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ChemicalBook > CAS DataBase List > 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

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Product Name
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
CAS No.
120666-13-9
Chemical Name
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Synonyms
Verkadebase;VERKADE SUPERBASE;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane;4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane;2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-;2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase
CBNumber
CB3138803
Molecular Formula
C9H21N4P
Formula Weight
216.26
MOL File
120666-13-9.mol
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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Property

Melting point:
110-115 °C(lit.)
Boiling point:
263.9±39.0 °C(Predicted)
pka
10.43±0.20(Predicted)
form 
solid
color 
white waxy
Sensitive 
moisture sensitive, store cold
BRN 
4970285
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
463558
Product name
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Packaging
1g
Price
$320
Updated
2024/03/01
Sigma-Aldrich
Product number
463558
Product name
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Packaging
5g
Price
$1000
Updated
2024/03/01
Strem Chemicals
Product number
15-6400
Product name
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane VERKADE SUPERBASE
Packaging
250mg
Price
$104
Updated
2024/03/01
Strem Chemicals
Product number
15-6400
Product name
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane VERKADE SUPERBASE
Packaging
1g
Price
$311
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0008271
Product name
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Purity
95.00%
Packaging
1G
Price
$816.19
Updated
2021/12/16
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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties,Usage,Production

Reaction

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.

Uses

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-?arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions.

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Suppliers

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120666-13-9, 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANERelated Search:


  • 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &
  • 2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase
  • VERKADE SUPERBASE
  • 2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane
  • Verkadebase
  • 4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane
  • 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-
  • 120666-13-9
  • C9H21N4P
  • Organic Bases
  • Synthetic Reagents
  • Achiral Phosphine
  • Alkyl Phosphine
  • organophosphine ligand