3-Bromo-9H-carbazole

Product Name: 3-Bromo-9H-carbazole
CAS No.: 1592-95-6
Chemical Name: 3-Bromo-9H-carbazole
Synonyms: 2-bromo-9H-carbazole;3-BROMOCARBAZOLE;9H-Carbazole, 3-bromo-;3-broMidecarbazole;Carbazole, 3-bromo-;3- broMinecarbazole;3-Bromo-9H-carbazoL;3-Bromocarbazole >3-BROMO-9H-CARBAZOLE;3-BroMocarbazole (3BC)
CBNumber: CB2444848
Molecular Formula: C12H8BrN
Formula Weight: 246.1
MOL File: 1592-95-6.mol

More

Less

3-Bromo-9H-carbazole Property

Melting point:: 195 °C
Boiling point:: 160℃/6mm
Density: 1.617±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 16.43±0.30(Predicted)
form: Solid
color: White
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C12H8BrN/c13-8-5-6-12-10(7-8)9-3-1-2-4-11(9)14-12/h1-7,14H
InChIKey: LTBWKAYPXIIVPC-UHFFFAOYSA-N
SMILES: N1C2=C(C=CC=C2)C2=C1C=CC(Br)=C2
EPA Substance Registry System: 3-Bromocarbazole (1592-95-6)

More

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-37/39-24/25
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29339900

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 777153
Product name: 3-Bromocarbazole
Purity: 97% (GC)
Packaging: 1g
Price: $64.6
Updated: 2023/06/20

TCI Chemical

Product number: B3458
Product name: 3-Bromocarbazole
Purity: >97.0%(GC)
Packaging: 5g
Price: $66
Updated: 2024/03/01

TCI Chemical

Product number: B3458
Product name: 3-Bromocarbazole
Purity: >97.0%(GC)
Packaging: 25g
Price: $229
Updated: 2024/03/01

Alfa Aesar

Product number: H64437
Product name: 3-Bromocarbazole, 98%
Packaging: 5g
Price: $105
Updated: 2024/03/01

Alfa Aesar

Product number: H64437
Product name: 3-Bromocarbazole, 98%
Packaging: 1g
Price: $28.6
Updated: 2023/06/20

More

Less

3-Bromo-9H-carbazole Chemical Properties,Usage,Production

Description

3-Bromo-9H-carbazole is an isomer to 2-Bromo-9H-carbazole, with the only difference being that 9H-carbazole is mono-brominated at 3-position. Blocked at 3-position, 3-Bromo-9H-carbazole derivatives reduce the chance of being oxidised to form excimers or oligomers. 3-bromo-9H-carbazole is a versatile building block that can be used to create a range of compounds, such as 9-Benzyl-3-bromo-9H-carbazole. 3-Bromo-9H-carbazole can be prepared by reacting 9H-carbzole with N-bromosuccinimide (NBS) In tetrahydrofuran at room temperature[1].

Chemical Properties

White to light yellow solid

Uses

3-Bromo-9H-carbazole is an aryl hydrocarbon receptor agonist. A standard for environmental testing and research. Substance for the bological potency study, characterization of mono to tetra-halogenated carbazoles.

Uses

3-Bromocarbazole is used as a intermediate for organic light-emitting diode(OLED) and pharmaceutical.

Preparation

3-Bromocarbazole synthesis: A solution of N-bromosuccinimide (1.1g, 5.98mmol) in dimethylformamide was added dropwise to a solution of carbazole (1, 1g, 5.96mmol) in dimethylformamide (15mL) at 0°C. The reaction mixture was then stirred at room temperature for 24h. The reaction was poured into distilled water to give a cream coloured precipitate. The precipitate was filtered off under vacuum and washed with distilled water (3 × 20mL). The precipitate was dissolved in ethyl acetate, dried with sodium sulfate and filtered. Upon concentration under reduced pressure the crude product was obtained as a brown solid. After crystallisation of the crude product with chloroform, the pure 3-Bromo-9H-carbazole(692 mg, 47%) was obtained as white crystals. Rf (ethyl acetate/hexane, 1:6 v/v): 0.43; melting point: 200–201°C.

References

[1] Peng-Mian Huang, Xiao-Chun Wang. “9-Benzyl-3-bromo-9H-carbazole.” Acta crystallographica. Section E, Structure reports online 65 Pt 8 (2009): o1763.

3-Bromo-9H-carbazole Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

3-Bromo-9H-carbazole Suppliers

Americas 1 Australia 1 Belgium 4 China 389 Europe 1 France 1 Germany 7 India 6 Japan 5 South Korea 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 13 United States 39 Global 471

Shanghai Future Optoetech Co. Ltd

Tel: 17316394829 19299290913
Email: pm01@futureoled.com
Country: China
ProdList: 20
Advantage: 58

Zhengzhou HQ Material Co., Ltd.

Tel: 0371-67759225 13526468238
Fax: +86-37155919558
Email: sales@hqmat.com
Country: China
ProdList: 814
Advantage: 55

Sunshine Optoelectronic

Tel: 027-027-87915283 15972929998
Fax: 027-87915283
Email: sales@sunshine-oled.com
Country: China
ProdList: 684
Advantage: 58

Zhengzhou Shengyi New Material Technology Co., LTD

Tel: 0371-63891666 18037898020
Email: sales@sinoemat.com
Country: China
ProdList: 39
Advantage: 58

Pingdingshan Longwei Biotechnology Co. , Ltd.

Tel: 15343756688
Email: 3079249712@qq.com
Country: China
ProdList: 330
Advantage: 58

Puyang Huicheng Electronic Material Co. Ltd.

Tel: 0393-0393-0393-8910800 15238090375
Fax: 0393-8912775
Email: info@huichengchem.com
Country: China
ProdList: 563
Advantage: 64

Ningbo jinuo chemical co., LTD

Tel: 0574-87314919 057487319282
Email: info@nbinno.com
Country: China
ProdList: 7033
Advantage: 58

Creasyn Finechem(Tianjin) Co., Ltd.

Tel: 022-83946278 13820503911
Fax: 022-83945176
Email: sales@creasyn.com
Country: China
ProdList: 993
Advantage: 68

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

More

Less

View Lastest Price from 3-Bromo-9H-carbazole manufacturers

Shengyan (Shanghai) New Material Co., Ltd.

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 100kg
Release date: 2024-12-25

Hebei Weibang Biotechnology Co., Ltd

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-11-18

Shaanxi Dideu Medichem Co. Ltd

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 99%
Supply Ability: 2000tons
Release date: 2019-12-31

1592-95-6, 3-Bromo-9H-carbazoleRelated Search:

Carbazole POLY(N-VINYLCARBAZOLE) 3,6-Dibromo-9-ethylcarbazole 3,6-Dibromocarbazole Bromine 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-PYRROLIDIN-1-YL-PROPAN-2-OL TIMTEC-BB SBB006353 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-[4-(4-FLUORO-PHENYL)-PIPERAZIN-1-YL]-PROPAN-2-OL 1,4-Dimethyl-6-bromo-9H-carbazole 3,6-DIBROMO-9-VINYLCARBAZOLE 3,6-DIBROMO-9-(OXIRAN-2-YLMETHYL)-9H-CARBAZOLE 3,6-DIBROMO-ALPHA-(1-PIPERAZINYLMETHYL)-9H-CARBAZOLE-9-ETHANOL DIHYDROCHLORIDE 1-(3,6-DIBROMO-9H-CARBAZOL-9-YL)-3-(DIMETHYLAMINO)PROPAN-2-OL 3,6-Dibromo-9-phenyl-9H-carbazole 3-Bromo-9H-carbazole AKOS BC-1674 1-(4-[2-HYDROXY-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPYL]PIPERAZINO)-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPAN-2-OL DIHYDROCHLORIDE SALOR-INT L150053-1EA

3-BROMO-9H-CARBAZOLE

2-bromo-9H-carbazole

3-BROMOCARBAZOLE

3-broMidecarbazole

3-BroMo-9H-carbazole, 95+%

3-Bromocarbazole 97% (GC)

3-BroMocarbazole (3BC)

3- broMinecarbazole

Carbazole, 3-bromo-

9H-Carbazole, 3-bromo-

3-Bromocarbazole &gt

3-Bromo-9H-carbazoL

1592-95-6

1595-95-6

1952-95-6

C12H8BrN

Pyridines

OLED materials,pharm chemical,electronic

Carbazole Series

organic chemicals and derivatives/others

OLED

Fused Ring Systems

Halides

bc0001