ChemicalBook > CAS DataBase List > POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Product Name
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
CAS No.
54575-49-4
Chemical Name
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
Synonyms
K-selectride;K-SELECTRIDE(R);insuresealtmbottle;k-selectride solution;Potassium tri-sec-butyL;K-Selectride(R) solution;Tributyl potassium borohydride;(ca. 1.0Mol/L in Tetrahydrofuran);Potassium tri(s-butyl)borohydride;Potassium tri-sec-butylborohyride
CBNumber
CB3113796
Molecular Formula
C12H25BK
Formula Weight
219.24
MOL File
54575-49-4.mol
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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Property

Density 
0.913 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
Flammables + water-Freezer (-20°C)e area
form 
Solution
color 
Clear slightly yellow
Sensitive 
moisture sensitive
EPA Substance Registry System
Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-15-34-37-19-14/15-40
Safety Statements 
16-26-36/37/39-43-45
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
3
F 
10
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
220760
Product name
K-Selectride? solution
Purity
1.0 M potassium tri-sec-butylborohydride in THF
Packaging
100ml
Price
$207
Updated
2024/03/01
Sigma-Aldrich
Product number
220760
Product name
K-Selectride? solution
Purity
1.0 M potassium tri-sec-butylborohydride in THF
Packaging
800ml
Price
$886
Updated
2024/03/01
Strem Chemicals
Product number
19-1965
Product name
Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
Packaging
0.1mole
Price
$274
Updated
2024/03/01
Strem Chemicals
Product number
19-1965
Product name
Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
Packaging
0.5mole
Price
$1091
Updated
2024/03/01
TRC
Product number
S247980
Product name
K-SelectrideSolution(1.0 MinTHF)
Packaging
100ml
Price
$385
Updated
2021/12/16
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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties,Usage,Production

Description

Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes.

Chemical Properties

clear slightly yellow solution

Uses

Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.

Uses

  • Reducing reagent

Reactant for:
  • Preparation of a PCP-pincer palladium hydride-K-Selectride complex
  • Formation of P-H, P-C, and C-H bonds by hydride attack
  • Stereoselective conjugate hydride reduction reactions

Uses

Mild reducing agents in organic synthesis.

reaction suitability

reagent type: reductant

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Suppliers

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View Lastest Price from POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE manufacturers

Career Henan Chemical Co
Product
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE 54575-49-4
Price
US $1.00/KG
Min. Order
1KG
Purity
97%-99.9%
Supply Ability
100kg
Release date
2019-12-26

54575-49-4, POTASSIUM TRI-SEC-BUTYLBOROHYDRIDERelated Search:

Potassium hydride Potassium borohydride KS-SELECTRIDE(R) TRI-SEC-BUTYLBORANE TRIMETHYLBORON Triethylborane POTASSIUM TRIETHYLBOROHYDRIDE POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

  • POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
  • potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-
  • potassiumtri-sec-butylborohydride,calselect?k,
  • potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran
  • K-SELECTRIDE(R)
  • Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal
  • potassiumtri-sec-butylborohydride,calselectk,intetrahydrofur
  • (ca. 1.0Mol/L in Tetrahydrofuran)
  • PotassiuM Tri-sec-butylborohydride&nbsp
  • K-selectride
  • Potassium tri-sec-butyL
  • Potassium tri(s-butyl)borohydride
  • Potassium tris(s-butyl)hydroborate(1-)
  • Potassium tri-sec-butylhydroborate(1-)
  • K-Selectride(R) solution 1.0 M potassiuM tri-sec-butylborohydride in THF
  • Potassium Tri-sec- Butylborohydride in THF
  • potassium tri-sec-butylhydroborate
  • Potassium tri-sec-butylborohydride, in tetrahydrofuran, 1M solution
  • POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE SOLUT ION, 1 M IN THF
  • K-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN
  • insuresealtmbottle
  • Potassiumtri-sec-butylborohydride1.0MinTHF
  • Potassium tri-sec-butylborohydride, 1 M solution in tetrahydrofuran
  • Potassium tri-sec-butylborohyride
  • Potassiumtri-sec-butylborohydride,1.0MinTHF,inSure/Sealbottle
  • Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)-
  • k-selectride solution
  • potassium tri-sec-butylborohydride solution
  • POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE
  • Potassium Tri-sec-butylborohydride (ca. 1.0mol/L in Tetrahydrofuran)
  • Potassium tri-sec-butylborohydride1M solution in tetrahydrofuranAcroSeal§3
  • K-Selectride(R) solution
  • K-Selectride Solution (1.0M in THF)
  • POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE ISO 9001：2015 REACH
  • Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal&trade
  • Tributyl potassium borohydride
  • M potassium tri-<I>sec</I>-butylborohydride in THF
  • K-Selectride? solution (POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE)
  • 54575-49-4
  • C12H28BK
  • KCHCH3CH2CH33BH
  • KBCHCH3C2H53H
  • Borohydrides
  • Synthetic Reagents
  • B (Classes of Boron Compounds)
  • Tetrahydroborates
  • Reduction
  • Classes of Metal Compounds
  • K (Potassium) Compounds (excluding simple potassium salts)
  • Typical Metal Compounds
  • B (Classes of Boron Compounds)
  • Classes of Metal Compounds
  • K (Potassium) Compounds (excluding simple potassium salts)
  • Reduction
  • Synthetic Organic Chemistry
  • Tetrahydroborates
  • Typical Metal Compounds
  • metal alkyl