1-Nitronaphthalene
- Product Name
- 1-Nitronaphthalene
- CAS No.
- 86-57-7
- Chemical Name
- 1-Nitronaphthalene
- Synonyms
- 1-Nitronaftalen;I-P#itronaphthalin;Nitrol (pesticide);1-Nitro-naphthaline;Naphthalene,1-nitro-;1-nitronaphthalene (alpha);NCI-C01956;1-nitronathalene;nitrol(pesticide);1-Nitronphthalene
- CBNumber
- CB2487528
- Molecular Formula
- C10H7NO2
- Formula Weight
- 173.17
- MOL File
- 86-57-7.mol
1-Nitronaphthalene Property
- Melting point:
- 56 °C
- Boiling point:
- 304 °C(lit.)
- Density
- 1.223 g/mL at 25 °C(lit.)
- refractive index
- 1.5200 (estimate)
- Flash point:
- 164 °C
- storage temp.
- 2-8°C
- solubility
- H2O: insoluble
- Specific Gravity
- 1.223
- color
- Light Yellow To Yellow
- Water Solubility
- 0.022 g/L
- Merck
- 14,6613
- BRN
- 1867714
- Stability:
- Stable. Combustible. Incompatible with oxidizing agents, strong reducing agents. Mixtures with sulfuric or nitric acid are dangerous.
- InChIKey
- RJKGJBPXVHTNJL-UHFFFAOYSA-N
- CAS DataBase Reference
- 86-57-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Naphthalene, 1-nitro-(86-57-7)
- IARC
- 3 (Vol. 46) 1989
- EPA Substance Registry System
- 1-Nitronaphthalene (86-57-7)
Safety
- Hazard Codes
- F,T,N
- Risk Statements
- 11-25-51/53-40-36/37/38-23/24/25
- Safety Statements
- 16-45-60-61-28A-36/37/39-26
- RIDADR
- UN 2538 4.1/PG 3
- WGK Germany
- 2
- RTECS
- QJ9720000
- Hazard Note
- Flammable/Toxic
- HazardClass
- 4.1
- PackingGroup
- III
- HS Code
- 29042000
- Hazardous Substances Data
- 86-57-7(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H228Flammable solid
H302Harmful if swallowed
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- BCR306
- Product name
- 1-Nitronaphthalene
- Purity
- BCR
- Packaging
- 10mg
- Price
- $218
- Updated
- 2023/06/20
- Product number
- 103594
- Product name
- 1-Nitronaphthalene
- Purity
- 99%
- Packaging
- 100g
- Price
- $77.4
- Updated
- 2023/06/20
- Product number
- N0212
- Product name
- 1-Nitronaphthalene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $28
- Updated
- 2023/06/20
- Product number
- N0212
- Product name
- 1-Nitronaphthalene
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $121
- Updated
- 2023/06/20
- Product number
- N496855
- Product name
- 1-Nitronaphthalene
- Packaging
- 5g
- Price
- $65
- Updated
- 2021/12/16
1-Nitronaphthalene Chemical Properties,Usage,Production
Chemical Properties
yellow crystalline solid
Uses
Usually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents.
Uses
1-Nitronaphthalene as a nitroaromatic compound is studied for mutagenicity, as nitroaromatics are used in everyday products from polmers, dyes to drugs.
Production Methods
One method to product 1-Nitronaphthalene: Naphthalene is charged to sulfuric acid alternately with mixed acid at 40 – 50 ℃ over 8 h, with the final temperature being 55 ℃. The acid strength used allows the molten product to be separated as an oil and washed. Continuous operation at 50 – 60 ℃ with mixed acid (33/48/19) gives a comparable product. The crude reaction product is obtained in 90 – 95 % yield and is purified by vacuum distillation.
Definition
ChEBI: A mononitronaphthalene substituted by a nitro group at position 1.
General Description
1-Nitronaphthalene is a mutagenic nitroaromatic compound present in diesel exhaust and it causes acute liver and lung toxicity in rodents. 1-Nitronaphthalene is a cytochrome P450-bioactivated, nonciliated bronchiolar epithelial (Clara) cell cytotoxicant .
Biochem/physiol Actions
1-Nitronaphthalene binds covalently to protein and forms adducts in the rat airway epithelium in vivo.
Safety Profile
Poison by intraperitoneal route. Mutation data reported. A skin, eye, and mucous membrane irritant. Flammable solid and combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical, or water spray. Explosive reaction with nitric acid + sulfuric acid above 60°C. Forms a sensitive explosive mixture with tetranitromethane. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITRONAPHTHALENE and NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
Purification Methods
Fractionally distil 1-nitronaphthalene under reduced pressure, then crystallise it from EtOH, aqueous EtOH or heptane. Chromatograph it on alumina with *benzene/pet ether as eluent. It sublimes in vacuo. The 1:1 picrate complex has m 72o (from EtOH). [Beilstein 5 H 553, 5 III 1593, 5 IV 1673.]
1-Nitronaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
1-Nitronaphthalene Suppliers
- Tel
- 400-1166-196 18981987031
- Fax
- 028-84555506 800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 400-1166-196 13458535857
- Fax
- QQ：800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 13350
- Advantage
- 58
- Tel
- 021-51619050 13301662590
- Fax
- +86-21-51619052
- mandy@atkchemical.com
- Country
- China
- ProdList
- 10200
- Advantage
- 55
- Tel
- 400-1166-196 18502815961
- Fax
- QQ：800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 14603
- Advantage
- 60
- Tel
- 021-56698539 18019222030
- bxsw_sh@163.com
- Country
- China
- ProdList
- 3724
- Advantage
- 58
- Tel
- 4008-099-669
- 23419001name@qq.com
- Country
- CHINA
- ProdList
- 73043
- Advantage
- 58
- Tel
- 58896805
- 7993601name@qq.com
- Country
- CHINA
- ProdList
- 15620
- Advantage
- 58
- Tel
- 18153089275
- 3032079623@qq.com
- Country
- China
- ProdList
- 22695
- Advantage
- 58