHENYLTHIO)PYRIDIN-2-YL)HYDRAZINECARBONYLSULFAMATE 1-(3,5-dichloropyridin-2-yl)-1-methylhydrazine 1-(5-chloropyridin-2-yl)-1-methylhydrazine 5-chloro-2-hydrazinyl-4,6-dimethylpyridine-3-carbonitrile 1-(3-bromo-5-chloropyridin-2-yl)-1-methylhydrazine 2-(1-methylhydrazinyl)-5-chloro-4,6-dimethylpyridine-3-carbonitrile 4-AMINO-3,5-DICHLORO-6-HYDRAZINO-PYRIDINE-2-CARBOXYLIC ACID HYDRAZIDE

5-CHLORO-2-HYDRAZINOPYRIDINE

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 5193-03-3

PYRIDINE,5-CHLORO-2-HYDRAZINYL-

5-chloro-2-hydrazono-1,2-dihydropyridine

27032-63-9

5193-3-3