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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE

Product Name
((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
CAS No.
116399-78-1
Chemical Name
((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
Synonyms
(E)-(4-Chlorobut-2-en-2-yl)trimethylsilane;((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE;(E)-(3-Chloro-1-methyl-1-propenyl)trimethylsilane;Silane, (3-chloro-1-methyl-1-propen-1-yl)trimethyl-
CBNumber
CB2838869
Molecular Formula
C7H15ClSi
Formula Weight
162.73
MOL File
116399-78-1.mol
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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Property

Boiling point:
167.7±15.0 °C(Predicted)
Density 
0.881±0.06 g/cm3(Predicted)
solubility 
freely sol organic solvents.
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ORS0001263
Product name
((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
Purity
95.00%
Packaging
5MG
Price
$497.83
Updated
2021/12/16
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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Chemical Properties,Usage,Production

Physical properties

bp 92–94°C/74 mmHg.

Uses

(E)-(3-Chloro-1-methyl-1-propenyl)- trimethylsilane acts as the alkylative equivalent of 3-buten-2-one (methyl vinyl ketone), permitting regiospecific enolate alkylation under nonequilibrating conditions. As a vinylsilane it can be converted,via the corresponding α,β-epoxy silane, into a 3-oxobutyl moiety, and hence used in an alkylative equivalent of Robinson annulation.Application of such methodology can be seen (eq 1) in the preparation of bicyclodecenones via the alkylation of dihydrocarvone with this reagent.Apart from this application, and its use in combination with potassium iodide, it has seen little use so far.

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Suppliers

China 1 United States 4 Global 5
Alfa Chemistry
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Alchem Pharmtech,Inc.
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sales@alchempharmtech.com
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116399-78-1, ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANERelated Search:

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE 2-PROPENYLTRIMETHYLSILANE

  • ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
  • (E)-(3-Chloro-1-methyl-1-propenyl)trimethylsilane
  • (E)-(4-Chlorobut-2-en-2-yl)trimethylsilane
  • Silane, (3-chloro-1-methyl-1-propen-1-yl)trimethyl-
  • 116399-78-1