ChemicalBook > CAS DataBase List > METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID

METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID

Product Name: METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
CAS No.: 167300-06-3
Chemical Name: METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
Synonyms: 3-(Methoxycarbonyl);METHY-2-METHYL-5-CARBOXYLICBENZOIC ACID;3-(Methoxycarbonyl)-4-Methylbenzoic acid;4-METHYL-3-(METHOXYCARBONYL)BENZOIC ACID;METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID;1,3-Benzenedicarboxylic acid, 4-methyl-, 3-methyl ester
CBNumber: CB2781790
Molecular Formula: C10H10O4
Formula Weight: 194.18
MOL File: 167300-06-3.mol

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METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Property

Boiling point:: 349.9±30.0 °C(Predicted)
Density: 1.243±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 4.00±0.10(Predicted)
Appearance: White to off-white Solid

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Safety

HS Code: 2917399590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M331698
Product name: 3-(Methoxycarbonyl)-4-methylbenzoicAcid
Packaging: 1g
Price: $310
Updated: 2021/12/16

AK Scientific

Product number: 8530AA
Product name: 3-(Methoxycarbonyl)-4-methylbenzoicacid
Packaging: 250mg
Price: $139
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0299451
Product name: METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
Purity: 95.00%
Packaging: 5MG
Price: $496.75
Updated: 2021/12/16

AK Scientific

Product number: 8530AA
Product name: 3-(Methoxycarbonyl)-4-methylbenzoicacid
Packaging: 5g
Price: $784
Updated: 2021/12/16

Ambeed

Product number: A213451
Product name: 3-(Methoxycarbonyl)-4-methylbenzoicacid
Purity: 98%
Packaging: 250mg
Price: $101
Updated: 2021/12/16

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METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Chemical Properties,Usage,Production

Synthesis

675148-96-6

167300-06-3

Methyl 5-formyl-2-methylbenzoate (268 mg, 1.5 mmol) was used as starting material and dissolved in N,N-dimethylformamide (DMF, 5 mL). Subsequently, Oxone (1.110 g, 1.8 mmol) was added to the solution and the reaction mixture was stirred at room temperature for 18 hours. After completion of the reaction, the reaction mixture was diluted with ethyl acetate (EtOAc, 10 mL) followed by 0.5 M aqueous hydrochloric acid (20 mL). The organic phase was separated, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to afford the target product 3-(methoxycarbonyl)-4-methylbenzoic acid as an off-white powder (247 mg, 1% yield). The structure of the product was confirmed by 1H NMR (500 MHz, DMSO-d6): δ 8.38 (d, J = 1.8 Hz, 1H), 8.01 (dd, J = 7.9, 1.9 Hz, 1H), 7.48 (d, J = 8.0 Hz, 1H), 3.86 (s, 3H), 2.59 (s, 3H).

References

[1] Patent: WO2018/89433, 2018, A1. Location in patent: Paragraph 00317

METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID manufacturers

Career Henan Chemical Co

Product: METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID 167300-06-3
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000kg
Release date: 2020-01-13

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