2-BROMO-3-METHYLBENZONITRILE

Product Name: 2-BROMO-3-METHYLBENZONITRILE
CAS No.: 263159-64-4
Chemical Name: 2-BROMO-3-METHYLBENZONITRILE
Synonyms: 2-BROMO-3-METHYLBENZONITRILE;Benzonitrile, 2-bromo-3-methyl-;2-BroMo-3-Methylbenzonitrile 97%;2-Bromo-3-methylbenzonitrile
CBNumber: CB2831840
Molecular Formula: C8H6BrN
Formula Weight: 196.04
MOL File: 263159-64-4.mol

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2-BROMO-3-METHYLBENZONITRILE Property

Melting point:: 67-71 °C
Boiling point:: 286.8±28.0 °C(Predicted)
Density: 1.51±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: powder
Appearance: White to off-white Solid

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Safety

Hazard Codes: Xn
Risk Statements: 22
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 697176
Product name: 2-Bromo-3-methylbenzonitrile
Purity: 97%
Packaging: 5g
Price: $112
Updated: 2025/07/31

Sigma-Aldrich

Product number: 697176
Product name: 2-Bromo-3-methylbenzonitrile
Purity: 97%
Packaging: 1g
Price: $40
Updated: 2023/06/20

TRC

Product number: B697040
Product name: 2-Bromo-3-methylbenzonitrile
Packaging: 500mg
Price: $65
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3737-9-01
Product name: 2-Bromo-3-methylbenzonitrile
Purity: 98%
Packaging: 250mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB42113
Product name: 2-Bromo-3-methylbenzonitrile
Packaging: 1g
Price: $65
Updated: 2021/12/16

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2-BROMO-3-METHYLBENZONITRILE Chemical Properties,Usage,Production

Synthesis

101421-85-6

263159-64-4

Step 2: To a solution of 2-bromo-3-methylbenzamide (12 g, 56.1 mmol) in N,N-dimethylformamide (DMF, 100 mL) was slowly added a solution of cyanuric chloride (15.47 g, 84.1 mmol) in DMF (50 mL) at 0 °C and under nitrogen protection. After addition, the reaction mixture was brought to room temperature and stirred overnight. Thin layer chromatography (TLC, unfolding agent: petroleum ether/ethyl acetate = 1:1) was monitored to show complete reaction. The reaction mixture was poured into water (500 mL) and extracted with ethyl acetate (EtOAc, 200 mL x 2). The organic phases were combined and washed sequentially with saturated aqueous sodium carbonate (200 mL × 2), saturated saline (200 mL × 4), dried over anhydrous sodium sulfate, and concentrated under reduced pressure to afford 2-bromo-3-methylbenzonitrile (11 g, 100% yield) as an off-white solid.1H NMR (400 MHz, CDCl3): δ 7.51-7.45 (m, 2H), 7.33 -7.29 (m, 1H), 2.47 (s, 3H).

References

[1] Patent: WO2013/132376, 2013, A1. Location in patent: Page/Page column 226
[2] Organic Letters, 2018, vol. 20, # 3, p. 728 - 731
[3] Bioorganic and Medicinal Chemistry Letters, 2011, vol. 21, # 2, p. 644 - 651
[4] Patent: WO2011/22337, 2011, A1. Location in patent: Page/Page column 73-74

2-BROMO-3-METHYLBENZONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-3-METHYLBENZONITRILE Suppliers

China 63 India 3 Switzerland 1 United Kingdom 3 United States 8 Global 78

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263159-64-4, 2-BROMO-3-METHYLBENZONITRILERelated Search:

2-Chloro-4-methyl-5-nitro-benzonitrile 2-IODO-3-METHYLBENZONITRILE 2-ethyl-5-nitrobenzonirile 2-METHOXY-4-(TRIFLUOROMETHOXY)BENZONITRILE 2-broMo-4-hydroxybenzonitrile 2-BROMO-5-METHYLBENZONITRILE 3-Bromo-4-methylbenzonitrile,3-Bromo-4-methylbenzonitrile 98%,3-BROMO-4-METHYLBENZONITRILE 97 3-BROMO-6-METHYLBENZONITRILE,5-BROMO-2-METHYLBENZONITRILE,5-BROMO-2-METHYLBENZONITRILE,98% 4-BROMO-3-METHYLBENZONITRILE,4-BROMO-3-METHYLBENZONITRILE 98% 4-Bromo-2-Methylbenzonitrile97%,4-BROMO-2-METHYLBENZONITRILE 3-BROMO-5-METHYLBENZONITRILE 2-BROMO-6-METHYLBENZONITRILE 3-BROMO-2-METHYLBENZONITRILE 2-BROMO-4-METHYLBENZONITRILE 3-AMINO-4-BROMO-5-METHYLBENZONITRILE 2-BROMO-3-METHYLBENZONITRILE 2-Bromo-3-(trifluoromethyl)benzonitrile 3-(2-OXOPROPYLAMINO)-4-BROMO-5-METHYLBENZONITRILE

2-BROMO-3-METHYLBENZONITRILE

Benzonitrile, 2-bromo-3-methyl-

2-BroMo-3-Methylbenzonitrile 97%

2-<WBR>Bromo-<WBR>3-<WBR>methylbenzonitrile

263159-64-4

Aromatic Nitriles

Bromine Compounds

C8 to C9

Cyanides/Nitriles

Nitrogen Compounds