ChemicalBook > CAS DataBase List > (S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL

(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL

Product Name
(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
CAS No.
320714-00-9
Chemical Name
(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
Synonyms
(S,S)-DPP-TROST LIGAND;Trost (S,S)-Bis-ProPhenol Ligand;(S,S)-TROST-BIS-PRO-PHENOL LIGAND;2,6-Bis[(2S)-2-(hydroxydiphenylmethyl)-1- pyrrolidinylmethyl]-4-methylphenol;(S,S)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)PYRROLIDIN-1-YLMETHYL]-4-METHYLPHENOL;(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL;2,6-Bis[(2S)-2-(hydroxydiphenylmethyl)-1- pyrrolidinylmethyl]-4-methylphenol,99%e.e.;(S,S)-(+)-2,6-Bis[2-(hydroxydiphenylmethyl)-1-pyrrolidinyl-methyl]-4-methylphenol 95%;2-Pyrrolidinemethanol, 1,1'-[(2-hydroxy-5-methyl-1,3-phenylene)bis(methylene)]bis[α,α-diphenyl-, (2S,2'S)-;((2S,2'S)-1,1'-((2-Hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis(pyrrolidine-2,1-diyl))bis(diphenylmethanol)
CBNumber
CB3126008
Molecular Formula
C43H46N2O3
Formula Weight
638.84
MOL File
Mol file
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(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL Property

Melting point:
93-102 °C
Boiling point:
777.5±55.0 °C(Predicted)
Density 
1.226±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.50±0.50(Predicted)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36-40-36/38-21/22
Safety Statements 
26-36/37
RIDADR 
UN 2811 6.1/PG 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
668370
Product name
(S,S)-(+)-2,6-Bis[2-(hydroxydiphenylmethyl)-1-pyrrolidinyl-methyl]-4-methylphenol
Purity
95%
Packaging
1G
Price
$36.44
Updated
2024/03/01
Sigma-Aldrich
Product number
668370
Product name
(S,S)-(+)-2,6-Bis[2-(hydroxydiphenylmethyl)-1-pyrrolidinyl-methyl]-4-methylphenol
Purity
95%
Packaging
5G
Price
$234
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0004950
Product name
(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
Purity
95.00%
Packaging
1G
Price
$646.88
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0004950
Product name
(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
Purity
95.00%
Packaging
5G
Price
$927.76
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0004950
Product name
(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
Purity
95.00%
Packaging
100G
Price
$4851
Updated
2021/12/16
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(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL Chemical Properties,Usage,Production

Uses

A useful catalyst in asymmetric aldol, Henry, and Mannich-type reactions.

(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91

320714-00-9, (S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOLRelated Search:


  • (S,S)-DPP-TROST LIGAND
  • (S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
  • (S,S)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)PYRROLIDIN-1-YLMETHYL]-4-METHYLPHENOL
  • (S,S)-TROST-BIS-PRO-PHENOL LIGAND
  • Trost (S,S)-Bis-ProPhenol Ligand, (S,S)-2,6-Bis[2-(hydroxydiphenylmethyl)pyrrolidin-1-ylmethyl]-4-methylphenol
  • Trost (S,S)-Bis-ProPhenol Ligand
  • (S,S)-(+)-2,6-Bis[2-(hydroxydiphenylmethyl)-1-pyrrolidinyl-methyl]-4-methylphenol 95%
  • 2,6-Bis[(2S)-2-(hydroxydiphenylmethyl)-1- pyrrolidinylmethyl]-4-methylphenol
  • 2,6-Bis[(2S)-2-(hydroxydiphenylmethyl)-1- pyrrolidinylmethyl]-4-methylphenol,99%e.e.
  • ((2S,2'S)-1,1'-((2-Hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis(pyrrolidine-2,1-diyl))bis(diphenylmethanol)
  • 2-Pyrrolidinemethanol, 1,1'-[(2-hydroxy-5-methyl-1,3-phenylene)bis(methylene)]bis[α,α-diphenyl-, (2S,2'S)-
  • ((2S,2'S)-1,1'-((2-Hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis(pyrrolidine-2,1-diyl))bis(diphenylmethanol)
  • 320714-00-9
  • Chiral Nitrogen