Triethylphosphine
- Product Name
- Triethylphosphine
- CAS No.
- 554-70-1
- Chemical Name
- Triethylphosphine
- Synonyms
- triethylphosphane;PEt3;Et3P;tl409;(C2H5)3P;Cytop? 320;CYTOP(R) 320;AURORA KA-1111;HISHICOLIN P-2;Triethylphophine
- CBNumber
- CB2753331
- Molecular Formula
- C6H15P
- Formula Weight
- 118.16
- MOL File
- 554-70-1.mol
Triethylphosphine Property
- Melting point:
- -88°C
- Boiling point:
- 127-128 °C(lit.)
- Density
- 0.88 g/mL at 20 °C
- refractive index
- n20/D 1.456(lit.)
- Flash point:
- 1 °F
- form
- liquid
- color
- colorless
- Odor
- vile, nauseating odor.stench
- Water Solubility
- Insoluble in water.
- Sensitive
- Air & Moisture Sensitive
- Merck
- 14,9675
- BRN
- 969170
- InChIKey
- RXJKFRMDXUJTEX-UHFFFAOYSA-N
- CAS DataBase Reference
- 554-70-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Phosphine, triethyl-(554-70-1)
- EPA Substance Registry System
- Phosphine, triethyl- (554-70-1)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34-67-17-40-37-19
- Safety Statements
- 26-36/37/39-45-7/9-33-16
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 3
- RTECS
- SZ3400000
- F
- 10-13-23
- TSCA
- Yes
- HazardClass
- 4.2
- PackingGroup
- I
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H250Catches fire spontaneously if exposed to air
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378In case of fire: Use … for extinction.
N-Bromosuccinimide Price
- Product number
- 245275
- Product name
- Triethylphosphine
- Purity
- 99%
- Packaging
- 5g
- Price
- $128
- Updated
- 2024/03/01
- Product number
- 245275
- Product name
- Triethylphosphine
- Purity
- 99%
- Packaging
- 25g
- Price
- $606
- Updated
- 2024/03/01
- Product number
- 030177
- Product name
- Triethylphosphine
- Purity
- 97%
- Packaging
- 5g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 030177
- Product name
- Triethylphosphine
- Purity
- 97%
- Packaging
- 25g
- Price
- $514
- Updated
- 2024/03/01
- Product number
- 15-6300
- Product name
- Triethylphosphine, 99%
- Packaging
- 5g
- Price
- $73
- Updated
- 2024/03/01
Triethylphosphine Chemical Properties,Usage,Production
Chemical Properties
Colorless Transparent Liquid
Uses
suzuki reaction
Uses
Triethylphosphine is used as a ligand for arylation. It is used in organic synthesis.
Uses
In organic syntheses.
Definition
ChEBI: Triethylphosphine is a tertiary phosphine.
Safety Profile
Highly flammable liquid. Reactswith oxygen at low temperatures to form an explosiveproduct. When heated to decomposition it emits toxicfumes of POx.
Synthesis
Triethylphosphine is prepared most conveniently by the reaction of excess Grignard reagent on phosphorus trichloride or triphenylphosphite.
3CH3CH2MgBr + PCl3 → (CH3CH2)3P + 3MgBrCl
3CH3CH2MgBr + P(OC6H5)3 → P(CH3CH2)3 + 3C6H5-OMgCl
Purification Methods
All operations should be carried out in an efficient fume cupboard because it is flammable, toxic and has a foul odour. Purify the phosphine by fractional distillation at atmospheric pressure in a stream of dry N2, as it is oxidised by air to the oxide. In 300% excess of CS2 it forms Et3PCS2 (m 118-120o crystallising from MeOH) which decomposes in CCl4 to give Et3PS as a white solid m 94o when recrystallised from EtOH. [Sorettas & Isbell J Org Chem 27 273 1962, Henderson & Streuli J Am Chem Soc 82 5791 1960, pK: Henderson & Streuli J Am Chem Soc 82 5791 1960, see also trimethylphosphine.] Store it in sealed vials under N2. Alternatively, dissolve it in Et2O and shake it with a solution of AgI and KI to form the insoluble complex. Filter off the complex, dry it over P2O5 and the Et3P is regenerated by heating the complex in a tube attached to a vacuum system. [Hewitt & Holliday J Chem Soc 530 1953, Schettas & Isbell J Org Chem 27 2573 1962, Kosolapoff Organophosphorus Compounds, Wiley p 31 1950, Beilstein 4 IV 3431.]
Triethylphosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Triethylphosphine manufacturers
- Product
- Triethylphosphine 554-70-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100tons
- Release date
- 2023-09-25
- Product
- Triethylphosphine 554-70-1
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1Kg
- Purity
- 98％
- Supply Ability
- 5Kg
- Release date
- 2024-07-26
- Product
- Triethylphosphine 554-70-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2023-03-14