2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

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Product Name: 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
CAS No.: 120666-13-9
Chemical Name: 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Synonyms: Verkadebase;VERKADE SUPERBASE;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane;4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane;2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-;2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase
CBNumber: CB3138803
Molecular Formula: C9H21N4P
Formula Weight: 216.26
MOL File: 120666-13-9.mol

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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Property

Melting point:: 110-115 °C(lit.)
Boiling point:: 263.9±39.0 °C(Predicted)
pka: 10.43±0.20(Predicted)
form: solid
color: white waxy
Sensitive: moisture sensitive, store cold
BRN: 4970285

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 463558
Product name: 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Packaging: 1g
Price: $320
Updated: 2024/03/01

Sigma-Aldrich

Product number: 463558
Product name: 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Packaging: 5g
Price: $1000
Updated: 2024/03/01

Strem Chemicals

Product number: 15-6400
Product name: 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane VERKADE SUPERBASE
Packaging: 250mg
Price: $104
Updated: 2024/03/01

Strem Chemicals

Product number: 15-6400
Product name: 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane VERKADE SUPERBASE
Packaging: 1g
Price: $311
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CHM0008271
Product name: 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Purity: 95.00%
Packaging: 1G
Price: $816.19
Updated: 2021/12/16

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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties,Usage,Production

Reaction

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.

Uses

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-?arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions.

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials

Raw materials

Preparation Products

5-PHENYL-1,3-OXAZOLE-4-CARBONYL CHLORIDE

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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Suppliers

China 14 Germany 1 Switzerland 1 United States 3 Global 19

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120666-13-9, 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANERelated Search:

n-Hendecane 2,8,9-TRI-I-PROPYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE TRIS(2-AMINOETHYL)AMINE 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE HYDROCHLORIDE 2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane TRIS(2-(METHYLAMINO)ETHYL)AMINE 97

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &

2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase

VERKADE SUPERBASE

2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane

Verkadebase

4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane

2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-

120666-13-9

C9H21N4P

Organic Bases

Synthetic Reagents

Achiral Phosphine

Alkyl Phosphine

organophosphine ligand