ChemicalBook > CAS DataBase List > (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

Product Name
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
CAS No.
175166-49-1
Chemical Name
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
Synonyms
SF140047;(-)-2,2'-Methylenebis;Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)methane;bis((3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)methane;(-)-2,2'-METHYLENEBIS(3A,8A-DIHYDRO-8H-I NDENO(1,2-D)OXAZOLE), 98%;(-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole;(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE;(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE];(-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]>(-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%
CBNumber
CB2493114
Molecular Formula
C21H18N2O2
Formula Weight
330.38
MOL File
175166-49-1.mol
More
Less

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Property

Melting point:
224 °C
Boiling point:
493.2±45.0 °C(Predicted)
Density 
1.48±0.1 g/cm3(Predicted)
refractive index 
-360 ° (C=1, CH2Cl2)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
almost transparency in Dichloromethane
form 
powder to crystal
pka
5.47±0.20(Predicted)
color 
White to Almost white
optical activity
[α]22/D 355°, c = 3.7 in chloroform
InChIKey
BDHSVQLSNIGJNC-JYWFKMLOSA-N
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29349990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
467073
Product name
(3aS,3′aS,8aR,8′aR)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity
98%
Packaging
500mg
Price
$61
Updated
2023/01/07
TCI Chemical
Product number
M1402
Product name
(-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity
>98.0%(HPLC)(N)
Packaging
100mg
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
M1402
Product name
(-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity
>98.0%(HPLC)(N)
Packaging
500mg
Price
$94
Updated
2024/03/01
TRC
Product number
M304475
Product name
(-)-2,2''-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8Hindeno[1,2-d]oxazole]
Packaging
5mg
Price
$45
Updated
2021/12/16
Chem-Impex
Product number
40963
Product name
(-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole],≥98%(Chiralpurity)
Purity
≥98%(Chiralpurity)
Packaging
100MG
Price
$29.12
Updated
2021/12/16
More
Less

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

(3aS,3′aS,8aR,8′aR)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] can be used as a chiral ligand:

  • In the preparation of oxazole α-hydroxy esters through intermolecular Alder-Ene reaction.
  • In the atom transfer radical polymerization reactions of methyl methacrylate.
  • In the copper-catalyzed synthesis of isoxazolidine derivatives by reacting nitrone with α,β-unsaturated acyl?phosphonate.

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3461
Advantage
50
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58

175166-49-1, (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]Related Search:


  • (3aS,8aR)-2-[(3aS,8aR)-3aH,8H,8aH-Indeno[1,2-d][1,3]oxazol-2-ylmethyl]-3aH,8H,8aH-indeno[1,2-d][1,3]oxazole
  • [3as-[2(3′Ar*,8′As*),3′AΑ,8′AΑ]]-()-2,2′-Methylenebis[3a,8a-Dihydro-8H-Inden
  • [3AS-[2(3'A R*,8'A S*),3'A-ALPHA,8'A-ALPHA]]-(-)-2,2'-METHYLENEBIS[3A,8A-DIHYDRO-8 H-INDENO[1,2-D]OXAZOLE]
  • (-)-2,2'-Methylenebis
  • (3aS,3′aS,8aR,8′aR)-(-)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
  • Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)methane
  • 8H-Indeno[1,2-d]oxazole,2,2'-Methylenebis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)-
  • (-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%
  • [3AS-[2(3'A R*,8'A S*),3'A-ALPHA,8'A-ALPHA]]-(-)-2,2'-METHYLENEBIS[3A,8A-DIHYDRO-8 H-INDENO[1,2-D]OXAZOLE]
  • (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
  • (-)-2,2'-METHYLENEBIS(3A,8A-DIHYDRO-8H-I NDENO(1,2-D)OXAZOLE), 98%
  • [3as-[2(3'ar*,8'as*),3'aα,8'aα]]-(-)-2,2'-methylenebis[3a,8a-dihydro-8h-indeno[1,2-d]oxazole]
  • SF140047
  • (-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]&gt
  • 3aS-[2(3'aR*,8'aS*),3'aα,8'aα]]-(-)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • (-)-2,2'-Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • bis((3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)methane
  • (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE
  • (3aS,3'aS,8aR,8'aR)-2,2'-Methylenebis[3a, 8a-dihydro-8H-indeno[1,2-d]oxazole]
  • (-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%
  • 175166-49-1
  • Privileged Ligands
  • Asymmetric Synthesis
  • BOX
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
  • BOX
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes
  • BOX series
  • Chiral Nitrogen