Lithium azide

Product Name: Lithium azide
CAS No.: 19597-69-4
Chemical Name: Lithium azide
Synonyms: LITHIUM AZIDE;ution in water;Lthium triazide;lithium triazide;LiN3 (20% in H2O);lithiumazide(li(n3));lithium azide solution;ithium azide, pure, 20% soL;LithiuM Azide (Aqueous Solution);LITHIUM AZIDE ISO 9001：2015 REACH
CBNumber: CB2739539
Molecular Formula: LiN3
Formula Weight: 48.96
MOL File: 19597-69-4.mol

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Lithium azide Property

Melting point:: decomposes at 115–298℃ [CRC10]
Boiling point:: 103 °C
Density: 1.088 g/mL at 25 °C
solubility: soluble in Water
form: Liquid
color: Clear colorless
Water Solubility: g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05]
EPA Substance Registry System: Lithium azide (Li(N3)) (19597-69-4)

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Safety

Hazard Codes: T+
Risk Statements: 26/27/28-32
Safety Statements: 23-36/37/39-45-36/37-28
RIDADR: UN 3287 6.1/PG 2
WGK Germany: 3
HazardClass: 4.1
HS Code: 28500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H311Toxic in contact with skin
Precautionary statements: P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 480525
Product name: Lithium azide solution
Purity: 20 wt. % in H2O
Packaging: 25g
Price: $309
Updated: 2024/03/01

Sigma-Aldrich

Product number: 480525
Product name: Lithium azide solution
Purity: 20 wt. % in H2O
Packaging: 100g
Price: $650
Updated: 2024/03/01

TRC

Product number: L469095
Product name: LithiumAzide(~20%inWater)
Packaging: 5g
Price: $120
Updated: 2021/12/16

TRC

Product number: L469095
Product name: LithiumAzide(~20%inWater)
Packaging: 25g
Price: $275
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0004395
Product name: LITHIUM AZIDE
Purity: 95.00%
Packaging: 25G
Price: $1200.99
Updated: 2021/12/16

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Lithium azide Chemical Properties,Usage,Production

Chemical Properties

clear colorless solution

Uses

Lithium azide is the lithium salt of Hydrazoic acid and is used to carry out azidolysis reactions (in Acetonitrile), as well as ring opening reactions of aromatics such as Styrene oxide (S687795).

Preparation

With gentle warming, NaN3 (91.30 g.) and LiSO4-H2O (1.41 g.) are dissolved in 7 ml. of H2O. Then 35 ml. of 96% alcohol is added with shaking. The solution is filtered after ten minutes and the residue of Na2SO4 and LiSO4 washed with alcohol. The filtrate and wash solutions are evaporated on a water bath and dried in a drying oven at 80°C. This crude product is digested at 35°C for two minutes with 10 ml. of 96% alcohol and filtered, and the solution is dried as described above. The yield is 0.6 g of 99.5% Lithium azide.

Purification Methods

Digest ~1g with 15mL of 96% EtOH at 35o, filter and dry it in air at temperatures below 80o. Store it in a cool place and treat it as potentially explosive. Its solubility in H2O is 66.4% at16o, and 20.26% at16o in EtOH. [Hofmann-Bang Acta Chem Scand 11 581 1957, Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 581 1963.]

Lithium azide Preparation Products And Raw materials

Raw materials

Preparation Products

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Lithium azide Suppliers

Belgium 1 China 42 France 1 Germany 1 India 5 Japan 1 Slovakia 1 Switzerland 1 United Kingdom 2 United States 10 Global 65

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Sigma-Aldrich

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19597-69-4, Lithium azideRelated Search:

BARIUM AZIDE Lithium hydroxide Magnesium nitride Silver azide TITANIUM NITRIDE Silicon nitride Rubidium azide IODINEAZIDE Tetrabutylammonium azide CESIUM AZIDE Lithium chloride Lithium sulfide potassium azide Calcium azide Copper(I) azide LITHIUM NITRIDE Lithium azide Lithium amide

LITHIUM AZIDE

lithiumazide(li(n3))

lithium triazide

LITHIUM AZIDE, 20 WT. % SOLUTION IN WATE R

Lithium azide, 20% solution in water, pure

lithium azide solution

Lithium azide,pure,20% solution in water

Lithium azide, moistened with ca 10% methanol,99%

LithiuM azide, 20 wt.% solution in H2O

LithiuM Azide (Aqueous Solution)

LithiuM azide solution 20 wt. % in H2O

Lthium triazide

Lithium azide, 20% Solution in Water

ithium azide, pure, 20% soL

ution in water

LITHIUM AZIDE ISO 9001：2015 REACH

Lithium azide, 20% w/w, solution in water

LITHIUM AZIDE SOLUTION 20% W/W IN WATER

LiN3 (20% in H2O)

19597-69-4

LiN3

C-X Bond Formation (Non-Halogen)

Synthetic Reagents

Azidation/Diazo Transfer

Inorganics

Azide SourcesMetal and Ceramic Science

Azidation/Diazo TransferChemical Ligation

Click Chemistry

C-X Bond Formation (Non-Halogen)

Lithium Salts

Salts

Synthetic Reagents