2-BROMO-6-HYDRAZINYLPYRIDINE
- Product Name
- 2-BROMO-6-HYDRAZINYLPYRIDINE
- CAS No.
- 26944-71-8
- Chemical Name
- 2-BROMO-6-HYDRAZINYLPYRIDINE
- Synonyms
- 2-Bromo-6-hydrazinopydine;2-hydrazine-6-bromopyridine;2-Diazanyl-6-Bromo Pyridine;2-Bromo-6-hydrazinopyridine;(6-bromo-2-pyridyl)hydrazine;2-BROMO-6-HYDRAZINYLPYRIDINE;(6-Bromopyridin-2-yl)hydrazine;Pyridine, 2-bromo-6-hydrazinyl-;2-Bromo-6-hydrazinopyridine,98%;1-(6-bromopyridin-2-yl)hydrazine
- CBNumber
- CB31479521
- Molecular Formula
- C5H6BrN3
- Formula Weight
- 188.03
- MOL File
- 26944-71-8.mol
2-BROMO-6-HYDRAZINYLPYRIDINE Property
- Melting point:
- 117-118℃
- Boiling point:
- 265.9±50.0 °C(Predicted)
- Density
- 1.82±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- solubility
- soluble in Methanol
- form
- Solid
- pka
- 9.08±0.70(Predicted)
- color
- Pale brown
Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
- HazardClass
- 6.1
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H301Toxic if swalloed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B5120
- Product name
- 2-Bromo-6-hydrazinopyridine
- Purity
- min. 98.0 %
- Packaging
- 1G
- Price
- $56
- Updated
- 2025/07/31
- Product number
- B5120
- Product name
- 2-Bromo-6-hydrazinopyridine
- Purity
- min. 98.0 %
- Packaging
- 5G
- Price
- $166
- Updated
- 2025/07/31
- Product number
- B997633
- Product name
- 2-Bromo-6-hydrazinylpyridine
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FB123838
- Product name
- 2-Bromo-6-hydrazinopyridine hydrochloride
- Packaging
- 500mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- 064391
- Product name
- 2-Bromo-6-hydrazinopyridine
- Packaging
- 25g
- Price
- $279
- Updated
- 2021/12/16
2-BROMO-6-HYDRAZINYLPYRIDINE Chemical Properties,Usage,Production
Uses
2-Bromo-6-hydrazinylpyridine is used as an intermediate in organic synthesis for the production and research of other compounds.
Synthesis
626-05-1
26944-71-8
General procedure for the synthesis of 2-bromo-6-hydrazinopyridine from 2,6-dibromopyridine: commercially available 2,6-dibromopyridine (4.12 g, 16.6 mmol) was suspended in ethanol (40 mL), followed by the addition of hydrazine hydrate (10 mL, 97.6 mmol, 50-60% aqueous solution). The reaction mixture was heated and refluxed in a sand bath at 115°C for 18 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the resulting residue was purified by silica gel column chromatography with the eluent ethyl acetate/n-heptane (60/40, v/v) to afford 2-bromo-6-hydrazinopyridine as an off-white solid (3.05 g, 93% yield).1H-NMR (400 MHz, CDCl3) δ: 7.33 (t, 1H), 6.83 (d, 1H ), 6.67 (d, 1H), 6.00 (br-s, 1H), 3.00-3.33 (br-s, 2H).
References
[1] Patent: US2011/256064, 2011, A1. Location in patent: Page/Page column 22
[2] Patent: EP2377860, 2011, A1. Location in patent: Page/Page column 29
[3] Patent: US2011/280808, 2011, A1. Location in patent: Page/Page column 54
[4] Patent: WO2015/110263, 2015, A1. Location in patent: Page/Page column 159
[5] Patent: US2017/2005, 2017, A1. Location in patent: Paragraph 0760; 0761; 0762; 0763
2-BROMO-6-HYDRAZINYLPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-BROMO-6-HYDRAZINYLPYRIDINE manufacturers
- Product
- 2-BROMO-6-HYDRAZINYLPYRIDINE 26944-71-8
- Price
- US $1.11/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-08-23
- Product
- 2-Bromo-6-hydrazinopyridine 26944-71-8
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 500 MT
- Release date
- 2020-05-12
- Product
- 2-BROMO-6-HYDRAZINYLPYRIDINE 26944-71-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2019-12-31