ChemicalBook > CAS DataBase List > [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester

Product Name
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester
CAS No.
13684-56-5
Chemical Name
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester
Synonyms
EP-475;KEMIFAM;Betanex;SN-38107;Bentanex;synbetand;Tiancaian;BETANEX(R);BETANAL AM;esmedipham
CBNumber
CB2762504
Molecular Formula
C16H16N2O4
Formula Weight
300.31
MOL File
13684-56-5.mol
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[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester Property

Melting point:
120 °C
Boiling point:
441.54°C (rough estimate)
Density 
1.1782 (rough estimate)
refractive index 
1.6240 (estimate)
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
12.96±0.70(Predicted)
color 
White to Off-White
Water Solubility 
7mg/L(room temperature)
BRN 
2395716
LogP
3.390
CAS DataBase Reference
13684-56-5(CAS DataBase Reference)
NIST Chemistry Reference
Desmedipham(13684-56-5)
EPA Substance Registry System
Desmedipham (13684-56-5)
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Safety

Hazard Codes 
N
Risk Statements 
50/53
Safety Statements 
60-61
RIDADR 
UN 3077
WGK Germany 
2
RTECS 
FD0425000
HS Code 
29242990
Toxicity
LC50 (96-hour) for rainbow trout 3.8 mg/L and bluegill sunfish 13.4 mg/L (Hartley and Kidd, 1987); acute oral LD50 of pure desmedipham and the formulated product for rats 10,300 and 3,700 mg/kg, respectively (Ashton and Monaco, 1991).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45426
Product name
Desmedipham
Purity
PESTANAL
Packaging
50mg
Price
$109
Updated
2024/03/01
TRC
Product number
D282100
Product name
Desmedipham
Packaging
500mg
Price
$145
Updated
2021/12/16
TRC
Product number
D282100
Product name
Desmedipham
Packaging
25g
Price
$1185
Updated
2021/12/16
AK Scientific
Product number
S367
Product name
Desmedipham,tech.
Packaging
1g
Price
$98
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0077703
Product name
3-ETHOXYCARBONYLAMINOPHENYL-N-PHENYL-CARBAMATE
Purity
95.00%
Packaging
5G
Price
$909.56
Updated
2021/12/16
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[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester Chemical Properties,Usage,Production

Chemical Properties

Colorless, crystalline solid.

Uses

Selective systemic herbicide used to control broad-leaved weeds such as buckwheat, chickweed, fiddleneck, kochnia, mustard, pigweed and ragweed.

Uses

Desmedipham is a carbanilate based herbicide used in the weed control programs in sugar beet.

Uses

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester is a carbanilate based herbicide used in the weed control programs in sugar beet.

Definition

ChEBI: A carbamate ester that is phenylcarbamic acid in which the hydrogen of the hydroxy group has been replaced by a 3-[(ethoxycarbonyl)amino]phenyl group. It is an agrochemical used as a herbicide.

Potential Exposure

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester is a postemergence bis-carbamate herbi- cide used on sugarbeets to control annual weeds such as pigweed, wild mustard, lamb’s quarters, nightshade, chick- weed, buckwheat, goosefoot, ragweed, fiddleneck, and kochia

Environmental Fate

Soil. Degrades in soil forming the intermediate 3-hydroxycarbanilate (Worthing and Hance, 1991). The reported half-lives in soil are 70 days, 20 hours and 10 minutes at pH values of 5, 7 and 9, respectively (Worthing and Hance, 1991).
Plant. In sugar beets, m-aminophenol and ethyl-N-(3-hydroxyphenyl)-carbamate were identified as metabolites (Hartley and Kidd, 1987).

Shipping

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Esters with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interac- tion of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Carbamates are incompatible with reducing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. Forms Carbon monoxide and toxic nitrogen oxides when heated to decomposition.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester Suppliers

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View Lastest Price from [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester manufacturers

Hebei Duling International Trade Co. LTD
Product
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester 13684-56-5
Price
US $9.90/kg
Min. Order
1kg
Purity
95%
Supply Ability
1000kg
Release date
2022-10-17
Longyan Tianhua Biological Technology Co., Ltd
Product
Desmedipham 13684-56-5
Price
US $28.00/Kg/Bag
Min. Order
10Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-10-29
Career Henan Chemical Co
Product
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester 13684-56-5
Price
US $1.00/KG
Min. Order
1IU
Purity
99%
Supply Ability
100kg
Release date
2019-12-24

13684-56-5, [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl esterRelated Search:

IMINOCTADINE TRIS(ALBESILATE) Phenyl carbamate Urethane METHYL (3-HYDROXYPHENYL)CARBAMATE betamix ETHYL (3-HYDROXYPHENYL)CARBAMATE PHENISOPHAM [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester

  • BETANAL AM
  • BETANAL AM(R)
  • BETANEX(R)
  • KEMIFAM
  • ETHYL-M-HYDROXYCARBANILATE CARBANILATE(ESTER)
  • ETHYL 3-PHENYLCARBAMOYLOXYPHENYLCARBAMATE
  • EP-475
  • DESMEDIPHAM
  • m-carbaniloyloxy-carbanilicaciethylester
  • phenylcarbamoyloxyphenyl-carbamicaciethylester
  • Schering 38107
  • schering38107
  • synbetand
  • (3-ETHOXYCARBONYLAMINOPHENYL) ANILINOFORMATE
  • 3-ETHOXYCARBONYLAMINOPHENYL-N-PHENYL-CARBAMATE
  • DESMEDIPHAM PESTANAL (ETHYL- 3-PHENYLCAR
  • desmedipham ethyl 3-phenylcarbamoyloxyphenylcarbamate
  • Tiancaian
  • DESMEDIPHAM, 250MG, NEAT
  • ETHYLMETA-HYDROXYCARBANILATECARBANILATE
  • [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester
  • 3-(Carbaniloyloxy)carbanilic acid ethyl ester
  • Bethanol 475
  • N-[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester
  • 3-((ethoxycarbonyl)amino)phenyl ester
  • SN-38107
  • (3-(((phenylamino)carbonyl)oxy)phenyl)-carbamicaciethylester
  • 3-(Aethoxycarbonylaminophenyl)-N-phenyl-carbamat
  • 3-Ethoxycarbnylaminophenyl N-Phenylcarbamate
  • Bentanex
  • Betamix70WP
  • Betanal-475
  • betanalam11
  • Betanex
  • N-[3-[anilino(oxo)methoxy]phenyl]carbamic acid ethyl ester
  • Betanex70WP
  • Carbamic acid, [3-[[(phenylamino)carbonyl]oxy]phenyl]-, ethyl ester
  • Carbamic acid, phenylcarbamoyloxyphenyl-, ethyl ester
  • Carbamicacid,N-phenyl-,3-((ethoxycarbonyl)amino)phenylester
  • carbamicacid,phenylcarbamoylphenyl-,ethylester
  • Carbanilic acid, m-carbaniloyloxy-, ethyl ester
  • Carbanilic acid, m-hydroxy-, ethyl ester, carbanilate (ester)
  • carbanilicacid,m-hydroxy-,ethylester,carbanilate(ester)
  • Ethyl m-hydroxycarbanilate carbanilate
  • Ethyl N-[3-(N'-phenylcarbamoyloxy)phenyl]carbamate
  • Ethyl N-[3-(N-phenylcarbamoyloxy)phenyl]carbamate
  • Ethyl phenylcarbamoyloxyphenylcarbamate
  • ethylm-hydroxycarbanilatecarbanilate
  • ethylphenylcarbamoyloxyphenylcarbamate
  • [3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester-D5
  • Desmedipham @100 μg/mL in MeOH
  • Desmedipham Standard
  • Carbamic acid, N-[3-[[(phenylamino)carbonyl]oxy]phenyl]-, ethyl ester
  • esmedipham
  • Phloroglucinol Impurity 218
  • Desmedipham-D5
  • 13684-56-5
  • 3684-56-5