(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE

Product Name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
CAS No.: 82499-43-2
Chemical Name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
Synonyms: (bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl;bicycloheptadiene(diphenylphosphino)butane rhodium BF4;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4;(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE;bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate
CBNumber: CB2698915
Molecular Formula: C35H36BF4P2Rh
Formula Weight: 708.32
MOL File: 82499-43-2.mol

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Property

Melting point:: 210 °C (dec.)(lit.)
storage temp.: Inert atmosphere,2-8°C
solubility: insol Et2O, pentane; sol CH2Cl2, MeOH, etc

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 341126
Product name: (Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate
Packaging: 100mg
Price: $82.8
Updated: 2024/03/01

TRC

Product number: B382845
Product name: (Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate
Packaging: 10mg
Price: $55
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: OGM0000781
Product name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
Purity: 95.00%
Packaging: 1G
Price: $809.55
Updated: 2021/12/16

BLDpharm

Product number: BD246784
Product name: (Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate
Purity: 98%
Packaging: 100mg
Price: $99
Updated: 2021/12/16

Arctom

Product number: AS556302
Product name: (Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate
Purity: 98%
Packaging: 100mg
Price: $182
Updated: 2021/12/16

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Chemical Properties,Usage,Production

Uses

(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate is a catalyst for hydrogenation, hydrosilylation, hydroboration and aldol condensation reactions.

Preparation

a solution of [Rh(nbd)acac] in THF is treated with fluoroboric acid, followed by addition of 1,4-bis(diphenylphosphino)butane (dppb). The solution becomes deep red and ether is added to precipitate the catalyst, which is then isolated by filtration. The unpurified product is generally adequately pure for most applications. Recrystallization from methanol can be performed to obtain orange needles of [Rh(nbd)(dppb)]BF4. Although air-sensitive in solution, the crystalline complex is indefinitely stable when prepared pure and stored under N2 or Ar below 0 °C. A convenient preparation of the corresponding trifluoromethanesulfonate has been described. The cyclooctadiene (cod) analog has been characterized by X-ray crystallography, and the dynamic solution structure of related systems has been studied by multinuclear NMR techniques.

reaction suitability

core: rhodium
reagent type: catalyst

storage

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE should store under argon in freezer; stable as solid; solutions are air sensitive. Literature describes the use of perchlorate salts but their use cannot be recommended due to risk of detonation. Use in a fume hood.

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Suppliers

China 35 Switzerland 1 United States 3 Global 39

Alfa Chemistry

Tel: 1-516-6625404
Fax: 1-516-927-0118
Email: support@alfa-chemistry.com
Country: United States
ProdList: 9171
Advantage: 60

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

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View Lastest Price from (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE manufacturers

Career Henan Chemical Co

Product: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE 82499-43-2
Price: US $2.00/g
Min. Order: 1g
Purity: 95~99.9%
Supply Ability: 5KG
Release date: 2020-03-05

82499-43-2, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATERelated Search:

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE 1,4-Bis(diphenylphosphino)butane METHYLPHOSPHINE BORANE COMPLEX BORANE-DIPHENYLPHOSPHINE COMPLEX 2,5-Norbornadiene 1,4-BIS(DIMETHYLPHOSPHINO)BUTANE

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE

(bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl

(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4

bicycloheptadiene(diphenylphosphino)butane rhodium BF4

bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate

82499-43-2

C35H36BF4P2Rh

Catalysis and Inorganic Chemistry

Chemical Synthesis

Rhodium