ChemicalBook > CAS DataBase List > 4-IODOTHIOANISOLE

4-IODOTHIOANISOLE

Product Name
4-IODOTHIOANISOLE
CAS No.
35371-03-0
Chemical Name
4-IODOTHIOANISOLE
Synonyms
4-Iodothioaniole;4-Iodothiaanisole;4-IODOTHIOANISOLE;p-Iodothioanisole;Methyl p-iodophenyl sulfide;4-Iodophenyl methyl sulfide;Methyl(4-iodophenyl) sulfide;1-Iodo-4-(methylthio)benzene;1-(Methylthio)-4-iodobenzene;(4-iodophenyl)(methyl)sulfane
CBNumber
CB3124004
Molecular Formula
C7H7IS
Formula Weight
250.1
MOL File
35371-03-0.mol
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4-IODOTHIOANISOLE Property

Melting point:
40 °C
Boiling point:
262.6±23.0 °C(Predicted)
Density 
1.78±0.1 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
Appearance
Light brown to brown Solid
CAS DataBase Reference
35371-03-0(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Oakwood
Product number
008044
Product name
4-Iodothioanisole
Purity
98%
Packaging
5g
Price
$50
Updated
2021/12/16
AK Scientific
Product number
J99589
Product name
4-Iodothioanisole
Packaging
10g
Price
$90
Updated
2021/12/16
Oakwood
Product number
008044
Product name
4-Iodothioanisole
Purity
98%
Packaging
25g
Price
$235
Updated
2021/12/16
AK Scientific
Product number
I353
Product name
4-Iodothioanisole
Packaging
25g
Price
$281
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0023977
Product name
4-IODOTHIOANISOLE
Purity
95.00%
Packaging
5G
Price
$465
Updated
2021/12/16
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4-IODOTHIOANISOLE Chemical Properties,Usage,Production

Chemical Properties

In solution, 4-Iodothioanisole shows a yellowish color due to intramolecular excitation of the cyclopentene system, while in the solid state it is orange because of free rotation around the carbon-iodine bond.It reacts with electrophiles to form carbon-iodine bonds and can be used to make cross-coupling reactions.

Uses

4-Iodothioanisole is a synthetic molecule that is used in organic chemistry as a reagent for the formation of carbon-carbon bonds. It also enhances the fluorescence of some molecules and has been used in supramolecular chemistry.

Synthesis

98546-51-1

35371-03-0

General procedure for the synthesis of 4-iodoanisole from 4-methylthiophenylboronic acid: KX (X = I, Br) (0.2 mmol), 4-methylthiophenylboronic acid (0.3 mmol), CuBr2 (4.5 mg, 10 mol%), 1,10-phenanthroline (7.2 mg, 20 mol%), and DMF ( 2 mL). The reaction mixture was stirred at 80 °C or 130 °C for the reaction. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue was purified by rapid column chromatography on silica gel to afford the target product 4-iodoanisole.

References

[1] Tetrahedron Letters, 2011, vol. 52, # 16, p. 1993 - 1995
[2] Tetrahedron Letters, 2015, vol. 56, # 9, p. 1122 - 1123
[3] RSC Advances, 2015, vol. 5, # 103, p. 84910 - 84919

4-IODOTHIOANISOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-IODOTHIOANISOLE Suppliers

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View Lastest Price from 4-IODOTHIOANISOLE manufacturers

Career Henan Chemical Co
Product
4-IODOTHIOANISOLE 35371-03-0
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-31

35371-03-0, 4-IODOTHIOANISOLERelated Search:

Meldrum's Acid o-Iodothioanisole,2-IODOTHIOANISOLE 3-IODOTHIOANISOLE,3-IODOTHIOANISOLE 98.0%MIN 4-IODOTHIOANISOLE (4-Iodophenyl)methylcyanocarbonimidodithioate 4-IODOPHENYL PHENYLSULFONATE 4-IODOPHENYL 4-METHYLPHENYLSULFONATE SALOR-INT L140783-1EA METHYL 2-([(2,5-DICHLOROPHENYL)SULFONYL]OXY)-5-IODOBENZENECARBOXYLATE (4-IODOPHENYL)DIPHENYLSULFONIUM TRIFLATE SALOR-INT L150118-1EA METHYL 2-([(4-BROMOPHENYL)SULFONYL]OXY)-5-IODOBENZENECARBOXYLATE 1-Piperazineethanol, 4-(10,11-dihydro-3-fluoro-8-iododibenzo(b,f)thiep in-10-yl)-, (Z)-2-butenedioate (1:2) METHYL 5-IODO-2-[(MESITYLSULFONYL)OXY]BENZENECARBOXYLATE 1-(2,2-DIMETHOXY-ETHYLSULFANYL)-4-IODO-BENZENE METHYL 2-([(4-FLUOROPHENYL)SULFONYL]OXY)-5-IODOBENZENECARBOXYLATE 4-[(Trifluoromethyl)thio]iodobenzene SALOR-INT L147850-1EA

  • 4-Iodothiaanisole
  • (4-iodophenyl)(methyl)sulfane
  • 1-(Methylthio)-4-iodobenzene
  • 1-Iodo-4-(methylthio)benzene
  • Methyl p-iodophenyl sulfide
  • Methyl(4-iodophenyl) sulfide
  • p-Iodothioanisole
  • 4-IODOTHIOANISOLE
  • 4-Iodothioaniole
  • 1-iodo-4-methylsulfanylbenzene
  • Benzene, 1-iodo-4-(methylthio)-
  • (4-Lodophenyl)(methyl)sulfane
  • 4-Iodophenyl methyl sulfide
  • 35371-03-0