ChemicalBook > CAS DataBase List > 3,5-DI-TERT-BUTYL-O-BENZOQUINONE

3,5-DI-TERT-BUTYL-O-BENZOQUINONE

Product Name
3,5-DI-TERT-BUTYL-O-BENZOQUINONE
CAS No.
3383-21-9
Chemical Name
3,5-DI-TERT-BUTYL-O-BENZOQUINONE
Synonyms
3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-;Dibutylbenzoquinone;3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE;DTBQ;3,5-Di-tert-butyl-o-quinone;3,5-di-t-Butyl-o-benzoquinone;3,5-Di-t-butyl-1,2-benzoquinone;3,5-DI-TERT-BUTYL-O-BENZOQUINONE;o-Benzoquinone, 3,5-di-tert-butyl-;3,5-Di-tert-butyl-1,2-benzenedione
CBNumber
CB3155419
Molecular Formula
C14H20O2
Formula Weight
220.31
MOL File
3383-21-9.mol
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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Property

Melting point:
112-114 °C(lit.)
Boiling point:
321.25°C (rough estimate)
Density 
1.0106 (rough estimate)
refractive index 
1.4970 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Very Slightly)
form 
Solid
color 
Very Dark Green to Very Dark Brown
BRN 
2047944
Stability:
Stable. Incompatible with reducing agents, strong oxidizing agents.
CAS DataBase Reference
3383-21-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29146990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
157457
Product name
3,5-Di-tert-butyl-o-benzoquinone
Purity
98%
Packaging
10g
Price
$230
Updated
2024/03/01
TCI Chemical
Product number
D2430
Product name
3,5-Di-tert-butyl-1,2-benzoquinone
Purity
>98.0%(GC)
Packaging
5g
Price
$89
Updated
2024/03/01
TCI Chemical
Product number
D2430
Product name
3,5-Di-tert-butyl-1,2-benzoquinone
Purity
>98.0%(GC)
Packaging
25g
Price
$264
Updated
2024/03/01
Alfa Aesar
Product number
L00169
Product name
3,5-Di-tert-butyl-o-benzoquinone, 98+%
Packaging
5g
Price
$61
Updated
2024/03/01
Alfa Aesar
Product number
L00169
Product name
3,5-Di-tert-butyl-o-benzoquinone, 98+%
Packaging
25g
Price
$239
Updated
2024/03/01
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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Chemical Properties,Usage,Production

Chemical Properties

dark red crystals or powder

Uses

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.

Uses

4,6-Di-tert-butyl-1,2-benzoquinone is a Ortho-Quinone derivative is know to possess a number of biological properties such as antitumoral, antimicrobacterial and anti-cardiovascular disease.

Synthesis Reference(s)

Tetrahedron, 44, p. 6397, 1988 DOI: 10.1016/S0040-4020(01)89827-6
Tetrahedron Letters, 23, p. 957, 1982 DOI: 10.1016/S0040-4039(00)86993-2

General Description

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.

Purification Methods

It can be recrystallised from MeOH or pet ether, and forms fine red plates or rhombs. [Flaig et al. Justus Liebigs Ann Chem 597 196 1955, IR: Ley & Müller Chem Ber 89 1402 1956, Beilstein 7 IV 2113.]

3,5-DI-TERT-BUTYL-O-BENZOQUINONE Preparation Products And Raw materials

Raw materials

Preparation Products

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3,5-DI-TERT-BUTYL-O-BENZOQUINONE Suppliers

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3383-21-9, 3,5-DI-TERT-BUTYL-O-BENZOQUINONERelated Search:

Methylglyoxal TRANS-2-METHYL-1,3-PENTADIENE 4-HEXEN-3-ONE 2-OXOBUTANALDEHYDE 1,3-HEXADIENE TRANS-3-OCTENE 5-Methyl-2-hexanone 3-HEXENAL 3,3-Dimethylbutyraldehyde 2,3,3-TRIMETHYL-1-BUTENE Methyl allyl ketone 5-METHYL-2,3-HEXANEDIONE trans-2-Pentenal TRANS-4,4-DIMETHYL-2-PENTENE 2,6-Di-tert-butyl-p-benzoquinone, 98+%,2,6-di-tert-Butyl-para-benzoquinone,2,6-DI-TERT-BUTYL-P-BENZOQUINONE 2,6-DI-TERT-BUTYL-P-BENZOQUINONE-4-OXIME,2,6-DI-TERT-BUTYL-P-BENZOQUINONE-4-OXIME, 98+% 2,5-DI-TERT-BUTYL-P-BENZOQUINONE,2,5-DI-TERT-BUTYL-PARA-BENZOQUINONE Catechol

  • 3,5-di-tert-Butyl-ortho-benzoquinone
  • o-Benzoquinone, 3,5-di-tert-butyl-
  • Dibutylbenzoquinone
  • 3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-
  • 3,5-Di-tert-butylbenzoquinone, 98+%
  • 3,5-Di-tert-butyl-1,2-benzenedione
  • 3,5-Ditert-butyl-3,5-cyclohexadiene-1,2-dione
  • 4,6-Ditert-butyl-3,5-cyclohexadiene-1,2-dione
  • 3,5-DI-TERT-BUTYL-O-BENZOQUINONE 98+%
  • 3,5-DI-TERT-BUTYL-O-BENZOQUINONE
  • 3,5-DI(TERT-BUTYL)BENZO-1,2-QUINONE
  • 3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE
  • o-Benzoquinone, 3,5-di-tert-butyl- (8CI)
  • 3,5-Di-<i>tert</i>-butyl-1,2-benzoquinone
  • 3,5-Di-t-butyl-1,2-benzoquinone
  • 3,5-Bis(tert-butyl)-1,2-benzoquinone
  • 3,5-Bis(tert-butyl)cyclohexa-3,5-diene-1,2-dione, 3,5-Bis(tert-butyl)-1,2-dioxocyclohexa-3,5-diene
  • 3,5-di-tert-butylcyclohexa-3,5-diene-1,2-dione
  • 3,5-Di-tert-butyl-o-benzoquinone 98%
  • 3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)- (9CI)
  • 3,5-di-t-Butyl-o-benzoquinone
  • 3,5-Di-tert-butyl-o-quinone
  • 3,5-Bis(tert-butyl)-1,2-benzoquinone 98%
  • 3,5-Di-tert-butyl-1,2-benzoquinone&gt
  • DTBQ
  • 3383-21-9
  • Carbonyl Compounds
  • C13 to C14
  • Building Blocks
  • Ketones
  • Organic Building Blocks
  • Anthraquinones, Hydroquinones and Quinones
  • C13 to C14
  • Carbonyl Compounds
  • Ketones