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Phosphorus trioxide

Product Name
Phosphorus trioxide
CAS No.
1314-24-5
Chemical Name
Phosphorus trioxide
Synonyms
Phosphorus trioxide;phosphorous anhydride;Diphosphorus trioxide;Phosphorus trioxide ISO 9001:2015 REACH
CBNumber
CB2852146
Molecular Formula
H4O5P2
Formula Weight
145.976282
MOL File
1314-24-5.mol
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Phosphorus trioxide Property

Melting point:
23.8°
Boiling point:
bp 173.1° in nitrogen atm
Density 
d421 2.135
solubility 
reacts with H2O
form 
colorless monoclinic crystals or liquid
color 
colorless monoclinic crystals, crystalline or liquid
Water Solubility 
slowly forms H3PO3 in cold H2O; reacts violently in hot H2O forming red P, PH3, and H3PO4 [MER06]
crystal system
Monoclinic
Space group
P21/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6430.78870.681290106.01900.3321
EPA Substance Registry System
Phosphorus trioxide (1314-24-5)
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Safety

RIDADR 
2578
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ING0013192
Product name
PHOSPHORUS TRIOXIDE
Purity
95.00%
Packaging
5MG
Price
$499.4
Updated
2021/12/16
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Phosphorus trioxide Chemical Properties,Usage,Production

Chemical Properties

transparent crystal(s); monoclinic or colorless liquid; disproportionates to red P and P2O4if heated above 210°C [MER06]

General Description

White crystalline solid or a liquid (melting point 24°C). Density 2.14 g / cm3. Toxic and corrosive. May severely irritate skin and eyes. Used to make other chemicals.

Air & Water Reactions

Fumes in air. Reacts slowly with cold water to give phosphorous acid. Reacts vigorously with hot water to generate red phosphorus, phosphine (highly toxic and flammable) and phosphoric acid [Merck 11th ed. 1989].

Reactivity Profile

Phosphorus trioxide reacts exothermically with bases. Melted Phosphorus trioxide readily ignites in air. Instantly ignites with a flame of almost blinding brilliance when thrown into oxygen at 50-60°C [J. Am. Chem. Soc. 125:347. 1924]. Incompatible with ammonia, disulfur dichloride, halogens, oxygen, phosphorus pentachloride, sulfur, sulfuric acid, water [Bretherick, 5th ed., 1995, p. 1778].

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Phosphorus trioxide Preparation Products And Raw materials

Raw materials

Preparation Products

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Phosphorus trioxide Suppliers

Shanghai ChuCheng Trade Co., Ltd.
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+86-029-89586680 +86-18192503167
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Hubei Jusheng Technology Co.,Ltd.
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027-59599243
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Hubei xin bonus chemical co. LTD
Tel
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1314-24-5, Phosphorus trioxideRelated Search:


  • Diphosphorus trioxide
  • phosphorous anhydride
  • Phosphorus trioxide
  • Phosphorus trioxide ISO 9001:2015 REACH
  • 1314-24-5
  • O3P2