NICKEL BROMATE

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Description References

Product Name: NICKEL BROMATE
CAS No.: 13462-88-9
Chemical Name: NICKEL BROMATE
Synonyms: NiBr2;Nickel dibromide;Nickel(II)-bromid;Nickel-bromid;NICKEL BROMATE;Nickel(Ⅱ) bromide;Dibromonickel(II);Nickeleus bromide;nickelbromide(nibr2);Nickel(II) dibromide
CBNumber: CB2669337
Molecular Formula: Br2Ni
Formula Weight: 218.5
MOL File: 13462-88-9.mol

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NICKEL BROMATE Property

Melting point:: 963 °C (lit.)
Density: 5.098 g/mL at 25 °C (lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: H2O: slightly soluble(lit.)
form: powder
color: Brown
Specific Gravity: 5.098
Water Solubility: Soluble in water, alcohol and ether.
Sensitive: Hygroscopic
Merck: 14,6502
Exposure limits: ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:: Stable. Incompatible with strong oxidizing agents.
InChIKey: IPLJNQFXJUCRNH-UHFFFAOYSA-L
CAS DataBase Reference: 13462-88-9(CAS DataBase Reference)
EPA Substance Registry System: Nickel(II) bromide (13462-88-9)

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Safety

Hazard Codes: T,N,Xi
Risk Statements: 45-22-43-50/53-68-48/23-42/43-61-49
Safety Statements: 53-36/37-45-60-61
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
TSCA: Yes
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 28275900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H350May cause cancer

H360May damage fertility or the unborn child

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 217891
Product name: Nickel(II) bromide
Purity: 98%
Packaging: 10g
Price: $37.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 217891
Product name: Nickel(II) bromide
Purity: 98%
Packaging: 50g
Price: $76.8
Updated: 2024/03/01

Alfa Aesar

Product number: 053115
Product name: Nickel(II) bromide, anhydrous, 99%
Packaging: 50g
Price: $106
Updated: 2024/03/01

Alfa Aesar

Product number: 053115
Product name: Nickel(II) bromide, anhydrous, 99%
Packaging: 250g
Price: $446
Updated: 2024/03/01

Strem Chemicals

Product number: 28-1140
Product name: Nickel(II) bromide, anhydrous (99+%-Ni)
Packaging: 50g
Price: $118
Updated: 2024/03/01

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NICKEL BROMATE Chemical Properties,Usage,Production

Description

Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.

References

https://en.wikipedia.org/wiki/Nickel(II)_bromide

Chemical Properties

Brownish powder

Uses

Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.

General Description

Yellowish-green odorless solid. Sinks in and mixes with water.

Air & Water Reactions

Deliquescent. Soluble in water.

Reactivity Profile

NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]

Health Hazard

Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.

Purification Methods

Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.

NICKEL BROMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from NICKEL BROMATE manufacturers

Hebei Henghe Import and Export Trading Co. LTD

Product: Nickel(II) bromide 13462-88-9
Price: US $10.00/KG
Min. Order: 100KG
Purity: 99%
Supply Ability: 100
Release date: 2020-12-11

Career Henan Chemical Co

Product: NICKEL BROMATE 13462-88-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-10

13462-88-9, NICKEL BROMATERelated Search:

Nickel bis(sulphamidate) Manganese(II) bromide tetrahydrate IRON (III) BROMIDE Nickel fluoride Anhydrous nickel acetate Anhydrous nickel sulfate Nickelous acetate Nickel carbonate Nickel chloride Magnesium bromide hexahydrate Sodium bromide Cupric bromide Zinc bromide Magnesium bromide NIOBIUM(III) BROMIDE ETHYLENE GLYCOL NICKEL(II) BROMIDE 2-METHOXYETHYL ETHER& Rhodium tribromide TITANIUM(IV) BROMIDE

NICKEL BROMATE

Nickel(II) bromide anhydrous, powder, >=99.9% trace metals basis

Nickel(II) bromide anhydrous, powder, >=99.99% trace metals basis

Nickel(II) bromide anhydrousAnalytical Reagent Grade, ≥ 99% (Assay)

NiBr2

Nickel bromide (NiBr2)

Nickel(II)-bromid

Nickel(II)-bromidwasserfrei

nickelbromide(nibr2)

Nickel(II) bromide, anhydrous 99%

Nickelbromideanhydrousyellowgreenpowder

Nickelbromidehydrateyellowgreenxtl

NICKEL(II)BROMIDE,ANHYDROUS,POWDER,99.9+%

NICKEL(II) BROMIDE, ANHYDROUS, POWDER, 9 9.99+%

Nickel(II) bromide anhydrous

Nickel-bromid

Nickel Bromide, Anhydrous

NICKEL(II) BROMIDE ANHYDROUS FOR SYNTHES

Nickel(II) bromide,99%

Nickel dibromide

"Nickel bromide, anhydrous/ 99%"

Nickel(Ⅱ) bromide

Nickel(II)bromide,anhydrous(99+%-Ni)

Dibromonickel(II)

Nickel(II) dibromide

Nickeleus bromide

Nickel Bromide Hydrate 98+%

Nickel Bromide, Anhydrous 99%

NICKEL BROMATE ISO 9001：2015 REACH

Nickel(II) bromide 22-25%aq.

Nickel(II) bromide 22-25%aq.[N/A]

13462-88-9

NiBr2稾H2O

Catalysis and Inorganic Chemistry

Crystal Grade Inorganics

Materials Science

Metal and Ceramic Science

Nickel

Nickel Salts

metal halide

Crystal Grade Inorganics

Metal and Ceramic Science

Nickel Salts

NickelMetal and Ceramic Science

Salts

Catalysis and Inorganic Chemistry

Chemical Synthesis