POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Product Name: POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
CAS No.: 54575-49-4
Chemical Name: POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
Synonyms: K-selectride;K-SELECTRIDE(R);insuresealtmbottle;k-selectride solution;Potassium tri-sec-butyL;K-Selectride(R) solution;Tributyl potassium borohydride;(ca. 1.0Mol/L in Tetrahydrofuran);Potassium tri(s-butyl)borohydride;Potassium tri-sec-butylborohyride
CBNumber: CB3113796
Molecular Formula: C12H25BK
Formula Weight: 219.24
MOL File: 54575-49-4.mol

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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Property

Density: 0.913 g/mL at 25 °C
Flash point:: 1 °F
storage temp.: Flammables + water-Freezer (-20°C)e area
form: Solution
color: Clear slightly yellow
Sensitive: moisture sensitive
EPA Substance Registry System: Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)

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Safety

Hazard Codes: F,C
Risk Statements: 11-15-34-37-19-14/15-40
Safety Statements: 16-26-36/37/39-43-45
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 3
F: 10
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 220760
Product name: K-Selectride? solution
Purity: 1.0 M potassium tri-sec-butylborohydride in THF
Packaging: 100ml
Price: $207
Updated: 2024/03/01

Sigma-Aldrich

Product number: 220760
Product name: K-Selectride? solution
Purity: 1.0 M potassium tri-sec-butylborohydride in THF
Packaging: 800ml
Price: $886
Updated: 2024/03/01

Strem Chemicals

Product number: 19-1965
Product name: Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
Packaging: 0.1mole
Price: $274
Updated: 2024/03/01

Strem Chemicals

Product number: 19-1965
Product name: Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
Packaging: 0.5mole
Price: $1091
Updated: 2024/03/01

TRC

Product number: S247980
Product name: K-SelectrideSolution(1.0 MinTHF)
Packaging: 100ml
Price: $385
Updated: 2021/12/16

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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties,Usage,Production

Description

Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes.

Chemical Properties

clear slightly yellow solution

Uses

Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.

Uses

Reducing reagent

Reactant for:

Preparation of a PCP-pincer palladium hydride-K-Selectride complex
Formation of P-H, P-C, and C-H bonds by hydride attack
Stereoselective conjugate hydride reduction reactions

Uses

Mild reducing agents in organic synthesis.

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Suppliers

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View Lastest Price from POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE manufacturers

Career Henan Chemical Co

Product: POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE 54575-49-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 97%-99.9%
Supply Ability: 100kg
Release date: 2019-12-26

54575-49-4, POTASSIUM TRI-SEC-BUTYLBOROHYDRIDERelated Search:

Potassium hydride Potassium borohydride KS-SELECTRIDE(R) TRI-SEC-BUTYLBORANE TRIMETHYLBORON Triethylborane POTASSIUM TRIETHYLBOROHYDRIDE POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-

potassiumtri-sec-butylborohydride,calselect?k,

potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran

K-SELECTRIDE(R)

Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal

potassiumtri-sec-butylborohydride,calselectk,intetrahydrofur

(ca. 1.0Mol/L in Tetrahydrofuran)

PotassiuM Tri-sec-butylborohydride&nbsp

K-selectride

Potassium tri-sec-butyL

Potassium tri(s-butyl)borohydride

Potassium tris(s-butyl)hydroborate(1-)

Potassium tri-sec-butylhydroborate(1-)

K-Selectride(R) solution 1.0 M potassiuM tri-sec-butylborohydride in THF

Potassium Tri-sec- Butylborohydride in THF

potassium tri-sec-butylhydroborate

Potassium tri-sec-butylborohydride, in tetrahydrofuran, 1M solution

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE SOLUT ION, 1 M IN THF

K-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN

insuresealtmbottle

Potassiumtri-sec-butylborohydride1.0MinTHF

Potassium tri-sec-butylborohydride, 1 M solution in tetrahydrofuran

Potassium tri-sec-butylborohyride

Potassiumtri-sec-butylborohydride,1.0MinTHF,inSure/Sealbottle

Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)-

k-selectride solution

potassium tri-sec-butylborohydride solution

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE

Potassium Tri-sec-butylborohydride (ca. 1.0mol/L in Tetrahydrofuran)

Potassium tri-sec-butylborohydride1M solution in tetrahydrofuranAcroSeal§3

K-Selectride(R) solution

K-Selectride Solution (1.0M in THF)

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE ISO 9001：2015 REACH

Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal&trade

Tributyl potassium borohydride

M potassium tri-<I>sec</I>-butylborohydride in THF

K-Selectride? solution (POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE)

54575-49-4

C12H28BK

KCHCH3CH2CH33BH

KBCHCH3C2H53H

Borohydrides

Synthetic Reagents

B (Classes of Boron Compounds)

Tetrahydroborates

Reduction

Classes of Metal Compounds

K (Potassium) Compounds (excluding simple potassium salts)

Typical Metal Compounds

B (Classes of Boron Compounds)

Classes of Metal Compounds

K (Potassium) Compounds (excluding simple potassium salts)

Reduction

Synthetic Organic Chemistry

Tetrahydroborates

Typical Metal Compounds

metal alkyl