2-Propenoic acid, 3-iodo, methyl ester, (Z)-
- Product Name
- 2-Propenoic acid, 3-iodo, methyl ester, (Z)-
- CAS No.
- 6214-23-9
- Chemical Name
- 2-Propenoic acid, 3-iodo, methyl ester, (Z)-
- Synonyms
- (Z)-Methyl 3-iodoacrylate;Methyl (Z)-3-Iodoacrylate;methyl (2Z)-3-iodoprop-2-enoate;Methyl (2Z)-3-iodo-2-propenoate|||;(Z)-3-Iodo Propenoic Acid Methyl Easter;2-Propenoic acid, 3-iodo, methyl ester, (Z)-;(Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E;2-Propenoic acid, 3-iodo-, methyl ester, (2Z)-;(Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E;2-Propenoic acid, 3-iodo, methyl ester, (Z)- ISO 9001：2015 REACH
- CBNumber
- CB31241634
- Molecular Formula
- C4H5IO2
- Formula Weight
- 211.99
- MOL File
- 6214-23-9.mol
2-Propenoic acid, 3-iodo, methyl ester, (Z)- Property
- Boiling point:
- 182.1±23.0 °C(Predicted)
- Density
- 1.918±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- form
- solid
- Appearance
- Yellow to brown Liquid
- InChI
- InChI=1S/C4H5IO2/c1-7-4(6)2-3-5/h2-3H,1H3/b3-2-
- InChIKey
- SUQXOFVGKSUSSM-IHWYPQMZSA-N
- SMILES
- C(OC)(=O)/C=C\I
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- SYX00331
- Product name
- (Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E
- Packaging
- 1g
- Price
- $179
- Updated
- 2025/07/31
- Product number
- 069612
- Product name
- (Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E
- Purity
- 98%
- Packaging
- 1g
- Price
- $180
- Updated
- 2021/12/16
- Product number
- HCH0352986
- Product name
- (Z)-3-IODOPROPENOIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $503.15
- Updated
- 2021/12/16
- Product number
- 069612
- Product name
- (Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E
- Purity
- 98%
- Packaging
- 5g
- Price
- $590
- Updated
- 2021/12/16
- Product number
- 6847AE
- Product name
- (Z)-3-Iodopropenoic acid methyl ester 95/5 Z/E
- Packaging
- 10g
- Price
- $732
- Updated
- 2021/12/16
2-Propenoic acid, 3-iodo, methyl ester, (Z)- Chemical Properties,Usage,Production
Synthesis
922-67-8
6214-23-9
The general procedure for the synthesis of (Z)-3-iodoacrylic acid methyl ester from methyl propargylate was as follows: a mixed solution of methyl propargylate (15.0 g, 178 mmol) and lithium iodide (LiI, 26.3 g, 196 mmol) in acetic acid (178 mL) was heated with stirring at 70 °C. The reaction process was monitored by gas chromatography-mass spectrometry (GC-MS) (after neutralization). After 11 h of reaction, water (900 mL) was added to the reaction mixture and neutralized with solid potassium carbonate (K2CO3) until no carbon dioxide gas was produced. Subsequently, extraction was carried out with ether (1.8 L x 3). The organic phases were combined, dried over anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (petroleum ether/ethyl acetate = 30/1) to afford methyl (Z)-3-iodoacrylate (32.36 g, 89% yield) as a pale yellow oil.
References
[1] Journal of the American Chemical Society, 2004, vol. 126, # 32, p. 9926 - 9927
[2] Chemistry - A European Journal, 2014, vol. 20, # 28, p. 8594 - 8598
[3] Journal of Organic Chemistry, 2007, vol. 72, # 7, p. 2525 - 2532
[4] Tetrahedron, 2009, vol. 65, # 40, p. 8418 - 8427
[5] Angewandte Chemie - International Edition, 2015, vol. 54, # 34, p. 9958 - 9962
2-Propenoic acid, 3-iodo, methyl ester, (Z)- Preparation Products And Raw materials
Raw materials
Preparation Products
2-Propenoic acid, 3-iodo, methyl ester, (Z)- Suppliers
- Tel
- tp@aladdinsci.com
- Country
- United States
- ProdList
- 52923
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@synthonix.com
- Country
- United States
- ProdList
- 6872
- Advantage
- 58
- Tel
- --
- Fax
- --
- sales@combi-blocks.com
- Country
- United States
- ProdList
- 6618
- Advantage
- 69
- Tel
- --
- Fax
- --
- Country
- United States
- ProdList
- 6773
- Advantage
- 87
- Tel
- --
- Fax
- --
- sales@matrixscientific.com
- Country
- United States
- ProdList
- 6632
- Advantage
- 80
- Tel
- --
- Fax
- --
- sales@honestjoy.cn
- Country
- United States
- ProdList
- 6675
- Advantage
- 54