2-BROMO-5-METHOXYPHENYLBORONIC ACID

Product Name: 2-BROMO-5-METHOXYPHENYLBORONIC ACID
CAS No.: 89694-44-0
Chemical Name: 2-BROMO-5-METHOXYPHENYLBORONIC ACID
Synonyms: 2-BROMO-5-METHOXYPHENYLBORONIC ACID;2-bromine-5-methoxyphenylboronic acid;(2-BROMO-5-METHOXY)BENZENEBORONIC ACID;Boronic acid, B-(2-bromo-5-methoxyphenyl)-;2-Bromo-5-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
CBNumber: CB2468882
Molecular Formula: C7H8BBrO3
Formula Weight: 230.85
MOL File: 89694-44-0.mol

More

Less

2-BROMO-5-METHOXYPHENYLBORONIC ACID Property

Melting point:: 214-216
Boiling point:: 376.6±52.0 °C(Predicted)
Density: 1.61±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
pka: 7.82±0.58(Predicted)
color: Beige

More

Less

Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 2931900090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More

Less

N-Bromosuccinimide Price

TRC

Product number: B694618
Product name: 2-Bromo-5-methoxyphenylboronicacid
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: B694618
Product name: 2-Bromo-5-methoxyphenylboronicacid
Packaging: 500mg
Price: $65
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0000770
Product name: (2-BROMO-5-METHOXY)BENZENEBORONIC ACID
Purity: 95.00%
Packaging: 5G
Price: $1347.42
Updated: 2021/12/16

ChemScene

Product number: CS-0038152
Product name: 2-Bromo-5-methoxybenzeneboronic acid
Packaging: 25g
Price: $670
Updated: 2021/12/16

AK Scientific

Product number: Z1036
Product name: 2-Bromo-5-methoxyphenylboronicacid
Packaging: 5g
Price: $862
Updated: 2021/12/16

More

Less

2-BROMO-5-METHOXYPHENYLBORONIC ACID Chemical Properties,Usage,Production

Synthesis

10365-98-7

89694-44-0

Under argon protection, 3-methoxyphenylboronic acid (9.12 g, 60.0 mmol) was dissolved in dichloromethane (200 mL) with triphenylphosphine sulfide (932 mg, 6.00 mmol) in a 300 mL aubergine flask, and stirred until completely dissolved. Subsequently, N-bromosuccinimide (13.0 g, 72.0 mmol) was added to the solution and stirred continuously for 48 hours at room temperature. Upon completion of the reaction, saturated aqueous sodium thiosulfate solution was added to quench the reaction. Extraction was carried out with dichloromethane (100 mL × 3) and the organic phases were combined, washed with saturated brine and dried over anhydrous sodium sulfate. After filtration, the crude product was concentrated under reduced pressure. The target product 2-bromo-5-methoxyphenylboronic acid (8.45 g, 36.6 mmol, 61.0% yield) was purified by silica gel column chromatography (silica gel 290 g, eluent hexane/acetone = 1/1).

References

[1] Organic Letters, 2010, vol. 12, # 11, p. 2480 - 2483
[2] Patent: JP2018/30788, 2018, A. Location in patent: Paragraph 0057
[3] Organic Letters, 2015, vol. 17, # 4, p. 1042 - 1045

2-BROMO-5-METHOXYPHENYLBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-BROMO-5-METHOXYPHENYLBORONIC ACID Suppliers

China 69 Germany 1 India 2 United Kingdom 2 United States 13 Global 87

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 52923
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

Anichem LLC

Tel: --
Fax: --
Email: sales@anichemllc.com
Country: United States
ProdList: 4112
Advantage: 34

BoroPharm Inc.

Tel: --
Fax: --
Email: sales@boropharm.com
Country: United States
ProdList: 96
Advantage: 50

Cuschem, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 353
Advantage: 42

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Abby PharmaTech, LLC

Tel: --
Fax: --
Country: United States
ProdList: 365
Advantage: 50

Pure Chemistry Scientific Inc

Tel: --
Fax: --
Email: sales@purechems.com
Country: United States
ProdList: 2321
Advantage: 50

AOBChem USA

Tel: --
Fax: --
Email: sales@aobchem.com
Country: United States
ProdList: 3487
Advantage: 50

AK Scientific, Inc.

Tel: --
Fax: --
Email: sales@aksci.com
Country: United States
ProdList: 6347
Advantage: 65

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

More

Less

View Lastest Price from 2-BROMO-5-METHOXYPHENYLBORONIC ACID manufacturers

Career Henan Chemical Co

Product: 2-BROMO-5-METHOXYPHENYLBORONIC ACID 89694-44-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%-100%
Supply Ability: 1
Release date: 2018-08-12

89694-44-0, 2-BROMO-5-METHOXYPHENYLBORONIC ACIDRelated Search:

3-Bromo-5-methoxybenzeneboronic acid 5-BROMO-2-METHOXYPHENYLBORONIC ACID 2-BROMO-5-METHOXYPHENYLBORONIC ACID (2,6-DIBROMO-5-METHOXY)BENZENEBORONIC ACID 6-Bromo-3-ethoxy-2-fluorobenzeneboronic acid 3-Benzyloxy-6-bromo-2-chlorophenylboronic acid 3-(Benzyloxy)-6-bromo-2-fluorophenylboronic acid 6-Bromo-2-fluoro-3-methoxybenzeneboronic acid (2,4-DIBROMO-5-METHOXY)BENZENEBORONIC ACID 6-Bromo-2-chloro-3-ethoxyphenylboronic acid 2-Bromo-5-(trifluoromethoxy)phenylboronic acid 6-Bromo-2-chloro-3-methoxyphenylboronic acid 6-BROMO-2-FLUORO-3-PROPOXYPHENYLBORONIC ACID 2-(6-BROMO-2-FLUORO-3-METHOXYPHENYL)-1,3,2-DIOXABOROLANE 6-BROMO-2-FLUORO-3-ISOPROPOXYPHENYLBORONIC ACID 6-BROMO-3-BUTOXY-2-FLUOROPHENYLBORONIC ACID 3-BROMO-2-METHOXYPHENYLBORONIC ACID 3-BROMO-5-METHOXYPHENYLBORONIC ACID

2-BROMO-5-METHOXYPHENYLBORONIC ACID

(2-BROMO-5-METHOXY)BENZENEBORONIC ACID

2-Bromo-5-methoxyphenylboronic Acid (contains varying amounts of Anhydride)

Boronic acid, B-(2-bromo-5-methoxyphenyl)-

2-bromine-5-methoxyphenylboronic acid

89694-44-0

C7H10BBrO3

blocks

BoronicAcids

Bromides