3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER
- Product Name
- 3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER
- CAS No.
- 29269-17-8
- Chemical Name
- 3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER
- Synonyms
- TRI(2-METHOXYCARBONYLETHYL)PHOSPHINE;Trimethyl3,3',3''-phosphinetriyltripropanoate;Trimethyl 3,3',3''-phosphineTriylTripropanoate;Propanoic acid, 3,3',3''-phosphinidynetris-, 1,1',1''-trimethyl ester;3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER;Propanoicacid,3,3',3''-phosphinidynetriChemicalbooks-,1,1',1''-trimethylester
- CBNumber
- CB2443593
- Molecular Formula
- C12H21O6P
- Formula Weight
- 292.27
- MOL File
- 29269-17-8.mol
3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER Property
- Boiling point:
- 365.4±37.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
Safety
- HS Code
- 2931499090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- CHM0085701
- Product name
- TRI(2-METHOXYCARBONYLETHYL)PHOSPHINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $945.95
- Updated
- 2021/12/16
- Product number
- CD50000193
- Product name
- Trimethyl3,3',3''-phosphinetriyltripropanoate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $35
- Updated
- 2021/12/16
- Product number
- BD00780815
- Product name
- Trimethyl3,3',3''-phosphinetriyltripropanoate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $51
- Updated
- 2021/12/16
- Product number
- CD50000193
- Product name
- Trimethyl3,3',3''-phosphinetriyltripropanoate
- Purity
- 95%
- Packaging
- 250mg
- Price
- $68
- Updated
- 2021/12/16
- Product number
- CD50000193
- Product name
- Trimethyl3,3',3''-phosphinetriyltripropanoate
- Purity
- 95%
- Packaging
- 1g
- Price
- $206
- Updated
- 2021/12/16
3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER Chemical Properties,Usage,Production
Synthesis
67-56-1
51805-45-9
29269-17-8
General procedure for the synthesis of trimethyl 3,3',3''-phosphono-tripropionate from methanol and tris(2-carboxyethyl)phosphine hydrochloride: tris(2-carboxyethyl)phosphine hydrochloride (TCEP) (7.0 g, 24.42 mmol) was co-evaporated with ethanol (EtOH) (2 × 100 mL) and subsequently dissolved in methanol (CH3OH) (200 mL) at 4 °C . Thionyl chloride (SOCl2) (9.0 mL, 122.29 mmol) was slowly added to this solution. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was concentrated and dried under vacuum to afford trimethyl 3,3',3''-phosphonyl tripropionate (7.0 g, 98% yield). The product was confirmed by electrospray ionization mass spectrometry (ESI MS) with an observed m/z of 293.2 (M+H)+.
References
[1] Patent: WO2015/28850, 2015, A1. Location in patent: Page/Page column 81
3-[BIS-(2-METHOXYCARBONYL-ETHYL)-PHOSPHANYL]-PROPIONIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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