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Azulene

Product Name
Azulene
CAS No.
275-51-4
Chemical Name
Azulene
Synonyms
AZULEN;AZULENE;Azunamic;Azulene,99%;AZULENE(RG);Azulene >AZULENE, FOR GC;Soluble azulene;275-51-4 AZULENE;AZULENE OEKANAL
CBNumber
CB2440183
Molecular Formula
C10H8
Formula Weight
128.17
MOL File
275-51-4.mol
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Azulene Property

Melting point:
98-100 °C(lit.)
Boiling point:
242 °C(lit.)
Density 
1.0530
refractive index 
1.5736 (estimate)
Flash point:
241-243°C
storage temp. 
Store at +2°C to +8°C.
solubility 
Soluble in organic solvents.
form 
Fine Crystalline Powder
color 
Dark blue
Merck 
14,926
BRN 
969517
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
CUFNKYGDVFVPHO-UHFFFAOYSA-N
LogP
3.200
CAS DataBase Reference
275-51-4(CAS DataBase Reference)
EPA Substance Registry System
Azulene (275-51-4)
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Safety

Hazard Codes 
N
Risk Statements 
51/53
Safety Statements 
61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
RTECS 
CO4570000
8
TSCA 
Yes
HS Code 
29029000
Toxicity
LD50 orl-rat: >4 g/kg DRUGAY 6,13,82
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
A97203
Product name
Azulene
Purity
99%
Packaging
100mg
Price
$82.3
Updated
2024/03/01
Sigma-Aldrich
Product number
A97203
Product name
Azulene
Purity
99%
Packaging
1g
Price
$225
Updated
2024/03/01
TCI Chemical
Product number
A0634
Product name
Azulene
Purity
>99.0%(GC)
Packaging
1g
Price
$378
Updated
2024/03/01
TCI Chemical
Product number
A0634
Product name
Azulene
Purity
>99.0%(GC)
Packaging
5g
Price
$1316
Updated
2024/03/01
Alfa Aesar
Product number
L08271
Product name
Azulene, 99%
Packaging
1g
Price
$212
Updated
2024/03/01
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Azulene Chemical Properties,Usage,Production

Chemical Properties

Azulene is a blue crystalline compound with the chemical formula C10H8 and a melting point of 99°C. It contains afive-membered ring fused to a seven-membered ring and has aromatic properties. When heated it is converted into naphthalene.

Uses

Azulene is used as an additive in ointments. It is an active ingredient in cosmetics, shaving creams and other topicals. It is used as antioxidant and in anti-inflammatory activities. It is involved in the colorimetric determination of furfural. It acts as ligand for low valent metals and forms pi complexes with both cyclopentadienyl and cylcloheptatrienyl ligands in organometallic chemistry. It is also used as precursor for the preparation of (azulene)Mo2 (CO)6 and (azulene)Fe2 (CO)5.

Uses

azulene is renowned as an anti-inflammatory, calming, and soothing agent. excellent for sensitive skin, azulene is a german chamomile derivative with a characteristic deep blue color. Careful, it stains!

Definition

ChEBI: Azulene is a mancude carbobicyclic parent consisting of a cycloheptatriene and cyclopentadiene rings. It has a role as a plant metabolite and a volatile oil component. It is an ortho-fused bicyclic arene, a member of azulenes and a mancude carbobicyclic parent.

Synthesis Reference(s)

Journal of the American Chemical Society, 75, p. 2386, 1953 DOI: 10.1021/ja01106a030
Tetrahedron Letters, 23, p. 495, 1982 DOI: 10.1016/S0040-4039(00)86871-9

Safety Profile

Poison by intraperitoneal,intravenous, and subcutaneous routes. When heated todecomposition it emits acrid smoke and irritating vapors.

Source

Azulene is a natural product and function as pigment in living organisms like plants, fungi etc. This compound was first isolated from the German Chamomile and later from yarrow, wormwood and other plants as oily liquid.

Purification Methods

Crystallise azulene from EtOH. It has UV max 270nm (log 4.72) in hexane. [Platner & Magyar Helv Chim Acta 25 581 1942, Beilstein 5 IV 1636.]

Azulene Preparation Products And Raw materials

Raw materials

Preparation Products

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Azulene Suppliers

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View Lastest Price from Azulene manufacturers

Hebei Kingfiner Technology Development Co.Ltd
Product
AZULENE 275-51-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500000kg
Release date
2023-11-28
Hebei Guanlang Biotechnology Co., Ltd.
Product
Azulene 275-51-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-24
Nanjing jinheyou Trading Co., Ltd.
Product
AZULENE 275-51-4
Price
US $0.00/g
Min. Order
1g
Purity
98%min
Supply Ability
20kg/month
Release date
2019-11-01

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