Nickel(II) nitrate hexahydrate
Description Preparation References- Product Name
- Nickel(II) nitrate hexahydrate
- CAS No.
- 13478-00-7
- Chemical Name
- Nickel(II) nitrate hexahydrate
- Synonyms
- NICKEL NITRATE;NICKEL NITRATE HEXAHYDRATE;NICKEL(II) NITRATE;Nitric acid nickel(II) salt hexahydrate;Nickel (II) nitrate hexahydrate≥ 97% (Titration);NickelNitrateAr;Nickelousnitrate,N;Nickel Nitrate (Ous);NICKEL (OUS) NITRATE;NICKEL NITRATE, HYDROUS
- CBNumber
- CB3115275
- Molecular Formula
- H12N2NiO12
- Formula Weight
- 290.79
- MOL File
- 13478-00-7.mol
Nickel(II) nitrate hexahydrate Property
- Melting point:
- 56 °C(lit.)
- Boiling point:
- 137 °C
- Density
- 2.05 g/mL at 25 °C(lit.)
- Flash point:
- 137°C
- storage temp.
- Store at +5°C to +30°C.
- solubility
- 940g/l
- form
- flakes
- color
- Green to blue
- Specific Gravity
- 2.05
- PH
- 5 (50g/l, H2O, 20℃)
- Water Solubility
- 238.5 g/100 mL (20 ºC)
- Sensitive
- Hygroscopic
- Merck
- 14,6513
- Exposure limits
- ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 - Stability:
- Stable. Strong oxidizer. Incompatible with reducing agents.
- InChIKey
- AOPCKOPZYFFEDA-UHFFFAOYSA-N
- CAS DataBase Reference
- 13478-00-7(CAS DataBase Reference)
Safety
- Hazard Codes
- O,T,Xi,Xn,N
- Risk Statements
- 45-8-22-43-40-68-50/53-48/23-42/43-41-38-20/22-61-49
- Safety Statements
- 53-17-36/37-45-61-60
- RIDADR
- UN 2725 5.1/PG 3
- WGK Germany
- 3
- RTECS
- QR7300000
- TSCA
- Yes
- HS Code
- 2834 29 20
- HazardClass
- 5.1
- PackingGroup
- III
- Toxicity
- LD50 orally in Rabbit: 1620 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H315Causes skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H341Suspected of causing genetic defects
H350May cause cancer
H360May damage fertility or the unborn child
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 203874
- Product name
- Nickel(II) nitrate hexahydrate
- Purity
- 99.999% trace metals basis
- Packaging
- 20g
- Price
- $66.7
- Updated
- 2024/03/01
- Product number
- 203874
- Product name
- Nickel(II) nitrate hexahydrate
- Purity
- 99.999% trace metals basis
- Packaging
- 100g
- Price
- $222
- Updated
- 2024/03/01
- Product number
- 1.06721
- Product name
- Nickel(II) nitrate hexahydrate
- Purity
- for analysis EMSURE? ACS
- Packaging
- 100g
- Price
- $84.3
- Updated
- 2024/03/01
- Product number
- 1.06721
- Product name
- Nickel(II) nitrate hexahydrate
- Purity
- for analysis EMSURE? ACS
- Packaging
- 250g
- Price
- $112
- Updated
- 2024/03/01
- Product number
- 1.06721
- Product name
- Nickel(II) nitrate hexahydrate
- Purity
- for analysis EMSURE? ACS
- Packaging
- 1kg
- Price
- $281
- Updated
- 2024/03/01
Nickel(II) nitrate hexahydrate Chemical Properties,Usage,Production
Description
Nickel (II) nitrate hexahydrate is the hexahydrate form of the nickel (II) nitrate. Nickel nitrate (chemical formula: Ni(NO3)2) is manufactured by the reaction of nickel oxide with nitric acid. The nickel (II) nitrate hexahydrate can be used as a precursor during the manufacturing of other nickel salts and supported nickel catalysts. For example, it is the precursor for the manufacturing of nickel sulfide-reduced graphene oxide (RGO) composite powders. It can also be used for the manufacturing of nickel and nickel oxide nanocrystals impregnated O-MWCNTs which is useful in semiconductor industries. Moreover, it can also be used in electroplating and as a mordent in textile dyeing. Finally, it can be used to improve the cycling stability and rate capability o Li2MnO2.
Preparation
Nickel nitrate hexahydrate may be prepared by several methods based on the reaction of dilute nitric acid on nickel powder, nickel oxide or nickel carbonate. The reaction is exothermic and requires controlled cooling during production. The hexahydrate can be dehydrated to anhydrous salt by treatment with fuming nitric acid.
References
https://www.alfa.com/en/catalog/A15540/
https://en.wikipedia.org/wiki/Nickel(II)_nitrate
Description
Nickel (II) nitrate hexahydrate appears as green crystals and substantially soluble in water. It is stable, a strong oxidiser, and incompatible with reducing agents. It has wide industrial applications in nickel plating as catalysts and is indirectly associated with other industries of nickel alloy manufacturers, nickel miners, smelters and refiners, nickel platers, and exposure to alloys, for example, in coinage.
Chemical Properties
Green crystal
Uses
Nickel plating, manufacturing of ceramic colorsNickel(II) nitrate hexahydrate is used as a precursor in the manufacturing of other nickel salts and supported nickel catalysts. It finds use as a catalyst in organic synthesis. Further it is used in electroplating and as a mordent in textile dyeing. It is a precursor for preparing nickel sulfide-reduced graphene oxide (RGO) composite powders with high initial capacities and good cycling performance. It can be employed in the preparation of nickel and nickel oxide nanocrystals impregnated O-MWCNTs (oxygen-functionalized multi-walled carbon nanotubes) with potential applications in semiconductor industries. It finds use in improving cycling stability ad rate capability of Li2MnO3.
Uses
Nickel(II) nitrate hexahydrate may be used as a precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders, Ni(II) oxide aerogels and crystalline nickel complexes, [Ni(C6H7N3O)2(NO3)2] and [Ni(C6H7N3O)3](NO3)2·H2O.
Preparation
Emerald green crystals of the hexahydrate Ni(N03)2?6H20 crystallize
from aqueous solutions at room temperature. These are isomorphous with the corresponding
cobalt(II) salt containing the regular octahedral [Ni(H20)6]2+ ions with Ni-O distances = 2.03 A. The tetrahydrate crystallize above 54° and the dihydrate above 85.4°.
The pale green anhydrous nitrate can be obtained by dehydration of the hydrate with
dinitrogen pentoxide in fuming nitric acid or by the liquid phase reaction of dinitrogen
tetroxide with nickel carbonyl [the gas phase reaction gives the nitrite Ni(N02)2]
Ni(CO)4+2N2O4 -* Ni(N03)2+2NO+4CO
The first product of this latter rather violent reaction is the adduct Ni(NO3)2N2O4 from
which the nitrogen tetroxide is removed by heating in vacuo. It can also be prepared by the
reaction of dinitrogen tetroxide-ethyl acetate mixtures with nickel(II) chloride. The infrared
spectrum shows it to be a typical covalent nitrate. It is involatile and decomposes upon
heating in nitrogen to give the nitrite Ni(NO2)2 above 260°.
General Description
Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.
Safety Profile
Confirmed carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also NICKEL(II) NITRATE.
Purification Methods
Crystallise it from water (3.3g/mL) by partial evaporation in a desiccator. Store it in a desiccator as it is deliquescent.
Nickel(II) nitrate hexahydrate Preparation Products And Raw materials
Raw materials
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View Lastest Price from Nickel(II) nitrate hexahydrate manufacturers
- Product
- Nickel(II) nitrate hexahydrate 13478-00-7
- Price
- US $100.00/bag
- Min. Order
- 1bag
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2023-08-21
- Product
- Nickel Nitrate Hexahydrate 13478-00-7
- Price
- US $30.00/Kg/Bag
- Min. Order
- 25KG
- Purity
- 99.99%
- Supply Ability
- 200ton
- Release date
- 2021-10-18
- Product
- Nickel(II) nitrate hexahydrate 13478-00-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-09