(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE Property

Density 

0.965 g/mL at 25 °C

Flash point:

1 °F

storage temp. 

2-8°C

Safety

Hazard Codes 

F,Xn

Risk Statements 

19-22-36/38-40-36/37-14-11

Safety Statements 

16-26-33-36-36/37

RIDADR 

UN 3399 4.3/PG 2

WGK Germany 

1

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H319Causes serious eye irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

(S)-(?)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:

• As an intermediate in the total synthesis of macrolide derivative laingolide B stereoisomers.
• As a substrate in the synthesis of (3R)-1-benzyl-3-methylpyrrolidine-2,5-dione (aliphatic carboxamide) using Ni^II-pincer complexes.