2-Methacryloyloxy-2-methyladamantane
- Product Name
- 2-Methacryloyloxy-2-methyladamantane
- CAS No.
- 177080-67-0
- Chemical Name
- 2-Methacryloyloxy-2-methyladamantane
- Synonyms
- 2-METHYL-2-ADAMANTYL METHACRYL;-Methyl-2-adamantylmethacrylate;2-Ethy1-2-adamantylmethacrylate;2-Methyl-2-adaMantyl Methacrylte;2-Methyl-2-adamantyl methacrylate;2-MethyladaMantan-2-yl Methacrylate;2-methacryloyloxy-2-methyladamantane;2-Methyl-2-adamantyl methacrylate (MADMA);Methacrylic Acid 2-Methyl-2-adamantyl Ester;2-Methyl-2-adamantylmethacrylate 177080-67-0
- CBNumber
- CB31483683
- Molecular Formula
- C15H22O2
- Formula Weight
- 234.33
- MOL File
- 177080-67-0.mol
2-Methacryloyloxy-2-methyladamantane Property
- Boiling point:
- 301.3±11.0 °C(Predicted)
- Density
- 1.06±0.1 g/cm3(Predicted)
- refractive index
- 1.5050 to 1.5090
- Flash point:
- 120°C(lit.)
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 1.06
- Sensitive
- Heat Sensitive
- InChI
- InChI=1S/C15H22O2/c1-9(2)14(16)17-15(3)12-5-10-4-11(7-12)8-13(15)6-10/h10-13H,1,4-8H2,2-3H3
- InChIKey
- FDYDISGSYGFRJM-UHFFFAOYSA-N
- SMILES
- C(OC1(C)C2CC3CC1CC(C3)C2)(=O)C(C)=C
Safety
- HS Code
- 2902190000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M2260
- Product name
- 2-Methacryloyloxy-2-methyladamantane (stabilized with MEHQ)
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $54
- Updated
- 2024/03/01
- Product number
- M2260
- Product name
- 2-Methacryloyloxy-2-methyladamantane (stabilized with MEHQ)
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $216
- Updated
- 2024/03/01
- Product number
- M219910
- Product name
- 2-Methyl-2-adamantylMethacrylate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 9297AA
- Product name
- 2-Methyladamantan-2-ylmethacrylate
- Packaging
- 1g
- Price
- $158
- Updated
- 2021/12/16
- Product number
- 9297AA
- Product name
- 2-Methyladamantan-2-ylmethacrylate
- Packaging
- 5g
- Price
- $425
- Updated
- 2021/12/16
2-Methacryloyloxy-2-methyladamantane Chemical Properties,Usage,Production
Description
2-Methyl-2-adamantylmethacrylate (2-Methacryloyloxy-2-methyladamantane) is an aliphatic hydrocarbon with a trifluoromethyl group. It is a monomer that can be used to make polymers. 2-Methyl-2-adamantylmethacrylate has been shown to polymerize rapidly and form high molecular weight polymers. It reacts with hydroxyl groups to form ester linkages. This molecule also has the ability to self assemble, making it a supramolecular material. Impurities may affect the polymerization kinetics of this molecule and must be removed before use. As this compound is hydrophobic, it can only be patterned using a sublimable process.
Chemical Properties
Off-white powder.
Uses
2-Methyl-2-adamantylmethacrylate can be used to prepare Analog Semiconductors, Light-Emitting Diodes LED, Solar Photovoltaics PV.
Application
2-Methacryloyloxy-2-methyladamantane as a guest molecule can be introduced onto the silicon substrate by interacting with β-cyclodextrin (β-CD) to construct supramolecular composite surfaces. After the assembly of hydrophilic guest molecules on the main surface, the wettability, water lubrication and resistance to algal cell adhesion of the supramolecular composite surface were improved. This host-guest interface supramolecule provides a new way to prepare water-based lubrication and antifouling materials[2].
General Description
Three different methacrylic monomers (g-butyrolactone methacrylate (GBLMA), 3-hydroxyl-1-adamantyl methacrylate (HAMA), and 2-methyl-2- adamantyl methacrylate (MAMA)) are the most often terpolymerized for 193 nm photoresists. The lactone group of GBLMA plays a vital role in the etching rate, facilitating binding to the substrate. The hydroxyl group of HAMA aids in the solubility and stability of the polymer. MAMA is particularly sensitive to 193 nm light and improves the etching resolution (chemical amplification)[1].
Synthesis
The synthesis of 2-Methyl-2-adamantylmethacrylate is as follows:Add 3546ml of n-heptane in the 5L four-necked flask equipped with stirring paddle, condenser tube and thermometer, turn on stirring, add 126.3g of 2-methyladamantanol to the system, and slowly add 0.022g polymerization inhibitor tetrachlorobenzoquinone to the reaction, add 110.8g basic ion exchange resin, adjust pH=7-8, cool down to -13°C, slowly add 110.8g vinyl methacrylate dropwise to the reaction system, keep the reaction for 7h, monitor the reaction progress, and take samples for detection After the reaction was completed, 1000 ml of water was added to the reaction system, and the mixture was stirred and extracted for phase separation. The organic phase was dried, concentrated under reduced pressure and evaporated to dryness to obtain 167 g of 2-methyl-2-adamantyl methacrylate (2-Methacryloyloxy-2-methyladamantane) product with a yield of 93.78%.
References
[1] M. Maríc. “Nitroxide‐mediated polymerization of adamantyl‐functional methacrylates for 193 nm photoresists.” Canadian Journal of Chemical Engineering 95 1 (2017): 708–716.
[2] RONGNIAN XU. Promoting Lubricity and Antifouling Properties by Supramolecular-Recognition-Based Surface Grafting[J]. Langmuir, 2018. DOI:10.1021/acs.langmuir.8b02375.
2-Methacryloyloxy-2-methyladamantane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Methacryloyloxy-2-methyladamantane manufacturers
- Product
- 2-Methyl-2-adamantyl methacrylate 177080-67-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%+
- Supply Ability
- 1000kg per Month
- Release date
- 2022-12-26
- Product
- 2-Methyl-2-adamantyl methacrylate 177080-67-0
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99.5%
- Supply Ability
- 1000kg
- Release date
- 2024-06-04
- Product
- 2-Methyl-2-adamantylmethacrylate 177080-67-0
- Price
- US $0.00/L
- Min. Order
- 1L
- Purity
- GC/LC≥98%
- Supply Ability
- According to customer requirements
- Release date
- 2022-10-11