3,5-DI-TERT-BUTYL-O-BENZOQUINONE

ChemicalBook > CAS DataBase List > 3,5-DI-TERT-BUTYL-O-BENZOQUINONE

3,5-DI-TERT-BUTYL-O-BENZOQUINONE

Product Name: 3,5-DI-TERT-BUTYL-O-BENZOQUINONE
CAS No.: 3383-21-9
Chemical Name: 3,5-DI-TERT-BUTYL-O-BENZOQUINONE
Synonyms: 3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-;Dibutylbenzoquinone;3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE;DTBQ;3,5-Di-tert-butyl-o-quinone;3,5-di-t-Butyl-o-benzoquinone;3,5-Di-t-butyl-1,2-benzoquinone;3,5-DI-TERT-BUTYL-O-BENZOQUINONE;o-Benzoquinone, 3,5-di-tert-butyl-;3,5-Di-tert-butyl-1,2-benzenedione
CBNumber: CB3155419
Molecular Formula: C14H20O2
Formula Weight: 220.31
MOL File: 3383-21-9.mol

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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Property

Melting point:: 112-114 °C(lit.)
Boiling point:: 321.25°C (rough estimate)
Density: 1.0106 (rough estimate)
refractive index: 1.4970 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Very Slightly)
form: Solid
color: Very Dark Green to Very Dark Brown
BRN: 2047944
Stability:: Stable. Incompatible with reducing agents, strong oxidizing agents.
CAS DataBase Reference: 3383-21-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29146990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 157457
Product name: 3,5-Di-tert-butyl-o-benzoquinone
Purity: 98%
Packaging: 10g
Price: $230
Updated: 2024/03/01

TCI Chemical

Product number: D2430
Product name: 3,5-Di-tert-butyl-1,2-benzoquinone
Purity: >98.0%(GC)
Packaging: 5g
Price: $89
Updated: 2024/03/01

TCI Chemical

Product number: D2430
Product name: 3,5-Di-tert-butyl-1,2-benzoquinone
Purity: >98.0%(GC)
Packaging: 25g
Price: $264
Updated: 2024/03/01

Alfa Aesar

Product number: L00169
Product name: 3,5-Di-tert-butyl-o-benzoquinone, 98+%
Packaging: 5g
Price: $61
Updated: 2024/03/01

Alfa Aesar

Product number: L00169
Product name: 3,5-Di-tert-butyl-o-benzoquinone, 98+%
Packaging: 25g
Price: $239
Updated: 2024/03/01

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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Chemical Properties,Usage,Production

Chemical Properties

dark red crystals or powder

Uses

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.

Uses

4,6-Di-tert-butyl-1,2-benzoquinone is a Ortho-Quinone derivative is know to possess a number of biological properties such as antitumoral, antimicrobacterial and anti-cardiovascular disease.

Synthesis Reference(s)

Tetrahedron, 44, p. 6397, 1988 DOI: 10.1016/S0040-4020(01)89827-6
Tetrahedron Letters, 23, p. 957, 1982 DOI: 10.1016/S0040-4039(00)86993-2

General Description

Reactions of the phosphinidene-bridged complexes [Fe₂(η⁵-C₅H₅)₂(μ-PR)(μ-CO)(CO)₂] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.

Purification Methods

It can be recrystallised from MeOH or pet ether, and forms fine red plates or rhombs. [Flaig et al. Justus Liebigs Ann Chem 597 196 1955, IR: Ley & Müller Chem Ber 89 1402 1956, Beilstein 7 IV 2113.]

3,5-DI-TERT-BUTYL-O-BENZOQUINONE Preparation Products And Raw materials

Raw materials

Preparation Products

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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Suppliers

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3383-21-9, 3,5-DI-TERT-BUTYL-O-BENZOQUINONERelated Search:

Methylglyoxal TRANS-2-METHYL-1,3-PENTADIENE 4-HEXEN-3-ONE 2-OXOBUTANALDEHYDE 1,3-HEXADIENE TRANS-3-OCTENE 5-Methyl-2-hexanone 3-HEXENAL 3,3-Dimethylbutyraldehyde 2,3,3-TRIMETHYL-1-BUTENE Methyl allyl ketone 5-METHYL-2,3-HEXANEDIONE trans-2-Pentenal TRANS-4,4-DIMETHYL-2-PENTENE 2,6-Di-tert-butyl-p-benzoquinone, 98+%,2,6-di-tert-Butyl-para-benzoquinone,2,6-DI-TERT-BUTYL-P-BENZOQUINONE 2,6-DI-TERT-BUTYL-P-BENZOQUINONE-4-OXIME,2,6-DI-TERT-BUTYL-P-BENZOQUINONE-4-OXIME, 98+% 2,5-DI-TERT-BUTYL-P-BENZOQUINONE,2,5-DI-TERT-BUTYL-PARA-BENZOQUINONE Catechol

3,5-di-tert-Butyl-ortho-benzoquinone

o-Benzoquinone, 3,5-di-tert-butyl-

Dibutylbenzoquinone

3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-

3,5-Di-tert-butylbenzoquinone, 98+%

3,5-Di-tert-butyl-1,2-benzenedione

3,5-Ditert-butyl-3,5-cyclohexadiene-1,2-dione

4,6-Ditert-butyl-3,5-cyclohexadiene-1,2-dione

3,5-DI-TERT-BUTYL-O-BENZOQUINONE 98+%

3,5-DI-TERT-BUTYL-O-BENZOQUINONE

3,5-DI(TERT-BUTYL)BENZO-1,2-QUINONE

3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE

o-Benzoquinone, 3,5-di-tert-butyl- (8CI)

3,5-Di-<i>tert</i>-butyl-1,2-benzoquinone

3,5-Di-t-butyl-1,2-benzoquinone

3,5-Bis(tert-butyl)-1,2-benzoquinone

3,5-Bis(tert-butyl)cyclohexa-3,5-diene-1,2-dione, 3,5-Bis(tert-butyl)-1,2-dioxocyclohexa-3,5-diene

3,5-di-tert-butylcyclohexa-3,5-diene-1,2-dione

3,5-Di-tert-butyl-o-benzoquinone 98%

3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)- (9CI)

3,5-di-t-Butyl-o-benzoquinone

3,5-Di-tert-butyl-o-quinone

3,5-Bis(tert-butyl)-1,2-benzoquinone 98%

3,5-Di-tert-butyl-1,2-benzoquinone&gt

DTBQ

3383-21-9

Carbonyl Compounds

C13 to C14

Building Blocks

Ketones

Organic Building Blocks

Anthraquinones, Hydroquinones and Quinones

C13 to C14

Carbonyl Compounds

Ketones