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DEXTROMETHORPHAN HYDROBROMIDE

Product Name
DEXTROMETHORPHAN HYDROBROMIDE
CAS No.
125-69-9
Chemical Name
DEXTROMETHORPHAN HYDROBROMIDE
Synonyms
DEXTROMETHORPHAN HBR;RACEMETHORPHAN;Dextro;Delsym;ROMILAR;Sisaal;medicon;tusilan;Tussade;antussan
CBNumber
CB3131945
Molecular Formula
C18H26BrNO
Formula Weight
352.31
MOL File
125-69-9.mol
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DEXTROMETHORPHAN HYDROBROMIDE Property

Melting point:
125-127℃
alpha 
D20 +27.6° (c = 1.5 in water)
pka
pKa 8.83(50% aq EtOH) (Uncertain)
form 
Solid
Water Solubility 
Soluble in water (40 mM), and alcohol (1:10).
EPA Substance Registry System
Morphinan, 3-methoxy-17-methyl-, hydrobromide (1:1),(9.alpha.,13.alpha.,14.alpha.)- (125-69-9)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
36/37
RIDADR 
3249
HazardClass 
6.1(b)
PackingGroup 
III
Toxicity
cat,LD50,intravenous,19800ug/kg (19.8mg/kg),LUNGS, THORAX, OR RESPIRATION: DYSPNEASENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE,Oyo Yakuri. Pharmacometrics. Vol. 6, Pg. 1207, 1972.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
J61732
Product name
Dextromethorphan hydrobromide
Packaging
5g
Price
$110
Updated
2023/06/20
Alfa Aesar
Product number
J61732
Product name
Dextromethorphan hydrobromide
Packaging
10g
Price
$217
Updated
2023/06/20
Alfa Aesar
Product number
J61732
Product name
Dextromethorphan hydrobromide
Packaging
50g
Price
$784
Updated
2023/06/20
DC Chemicals
Product number
DCAPI1431
Product name
Dextromethorphan hydrobromide
Purity
>99%
Packaging
1g
Price
$500
Updated
2021/12/16
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DEXTROMETHORPHAN HYDROBROMIDE Chemical Properties,Usage,Production

Originator

Symptom 1 ,Parke Davis,US,1977

Uses

It is used as a potentially useful NMDA receptor agonist. it is usually used as central nervous antitussive, cough suppressant. This is one of the most popular ingredients in over-the-counter cold and cough medications. Dextromethorphan hydrobromide may be added to other preparations to help treat pain and a variety of other disturbances as well. It is used as a pharmaceutical raw material.

Uses

relieving cough

Uses

Cough and cold preparations, Antitussives, OTC cough medicine

Manufacturing Process

The methylation of 51.4 parts by weight of D,L-3-hydroxy-N-methylmorphinan is carried out with a methylating solution obtained from 51.5 parts by weight of phenyl-trimethylammonium-chloride. The D,L-3-methoxy-Nmethyl-morphinan is isolated in the form of its hydrobromide, which melts with 1 mol of water at 92°-94°C,without water at 239°-240°C. The base isolated from the aqueous solution by means of sodium carbonate melts at 81°-83°C.
27.1 parts by weight of D,L-3-methoxy-N-methyl-morphinan base are dissolved with 15.0 parts by weight of D-tartaric acid in 150 parts by volume of hot alcohol. The solution is cooled and seeded with (+)-3-methoxy-Nmethyl-morphinan-tartrate.The (+)-form which is difficultly soluble in alcohol separates, is filtered by suction and washed with a little alcohol.
[The (-)-form may be crystallized from the residue obtained by concentrating the mother liquor, separating therefrom as much as possible of the (+)-form and adding acetone].
The (+)-3-methoxy-N-methyl-morphinan-tartrate melts with 1 mol of water at 195°-196°C [α]D20 =+30.6° (c = 1.5 in water). The (+) base melting at 108°-109°C may be obtained from the tartrate by means of sodium carbonate. The corresponding hydrobromide melts at 122°-124°C [α]D20 =+27.6° (c = 1.5 in water).

brand name

Benylin DM (Parke-Davis); Dextromethorphan Hydrobromide OROS Tablets (Ciba-Geigy); Drixoral Cough (Schering-Plough HealthCare); PediaCare 1 (McNeil Consumer); Romilar (Hoffmann-LaRoche-International); St. Joseph Cough Syrup (Schering-Plough HealthCare).

Therapeutic Function

Antitussive

DEXTROMETHORPHAN HYDROBROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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DEXTROMETHORPHAN HYDROBROMIDE Suppliers

125-69-9, DEXTROMETHORPHAN HYDROBROMIDERelated Search:


  • DEXTROMETHORPHAN HYDROBROMIDE / DXM Hbr
  • DEXTROMETHORPHAN HBR
  • DEXTROMETHORPHAN HYDROBROMICUM
  • DEXTROMETHORPHAN HYDROBROMIDE
  • RACEMETHORPHAN
  • ROMILAR
  • 13-alpha,14-alpha-morphinan,3-methoxy-17-methyl-9-alphhydrobromide
  • 3-methoxy-n-methyl-,hydrobromide,(+)-morphina
  • antussan
  • demorphan
  • dextromethorphanbromide
  • dextrometorphanhydrobromide
  • d-methorphanhydrobromide
  • dormethan
  • medicon
  • methoratehydrobromide
  • metrorat
  • ro1-5470/5
  • romilarhydrobromide
  • tusilan
  • 3-METHOXY-17-METHYL-9ALPHA,13ALPHA-14ALPHA-MORPHINAN HYDRO-BROMIDE
  • (9S,13S,14S)-3-METHOXY-17-METHYLMORPHINAN HYDROBROMIDE
  • DEXTROMETHORPHAN MALEATE HBR
  • (9alpha,13alpha,14alpha)-3-methoxy-17-methylmorphinan hydrobromide
  • Dextromethorphan Hydrobromide, substrate for Cytochrome P450 2D6
  • DextromethorphanHydrobromideUsp
  • Dextromethorphanehydrobromide
  • Morphinan, 3-methoxy-17-methyl-, hydrobromide, (9.alpha.,13.alpha.,14.alpha.)-
  • 9α,13α,14α-Morphinan, 3-methoxy-17-methyl-, hydrobromide (8CI)
  • Delsym
  • Demorphine
  • Dormetan
  • Morphinan, 3-methoxy-17-methyl-, hydrobromide, (9α,13α,14α)-
  • Ro 1-5470
  • Tussade
  • Astomari
  • Detomefan
  • Dextophan
  • Hihustan
  • Sisaal
  • Morphinan,3-Methoxy-17-Methyl-, hydrobroMide (1:1), (9a,13a,14a)-
  • Dextro
  • 10B-hydroxy DextroMethorphan
  • d-Form hydrobromide
  • Dextromethorphan Hydrohromide
  • dextromethorphan hydrodromide
  • Dextromethorphan hydrobromide DXM
  • dextromethorphan hydropomide
  • Dxm (Dextromethorphan Hydrobromide)
  • Dextromethorphan hydrobromide CRS
  • Dextromethorphan Hydrobromide DISCONTINUED. Please see D299455 or D299455
  • (4bS,8aS,9S)-3-methoxy-11-methyl-6,7,8,8a,9,10-hexahydro-5H-9,4b-(epiminoethano)phenanthrene hydrobromide
  • Dextromethorphan Hydrobromide/Romilar
  • 125-69-9
  • C18H25NOBrH
  • C18H25NOHBr
  • C18H26BrNO
  • API