N-Methyl methanesulfonamide
- Product Name
- N-Methyl methanesulfonamide
- CAS No.
- 1184-85-6
- Chemical Name
- N-Methyl methanesulfonamide
- Synonyms
- N-methylmethylsulfonamide;AKOS 91020;N-Methylmethane;N-Methyl methanesulf;N - Methyl sulfonaMide;N-Methyl methanesulfomide;n-methyl-methanesulfonamid;Methy sulfonyl methylamine;METHYL SULFONYL METHYLAMINE;N-METHYL METHANESULFONAMIDE
- CBNumber
- CB3188242
- Molecular Formula
- C2H7NO2S
- Formula Weight
- 109.15
- MOL File
- 1184-85-6.mol
N-Methyl methanesulfonamide Property
- Boiling point:
- 118°C/0.3mmHg(lit.)
- Density
- 1.194±0.06 g/cm3(Predicted)
- refractive index
- 1.4500 to 1.4540
- Flash point:
- 53 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- clear liquid
- pka
- 11.57±0.40(Predicted)
- Specific Gravity
- 1.28
- color
- Colorless to Almost colorless
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/C2H7NO2S/c1-3-6(2,4)5/h3H,1-2H3
- InChIKey
- UHNHTTIUNATJKL-UHFFFAOYSA-N
- SMILES
- CS(NC)(=O)=O
- CAS DataBase Reference
- 1184-85-6(CAS DataBase Reference)
Safety
- RIDADR
- UN 1993 9/PG III
- RTECS
- PB0476750
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 2935909099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M2170
- Product name
- N-Methylmethanesulfonamide
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $58
- Updated
- 2025/07/31
- Product number
- M339058
- Product name
- N-MethylMethanesulfonamide
- Packaging
- 10g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- M339058
- Product name
- N-MethylMethanesulfonamide
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 8169-1-11
- Product name
- N-Methylmethanesulfonamide
- Packaging
- 25g
- Price
- $80
- Updated
- 2021/12/16
- Product number
- OR52265
- Product name
- N-Methylmethanesulphonamide
- Purity
- 97%
- Packaging
- 100g
- Price
- $135
- Updated
- 2021/12/16
N-Methyl methanesulfonamide Chemical Properties,Usage,Production
Uses
N-Methyl methanesulfonamide is used as a pharmaceutical or pesticide intermediate.
Synthesis
124-63-0
74-89-5
1184-85-6
Methanesulfonyl chloride (100 g, 1.0 eq.) was added slowly and dropwise to a stirred ethanol solution of monomethylamine (8 M in EtOH, 525 mL, 4.8 eq.) at 0 °C. After the dropwise addition, the reaction mixture was warmed to room temperature and stirred continuously for 16 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was diluted with dichloromethane (200 mL) and the isolated solid was filtered. The filtrate was concentrated to afford the target product, N-methylsulfonylmethylamine, as an orange oil (82 g, yield not indicated). The product was characterized by 1H NMR (CDCl3, 400 MHz): δ 4.819 (broad single peak, 1H), 2.929 (single peak, 3H), 2.789 (single peak, 3H).
Toxics Screening Level
The initial threshold screening level (ITSL) for methyl methane sulfonamide is 0.1 μg/m3(annual averaging time).
References
[1] Patent: WO2015/38417, 2015, A1. Location in patent: Page/Page column 82
[2] Journal of Organic Chemistry, 2003, vol. 68, # 13, p. 5300 - 5309
[3] Journal of the Chemical Society, 1955, p. 669,674
[4] Journal of the Chemical Society, 1965, p. 3228 - 3234
[5] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986, p. 1211 - 1216
N-Methyl methanesulfonamide Preparation Products And Raw materials
Raw materials
Preparation Products
N-Methyl methanesulfonamide Suppliers
- Tel
- --
- Fax
- --
- contact@fischer-group.ch
- Country
- Switzerland
- ProdList
- 411
- Advantage
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View Lastest Price from N-Methyl methanesulfonamide manufacturers
- Product
- N-Methyl methanesulfonamide 1184-85-6
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-21
- Product
- N-Methyl methanesulfonamide 1184-85-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-30
- Product
- N-Methyl methanesulfonamide 1184-85-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-12